Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Nverify (what is YN ?)
Infobox references
Chemical compound
Thionyl tetrafluoride, also known as sulfur tetrafluoride oxide, is an inorganic compound with the formula SOF4. It is a colorless gas.
The shape of the molecule is a distorted trigonal bipyramid, with the oxygen found on the equator. The atoms on the equator have shorter bond lengths than the fluorine atoms on the axis. The sulfur oxygen bond is 1.409Å. A S−F bond on the axis has length 1.596Å and the S−F bond on the equator has length 1.539Å. The angle between the equatorial fluorine atoms is 112.8°. The angle between axial fluorine and oxygen is 97.7°. The angle between oxygen and equatorial fluorine is 123.6° and between axial and equatorial fluorine is 85.7°.[2] The fluorine atoms only produce one NMR line, probably because they exchange positions.[1] It is isoelectronic with phosphorus pentafluoride.
^ abcdCite error: The named reference aiic was invoked but never defined (see the help page).
^Lise Hedberg and Kenneth Hedberg "Thionyl tetrafluoride. Reanalysis of the molecular structure and resolution of the multiple model problem" the Journal of Physical Chemistry March 1982 vol 86 page 598 doi 10.1021/j100394a004 [1]
and 28 Related for: Thionyl tetrafluoride information
Thionyltetrafluoride, also known as sulfur tetrafluoride oxide, is an inorganic compound with the formula SOF4. It is a colorless gas. The shape of the...
Xenon tetrafluoride is a chemical compound with chemical formula XeF 4. It was the first discovered binary compound of a noble gas. It is produced by...
result of electrical discharges which generate sulfur tetrafluoride. SF4 hydrolyzes to give thionyl fluoride, which in turn hydrolyzes further as described...
Tetrafluoromethane, also known as carbon tetrafluoride or R-14, is the simplest perfluorocarbon (CF4). As its IUPAC name indicates, tetrafluoromethane...
Sulfur tetrafluoride is a chemical compound with the formula SF4. It is a colorless corrosive gas that releases dangerous hydrogen fluoride gas upon exposure...
Silicon tetrafluoride or tetrafluorosilane is a chemical compound with the formula SiF4. This colorless gas is notable for having a narrow liquid range:...
Ronald D.; Engelhardt, Vaughn A. (February 1960). "Chemistry of Sulfur Tetrafluoride. III. Organoiminosulfur Difluorides". Journal of the American Chemical...
Eggers, D. F. (April 1956). "Pentafluorosulfur Hypofluorite and ThionylTetrafluoride". Journal of the American Chemical Society. 78 (8): 1553–1557. doi:10...
constant (Badger's rule). The molecule can be considered as sulfur tetrafluoride in which a sulfur atom is inserted into a S-F bond. Atoms are labelled...
Hafnium tetrafluoride is the inorganic compound with the formula HfF4. It is a white solid. It adopts the same structure as zirconium tetrafluoride, with...
such as thionyl chloride, SOCl2 and oxidation state +6, such as sulfuryl fluoride (SO2F2), sulfuryl chloride (SO2Cl2), and thionyltetrafluoride (SOF4)...
Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent...
Kirshenbaum, A. D.; Streng, A. G.; Streng, L. V. (15 March 1963). "Krypton Tetrafluoride: Preparation and Some Properties". Science. 139 (3559): 1047–1048. Bibcode:1963Sci...
Tellurium tetrafluoride, TeF4, is a stable, white, hygroscopic crystalline solid and is one of two fluorides of tellurium. The other binary fluoride is...
Diboron tetrafluoride is the inorganic compound with the formula (BF2)2. A colorless gas, the compound has a halflife of days at room temperature. It...
to give the heptafluorozirconate salt, which can be converted to the tetrafluoride at 500 °C: 2ZrO2 + 7 (NH4)HF2 → 2 (NH4)3ZrF7 + 4 H2O + NH3 (NH4)3ZrF7...
Germanium tetrafluoride (GeF4) is a chemical compound of germanium and fluorine. It is a colorless gas. Germanium tetrafluoride is formed by treating...
chlorides also entail the reaction of carboxylic acids with phosgene, thionyl chloride, and phosphorus trichloride Phosphorus pentabromide is used for...
sulfonic acids using thionyl chloride. Sulfonyl fluorides can be produced by treating sulfonic acids with sulfur tetrafluoride: SF4 + RSO3H → SOF2 +...
very hygroscopic. Unlike the corresponding vanadium tetrachloride, the tetrafluoride is not volatile because it adopts a polymeric structure. It decomposes...
reagents exist for and introducing halogens into diverse substrates, e.g. thionyl chloride. Several pathways exist for the halogenation of organic compounds...
with lithium hydroxide or lithium carbonate or by reacting silicon tetrafluoride with lithium fluoride. H2[SiF6] + 2LiOH → Li2[SiF6] + 2H2O Lithium hexafluorosilicate...
produced. Other metal fluorides are produced using HF, including uranium tetrafluoride. HF is the precursor to elemental fluorine, F2, by electrolysis of a...
oxide positions are disordered. A similar motif is adopted by titanium tetrafluoride. The compound can be obtained by thermal decomposition of the dioxotetrafluoride...
Global Information
verify (what is 
?)
