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Octet rule information


The bonding in carbon dioxide (CO2): all atoms are surrounded by 8 electrons, fulfilling the octet rule.

The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The rule is especially applicable to carbon, nitrogen, oxygen, and the halogens; although more generally the rule is applicable for the s-block and p-block of the periodic table. Other rules exist for other elements, such as the duplet rule for hydrogen and helium, and the 18-electron rule for transition metals.

The valence electrons can be counted using a Lewis electron dot diagram as shown at the right for carbon dioxide. The electrons shared by the two atoms in a covalent bond are counted twice, once for each atom. In carbon dioxide each oxygen shares four electrons with the central carbon, two (shown in red) from the oxygen itself and two (shown in black) from the carbon. All four of these electrons are counted in both the carbon octet and the oxygen octet, so that both atoms are considered to obey the octet rule.

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Octet rule

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The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons...

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Octet

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Look up octet in Wiktionary, the free dictionary. Octet may refer to: Octet (music), ensemble consisting of eight instruments or voices, or composition...

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Electron deficiency

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species that violate the octet rule because they have too few valence electrons and species that happen to follow the octet rule but have electron-acceptor...

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Hypervalent molecule

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(i.e. 3, 2, 1, 0 for Groups 15, 16, 17, 18 respectively, based on the octet rule). Several specific classes of hypervalent molecules exist: Hypervalent...

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Lewis structure

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electrons, then count up the number of electrons needed to complete the octet rule (or with hydrogen just 2 electrons), then take the difference of these...

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Electron counting

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predicting their electronic structure and bonding. Many rules in chemistry rely on electron-counting: Octet rule is used with Lewis structures for main group elements...

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Oxidation state

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papers about the octet rule. The periodicity of the oxidation states was one of the pieces of evidence that led Langmuir to adopt the rule. The oxidation...

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Cubical atom

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Lewis' theory was based on Abegg's rule. It was further developed in 1919 by Irving Langmuir as the cubical octet atom. The figure below shows structural...

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Chemistry

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each have eight electrons in their valence shell are said to follow the octet rule. However, some elements like hydrogen and lithium need only two electrons...

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Orbital hybridisation

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group elements are the one s and three p orbitals with the corresponding octet rule, spx hybridization is used to model the shape of these molecules. As the...

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Electron configuration

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stability. Main-group atoms generally obey the octet rule, while transition metals generally obey the 18-electron rule. The noble gases (He, Ne, Ar, Kr, Xe, Rn)...

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Valence electron

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rule, a main-group element (except hydrogen or helium) tends to react to form a s2p6 electron configuration. This tendency is called the octet rule,...

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Covalent bond

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valence of four and is, therefore, surrounded by eight electrons (the octet rule), four from the carbon itself and four from the hydrogens bonded to it...

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Chemical bond

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practice, simplified rules and other theories allow chemists to predict the strength, directionality, and polarity of bonds. The octet rule and VSEPR theory...

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Noble gas

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eight electrons. In 1916, Gilbert N. Lewis formulated the octet rule, which concluded an octet of electrons in the outer shell was the most stable arrangement...

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Electrophile

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agents such as organic peracids, chemical species that do not satisfy the octet rule such as carbenes and radicals, and some Lewis acids such as BH3 and DIBAL...

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8

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can occupy a valence shell (except for transitional elements), see the octet rule. The red pigment lycopene consists of eight isoprene units. A disphenoid...

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History of the periodic table

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electron configurations; from this notion emerged the octet rule originally referred to as Abegg's Rule of 1904. Among the notable works that established...

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Beryllium

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Such compounds obey the octet rule. Other 4-coordinate complexes, such as the aqua-ion [Be(H2O)4]2+ also obey the octet rule. Solutions of beryllium salts...

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Boron

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in its ground state. Unlike most other p-elements, it rarely obeys the octet rule and usually places only six electrons (in three molecular orbitals) onto...

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Richard Abegg

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theory of freezing-point depression and anticipated Gilbert Newton Lewis's octet rule by revealing that the lowest and highest oxidation states of elements...

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Jack Linnett

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originated a modification to the octet rule, originally proposed by Lewis, concerning valence electrons. He proposed that the octet should be considered as a...

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Period 2 element

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and neon) obey the octet rule in that they need eight electrons to complete their valence shell (lithium and beryllium obey duet rule, boron is electron...

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