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Potassium bisulfite information


Potassium bisulfite
Names
IUPAC name
Potassium hydrogen sulfite
Other names
  • Potassium bisulfite
  • potassium bisulphite
  • monopotassium salt
  • monopotassium sulfite
  • potassium hydrosulfite
Identifiers
CAS Number
  • 7773-03-7 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 22889 ☒N
ECHA InfoCard 100.028.973 Edit this at Wikidata
EC Number
  • 231-870-1
E number E228 (preservatives)
PubChem CID
  • 23663620
UNII
  • QJK5LO891P ☒N
CompTox Dashboard (EPA)
  • DTXSID6064795 Edit this at Wikidata
InChI
  • InChI=1S/K.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-1
SMILES
  • OS(=O)[O-].[K+]
Properties
Chemical formula
KHSO3
Molar mass 120.1561 g/mol
Appearance White crystalline powder
Odor SO2-like
Melting point 190 °C (374 °F; 463 K) (decomposes)
Solubility in water
49 g/100mL (20 °C)
115 g/100mL (100 °C)
Solubility Insoluble in alcohol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Potassium bisulfite (or potassium hydrogen sulfite) is a chemical mixture with the approximate chemical formula KHSO3. Potassium bisulfite in fact is not a real compound,[1] but a mixture of salts that dissolve in water to give solutions composed of potassium ions and bisulfite ions. It is a white solid with an odor of sulfur dioxide. Attempts to crystallize potassium bisulfite yield potassium metabisulfite, K2S2O5.[2]

Potassium bisulfite is used as a sterilising agent in the production of alcoholic beverages.[3] This additive is classified as E number E228 under the current EU-approved food additive legislation.[4]

  1. ^ Tudela, David; Jenkins, H. Donald B. (2003). "New Methods to Estimate Lattice Energies: Application to the Relative Stabilities of Bisulfite (HSO3) and Metabisulfite (S2O52-) Salts". Journal of Chemical Education. 80 (12): 1482. Bibcode:2003JChEd..80.1482T. doi:10.1021/ed080p1482.
  2. ^ Johnstone, H. F. (1946). "Sulfites and Pyrosulfites of the Alkali Metals". Inorganic Syntheses. Inorganic Syntheses. Vol. 2. pp. 162–167. doi:10.1002/9780470132333.ch49. ISBN 9780470132333.
  3. ^ Barberá, José Jiménez; Metzger, Adolf; Wolf, Manfred (2000). "Sulfites, Thiosulfates, and Dithionitesl Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a25_477. ISBN 978-3527306732.
  4. ^ "Approved additives and E numbers". Food Standards Agency. Retrieved 2020-04-07.

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and potassium salts of bisulfite cannot be obtained. However, there are some reports of anhydrous bisulfites with large counter ions. Bisulfite is a...

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sulfite, but a closely related chemical oxide Potassium bisulfite or potassium metabisulfite Sodium bisulfite, sodium metabisulfite or sodium sulfite Sulfites...

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silvering of mirrors. Potassium bromate (KBrO3) is a strong oxidizer (E924), used to improve dough strength and rise height. Potassium bisulfite (KHSO3) is used...

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Conditioning Agents Potassium Sulfite, Sodium Sulfite(Anhydrous), Sodium Bisulfite, Sodium Hydrosulfite, Potassium Metabisulfite, Potassium Bisulfite, Sodium Metabisulfite...

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Potassium metabisulfite, K2S2O5, also known as potassium pyrosulfite, is a white crystalline powder with a pungent odour. It is mainly used as an antioxidant...

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Antichlor

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material that has been bleached. Antichlors include sodium bisulfite, potassium bisulfite, sodium metabisulfite, sodium thiosulfate, and hydrogen peroxide...

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of iodate ion (for instance potassium iodate) to which an acidified solution (again with sulfuric acid) of sodium bisulfite is added. In this protocol...

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International Numbering System for Food Additives

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antioxidant 227 E U calcium bisulfite, calcium hydrogen sulfite preservative, antioxidant 228 A E U potassium bisulfite, potassium hydrogen sulfite preservative...

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mineral salt Potassium bisulfite – preservative, antioxidant Potassium bromate – flour treatment agent Potassium carbonate – mineral salt Potassium chloride...

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Treacle

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of Sodium Sulfite, Potassium Sulfite, Ammonium Sulfite, Sodium Bisulfite, Ammonium Bisulfite, Sodium Metabisulfite and Potassium Metabisulfite, International...

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Potassium bisulfite – KHSO3 Potassium carbonate – K2CO3 Potassium calcium chloride – KCaCl3 Potassium chlorate – KClO3 Potassium chloride – KCl Potassium chlorite...

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Sodium metabisulfite

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respectively. Upon dissolution in water, bisulfite is generated: Na2S2O5 + H2O → 2 Na+ + 2 HSO3− Sodium and potassium metabisulfite have many major and niche...

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Glossary of chemical formulae

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13455-21-1 KOF potassium hypofluorite KH potassium hydride KHCO3 potassium bicarbonate 298-14-6 KHS potassium hydrosulfide KHSO3 potassium bisulfite 7773-03-7...

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Dough conditioner

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elasticity, reduced proofing time, and improved machinability. Cysteine and bisulfite are reducing agents which relax wheat dough. Adding minute amounts of...

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and bisulfite ions. These chemicals cleave the bonds between the cellulose and lignin components of the lignocellulose. A variety of sulfite/bisulfite salts...

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with bisulfite salts: SCl2 + 2 HSO−3 → [O3SSSO3]2− + 2 HCl S2Cl2 + 2 HSO−3 → [O3SS2SO3]2− + 2 HCl SCl2 + 2 HS2O−3 → [O3SS3SO3]2− + 2 HCl Potassium pentathionate...

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Stop bath

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bromocresol purple is used. Low-odor stop baths use citric acid or sodium bisulfite in place of acetic acid.[citation needed] Sowerby, A.L.M., ed. (1961)...

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Aldehyde

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employed. Aldehydes characteristically form "addition compounds" with bisulfites: RCHO + HSO−3 → RCH(OH)SO−3 This reaction is used as a test for aldehydes...

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+ H2O Although the equilibrium lies far to the left, evaporation of a bisulfite salt will produce a substantial amount of disulfite. Disulfite is the...

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Sodium sulfite

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oxidation by air. Sodium bisulfite, NaHSO3, is mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions. According to...

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compared to the normal hydrogen electrode. Redox occurs with formation of bisulfite: S2O42- + 2 H2O → 2 HSO3− + 2 e− + 2 H+ Sodium dithionite reacts with...

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sulfosuccinate can be obtained by treating dioctyl maleate with sodium bisulfite. The bisulfite anion adds to the double bond: −CH=CH− + HSO−3 → −CH(−SO−3)−CH2−...

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