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Metal halides information


Metal halides are compounds between metals and halogens. Some, such as sodium chloride are ionic, while others are covalently bonded. A few metal halides are discrete molecules, such as uranium hexafluoride, but most adopt polymeric structures, such as palladium chloride.[1][2]

  1. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 819–824. ISBN 978-0-08-037941-8.
  2. ^ Köhler, J. (2014). "Halides: Solid-State Chemistry". Encyclopedia of Inorganic and Bioinorganic Chemistry. pp. 1–22. doi:10.1002/9781119951438.eibc0078.pub2. ISBN 9781119951438.

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Metal halides

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metals to form metal halides according to the following equation: 2M + nX2 → 2MXn where M is the metal, X is the halogen, and MXn is the metal halide...

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Halide

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or I). Many salts are halides; the hal- syllable in halide and halite reflects this correlation. All Group 1 metals form halides that are white solids...

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Alkali metal halide

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Alkali metal halides, or alkali halides, are the family of inorganic compounds with the chemical formula MX, where M is an alkali metal and X is a halogen...

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Alkali metal

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the alkali metal halides. The reaction is very vigorous and can sometimes result in explosions.: 76  All twenty stable alkali metal halides are known;...

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Halogen

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the halogens have been observed to react with hydrogen to form hydrogen halides. For fluorine, chlorine, and bromine, this reaction is in the form of:...

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Silver halide

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silver metal speck. Silver halides are also used to make corrective lenses darken when exposed to ultraviolet light (see photochromism). Silver halides, except...

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Grow light

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(HPS/SON) and metal halide (MH) HID lights, but fluorescents and LEDs are replacing metal halides due to their efficiency and economy. Metal halide lights are...

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Metal cluster compound

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halides of the late transition metals, where metal-halide bonding is replete. Transition metal halide clusters are prevalent for the heavier metals:...

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Transition metal alkoxide complex

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that NaCl is insoluble in common organic solvents. For electrophilic metal halides, conversion to the alkoxide requires no or mild base. Titanium tetrachloride...

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LED lamp

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they require a 5–7-minute warmup period before they reach full output, metal-halides are not used for residential lighting, but for commercial and industrial...

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Marine aquarium

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the intensity, allowing metal halide lamps to penetrate light to even the very bottom levels of most aquariums. Metal halides are available in many color...

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Thallium halides

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in solution and when thallium(I) halides are incorporated into alkali metal halides. These doped alkali metal halides have new absorption and emission...

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Metal acetylacetonates

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complexes are soluble in organic solvents, in contrast to the related metal halides. Because of these properties, acac complexes are sometimes used as catalyst...

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Gold halide

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Gold halides are compounds of gold with the halogens. AuCl, AuBr, and AuI are all crystalline solids with a structure containing alternating linear chains:...

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Gallium halides

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There are three sets of gallium halides, the trihalides where gallium has oxidation state +3, the intermediate halides containing gallium in oxidation...

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Hydride

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NaOH}}} ΔH = −83.6 kJ/mol, ΔG = −109.0 kJ/mol Often alkali metal hydrides react with metal halides. Lithium aluminium hydride (often abbreviated as LAH) arises...

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Alkaline earth metal

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+ NaOH + 2H2O → Na[Be(OH)3] + H2 Reaction with alkyl halides Magnesium reacts with alkyl halides via an insertion reaction to generate Grignard reagents...

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Zinc chloride

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those used in the palladium catalyzed Negishi coupling with aryl halides or vinyl halides. In such cases the organozinc compound is usually prepared by transmetallation...

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Potassium chloride

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Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous...

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Graphite intercalation compound

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graphite with [O2]+[AsF6]− affords the salt [C8]+[AsF6]−. A number of metal halides intercalate into graphite. The chloride derivatives have been most extensively...

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Silver bromide

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known (along with other silver halides) for its unusual sensitivity to light. This property has allowed silver halides to become the basis of modern photographic...

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Aluminium chloride

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arene can be used to synthesize bis(arene) metal complexes, e.g. bis(benzene)chromium, from certain metal halides via the Fischer–Hafner synthesis. Dichlorophenylphosphine...

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