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Zirconium tungstate information


Zirconium(IV) tungstate
Zirconium(IV) tungstate
Names
Other names
zirconium tungsten oxide
Identifiers
CAS Number
  • 16853-74-0 ☒N
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10710102
ECHA InfoCard 100.037.145 Edit this at Wikidata
EC Number
  • 240-876-3
PubChem CID
  • 21954342
InChI
  • InChI=1S/8O.2W.Zr/q;;;;4*-1;;;+4
    Key: OJLGWNFZMTVNCX-UHFFFAOYSA-N
SMILES
  • [O-][W](=O)(=O)[O-].[O-][W](=O)(=O)[O-].[Zr+4]
Properties
Chemical formula
Zr(WO4)2
Molar mass 586.92 g/mol
Appearance white powder
Density 5.09 g/cm3, solid
Solubility in water
negligible
Hazards
GHS labelling:[1]
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H315, H319, H335
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Safety data sheet (SDS) MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Zirconium tungstate (ZrWO4) is the zirconium salt of tungstic acid and has unusual properties. The phase formed at ambient pressure by reaction of ZrO2 and WO3 is a metastable cubic phase, which has negative thermal expansion characteristics, namely it shrinks over a wide range of temperatures when heated.[2] In contrast to most other ceramics exhibiting negative CTE (coefficient of thermal expansion), the CTE of ZrW2O8 is isotropic and has a large negative magnitude (average CTE of -7.2x10−6K−1) over a wide range of temperature (-273 °C to 777 °C).[3] A number of other phases are formed at high pressures.

  1. ^ "C&L Inventory". echa.europa.eu. Retrieved 8 December 2021.
  2. ^ Mary, T. A.; J. S. O. Evans; T. Vogt; A. W. Sleight (1996-04-05). "Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8". Science. 272 (5258): 90–92. Bibcode:1996Sci...272...90M. doi:10.1126/science.272.5258.90. S2CID 54599739. Retrieved 2008-02-20.
  3. ^ Sleight, A.W. (1998). "Isotropic Negative Thermal Expansion". Annu. Rev. Mater. Sci. 28: 29–43. Bibcode:1998AnRMS..28...29S. doi:10.1146/annurev.matsci.28.1.29.

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Zirconium tungstate

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Zirconium tungstate (ZrWO4) is the zirconium salt of tungstic acid and has unusual properties. The phase formed at ambient pressure by reaction of ZrO2...

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Zirconium

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substitute. Zirconium monoxide, ZrO, is also known and S-type stars are recognised by detection of its emission lines. Zirconium tungstate has the unusual...

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List of inorganic compounds

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Zn(SCN)2 Zinc tungstate – ZnWO4 Zirconia hydrate – ZrO2·nH2O Zirconium boride – ZrB2 Zirconium carbide – ZrC Zirconium(IV) chloride – ZrCl4 Zirconium(IV) oxide...

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Rigid unit modes

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that exist in network materials such as quartz, cristobalite or zirconium tungstate. Network materials can be described as three-dimensional networks...

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Negative thermal expansion

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most studied materials to exhibit negative thermal expansion is zirconium tungstate (ZrW 2O 8). This compound contracts continuously over a temperature...

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Zinc cyanide

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coefficients of thermal expansion (exceeding the previous record holder, zirconium tungstate). Typical for an inorganic polymer, Zn(CN)2 is insoluble in most...

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Tungsten

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polymerizes; alkaline soils cause monomeric tungstates; acidic soils cause polymeric tungstates. Sodium tungstate and lead have been studied for their effect...

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Langbeinites

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(BeF2−4), selenate (SeO2−4), chromate (CrO2−4), molybdate (MoO2−4), or tungstates. Although monofluorophosphates are predicted, they have not been described...

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List of CAS numbers by chemical compound

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zirconium(IV) silicide 12039–90–6 ZrSiO4 zirconium(IV) silicate 10101–52–7 ZrTe2 zirconium(IV) telluride 32321–65–6 Zr(WO4)2 zirconium(IV) tungstate 16853–74–0...

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Solubility table

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76.6 78.5 81.8 66.7 63.1 60.8 Cadmium sulfide CdS 1.292×10−12 Cadmium tungstate CdWO4 0.04642 Caesium acetate CsC2H3O2 1010 1345.5 Caesium azide CsN3...

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Terbium

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exchange techniques. Terbium is used to dope calcium fluoride, calcium tungstate and strontium molybdate in solid-state devices, and as a crystal stabilizer...

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Fluoroscopy

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intensity to be commercialized. Edison had quickly discovered that calcium tungstate screens produced brighter images. Edison, however, abandoned his research...

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Glossary of chemical formulae

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ZrF4 zirconium fluoride 7783-64-4 ZrI4 zirconium iodide 13986-26-0 ZrN zirconium nitride 25658-42-8 Zr(NO3)4 zirconium(IV) nitrate Zr(OH)4 zirconium hydroxide...

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Beryllium

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content of beryllium to emit greenish light. Small additions of magnesium tungstate improved the blue part of the spectrum to yield an acceptable white light...

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Oxidation state

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(Ca2+)22[Bi4]4−([Bi2]4−)4[Bi3−]8; see Ponou, Siméon (2006). "Germanides, Germanide-Tungstate Double Salts and Substitution Effects in Zintl Phases". Technische Universität...

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Vanadium

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Oligomerization, and Condensation Reactions of Vanadate(V), Molybdate(vi), and Tungstate(vi), Advances in Inorganic Chemistry, vol. 49, Academic Press, pp. 127–182...

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Molybdenum

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weight, and gout; it can also affect the lungs, kidneys, and liver. Sodium tungstate is a competitive inhibitor of molybdenum. Dietary tungsten reduces the...

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Heavy metals

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"Tissue distribution of tungsten in mice following oral exposure to sodium tungstate," Chemical Research in Toxicology, vol. 24, no. 4, pp 488–493, doi:10...

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Thorium compounds

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the low number of other known thorium oxometallates are the arsenate, tungstate, germanate, silicate, borate, and perrhenate. While thorium titanates...

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List of aqueous ions by element

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Hf(OH)3+ polymeric species 73 Tantalum +5 tantalates 74 Tungsten +6 WO2−4, tungstates 75 Rhenium +7 ReO−4 76 Osmium +6 +8 [OsO2(OH)4]2− (purple) [OsO4(OH)2]2−...

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List of minerals recognized by the International Mineralogical Association

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minerals Sulfate class (class 7), monomeric minerals: sulfates [SO4]2−, tungstates [WO4]2−, niobates [NbO4]2−, molybdates [MoO4]2−, chromates [CrO4]2−, tetraoxotantalate...

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List of vacuum tubes

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oxide touched the nickel cathode that could form conductive aluminium tungstate and which could ultimately develop into a heater-cathode short circuit...

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Environmental radioactivity

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a density separation in a heavy liquid medium such as lithium sodium tungstate (LST). The sample is then dissolved, a common isotope carrier added (Be-9...

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Glossary of geology

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positive peaks shaded in a single dark colour. wolframite An iron manganese tungstate mineral with the chemical formula (Fe,Mn)WO4. Contents:  Top A B C D E...

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