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Chemical compound
Arsole, also called arsenole[1] or arsacyclopentadiene, is an organoarsenic compound with the formula C4H4AsH. It is classified as a metallole and is isoelectronic to and related to pyrrole except that an arsenic atom is substituted for the nitrogen atom. Whereas the pyrrole molecule is planar, the arsole molecule is not, and the hydrogen atom bonded to arsenic extends out of the molecular plane. Arsole is only moderately aromatic, with about 40% the aromaticity of pyrrole.[2] Arsole itself has not been reported in pure form, but several substituted analogs called arsoles exist. Arsoles and more complex arsole derivatives have similar structure and chemical properties to those of phosphole derivatives. When arsole is fused to a benzene ring, this molecule is called arsindole, or benzarsole.[3]
^Mann 1970: "In English this ring system has frequently named arsenole 'for euphony'."
^Cite error: The named reference rev was invoked but never defined (see the help page).
^A. Muranaka; S. Yasuike; C.-Y. Liu; J. Kurita; N. Kakusawa; T. Tsuchiya; M. Okuda; N. Kobayashi; Y. Matsumoto; K. Yoshida; D. Hashizume; M. Uchiyama (2009). "Effect of Periodic Replacement of the Heteroatom on the Spectroscopic Properties of Indole and Benzofuran Derivatives". J. Phys. Chem. A. 113 (2): 464–473. doi:10.1021/jp8079843. PMID 19099440.
Arsole, also called arsenole or arsacyclopentadiene, is an organoarsenic compound with the formula C4H4AsH. It is classified as a metallole and is isoelectronic...
"Untersuchungen zur Chemie der Arsole 1,1-dichlor-1-R-λ5-arsole-1-chlorarsole 2,2′,5,5′-tetraphenyldiarsolyl (Studies on the chemistry of arsoles)". J. Organomet. Chem...
mass 84.058 g·mol−1 Related compounds Related compounds Pyrrole, bismole, arsole, stibole; phosphorine Except where otherwise noted, data are given for materials...
(SDS) Chemical Safety Data Related compounds Related compounds Phosphole, arsole, bismole, stibole Except where otherwise noted, data are given for materials...
Metalloles, which can also be viewed as structural analogs of pyrrole, include: Arsole, a moderately-aromatic arsenic analog Bismole, a bismuth analog Borole,...
174.844 g·mol−1 Related compounds Related compounds Pyrrole, phosphole, arsole, bismole Except where otherwise noted, data are given for materials in their...
262.064 g·mol−1 Related compounds Related compounds Pyrrole, phosphole, arsole, stibole Except where otherwise noted, data are given for materials in their...
variety of heterocycles containing arsenic(III) are known. These include arsole, the arsenic analogue of pyrrole, and arsabenzene, the arsenic analogue...
doi:10.1002/9780470772263.ch9. ISBN 0471915564. Caster, Kenneth C. (1996). "Arsoles, stiboles, and bismoles". In Katritzky, Alan R.; Rees, Charles Wayne; Scriven...