The Monsanto process is an industrial method for the manufacture of acetic acid by catalytic carbonylation of methanol.[1] The Monsanto process has largely been supplanted by the Cativa process, a similar iridium-based process developed by BP Chemicals Ltd, which is more economical and environmentally friendly.
This process operates at a pressure of 30–60 atm and a temperature of 150–200 °C and gives a selectivity greater than 99%. It was developed in 1960 by the German chemical company BASF and improved by the Monsanto Company in 1966, which introduced a new catalyst system.[2]
^Hosea Cheung, Robin S. Tanke, G. Paul Torrence "Acetic Acid" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. doi:10.1002/14356007.a01_045.
^"Production method: The Monsanto process". www.greener-industry.org.uk. Archived from the original on 2014-08-11. Retrieved 2014-08-27.{{cite web}}: CS1 maint: unfit URL (link)
The Monsantoprocess is an industrial method for the manufacture of acetic acid by catalytic carbonylation of methanol. The Monsantoprocess has largely...
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a number of industrial processes, notably in catalytic carbonylation of methanol to produce acetic acid by the Monsantoprocess. It is also used to catalyze...
homogeneous catalysts to give acetic acid, as practiced in the Monsantoprocess and Cativa processes. Related reactions include hydrocarboxylation and hydroesterifications...
product and regeneration of the catalyst. Articles on the Monsantoprocess, the Wacker process, and the Heck reaction show catalytic cycles. A catalytic...
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iodomethane, C-alkylation nearly always predominates. In the Monsantoprocess and the Cativa process, MeI forms in situ from the reaction of methanol and hydrogen...
monoxide is catalyzed via metal carbonyl complexes in the Monsantoprocess and Cativa process. Most synthetic aldehydes are produced via hydroformylation...
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