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Bismuth organometallic chemistry information


The stabilization of bismuth's +3 oxidation state due to the inert pair effect yields a plethora of organometallic bismuth-transition metal compounds and clusters with interesting electronics and 3D structures.[1]

  1. ^ Braunschweig, Holger; Cogswell, Paul; Schwab, Katrin (January 2011). "Synthesis, structure and reactivity of complexes containing a transition metal–bismuth bond". Coordination Chemistry Reviews. 255 (1–2): 101–117. doi:10.1016/j.ccr.2010.07.002.

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Bismuth organometallic chemistry

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The stabilization of bismuth's +3 oxidation state due to the inert pair effect yields a plethora of organometallic bismuth-transition metal compounds...

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Organobismuth chemistry

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Organobismuth chemistry is the chemistry of organometallic compounds containing a carbon to bismuth chemical bond. Applications are few. The main bismuth oxidation...

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Bismuth subhalides

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Bismuth-containing solid-state compounds pose an interest to both the physical inorganic chemists as well as condensed matter physicists due to the element's...

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Bismuth compounds

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compounds Bismuth subhalides Organobismuth chemistry Bismuth organometallic chemistry Levason, W.; Reid, G. (2003). "Coordination Chemistry of the s,...

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Organoarsenic chemistry

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Nuclear Chemistry. 16 (3–4): 213–218. doi:10.1016/0022-1902(61)80492-2. Patai, Saul, ed. (1994). The Chemistry of Organic Arsenic, Antimony, and Bismuth Compounds...

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DuPont Central Research

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and Bob Burch's and Karin Karel's fluoro-organometallic chemistry. The major outlet for organometallic chemistry is homogeneous catalysis. DuPont developed...

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Tin

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of tetraorganotins and organotin(IV) halides" (PDF). Journal of Organometallic Chemistry. 689 (13): 2145–2157. doi:10.1016/j.jorganchem.2004.03.027. hdl:1874/6594...

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Heavy metals

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up to 96 out of the 118 known chemical elements; only mercury, lead and bismuth meet all of them. Despite this lack of agreement, the term (plural or singular)...

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Polonium

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irradiation of bismuth. Due to its intense radioactivity, which results in the radiolysis of chemical bonds and radioactive self-heating, its chemistry has mostly...

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Metalloid

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Antimony and Bismuth: Some General Properties and Aspects of Periodicity', in NC Norman (ed.), Chemistry of Arsenic, Antimony and Bismuth, Blackie Academic...

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Relativistic quantum chemistry

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Relativistic quantum chemistry combines relativistic mechanics with quantum chemistry to calculate elemental properties and structure, especially for the...

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In organic and organometallic chemistry, trisulfide is the functional group R-S-S-S-R. Examples include: Diallyl trisulfide Dimethyl trisulfide Trisulfane...

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Cobalt

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Roland, eds. (2010). Organometallics in Environment and Toxicology (Metal Ions in Life Sciences). Cambridge, UK: Royal Society of Chemistry Publishing. p. 75...

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Astatine

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isotope of an element in isotope-related chemistry. See however Nagatsu et al. who encapsulate the bismuth target in a thin aluminium foil and place...

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Period 6 element

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the last stable element; all subsequent elements are radioactive. For bismuth, however, its only primordial isotope, 209Bi, has a half-life of more than...

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Glossary of chemistry terms

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This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools...

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Iron

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states differing by steps of one and a very large coordination and organometallic chemistry: indeed, it was the discovery of an iron compound, ferrocene, that...

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Carbon

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other carbon ligands to be purely inorganic, and not organometallic. However, most organometallic chemists consider metal complexes with any carbon ligand...

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Arsole

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IUPAC, retrieved 29 Sept 2008 Nicholas C. Norman (1998). Chemistry of arsenic, antimony, and bismuth. Springer. p. 235. ISBN 978-0-7514-0389-3. Retrieved...

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Nitrogen

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periodic table, its chemistry shows huge differences from that of its heavier congeners phosphorus, arsenic, antimony, and bismuth. Nitrogen may be usefully...

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Iridium

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Lead

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compounds (due to the Pb–C bond being rather weak). This makes the organometallic chemistry of lead far less wide-ranging than that of tin. Lead predominantly...

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Gallium

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(2010). "Bioorganometallic Chemistry and Malaria". Medicinal Organometallic Chemistry. Topics in Organometallic Chemistry. Vol. 32. p. 155. doi:10...

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Organoantimony chemistry

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ed. (1994). The Chemistry of Organic Arsenic, Antimony, and Bismuth Compounds. Chemistry of Functional Groups. Chichester, UK: Wiley. doi:10.1002/0470023473...

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Chemical element

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nucleophile. "L" is used to represent a general ligand in inorganic and organometallic chemistry. "M" is also often used in place of a general metal. At least two...

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Lanthanide

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behavior in transition metal organometallic compounds. Because of their large size, lanthanides tend to form more stable organometallic derivatives with bulky...

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