Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Phosphorus mononitride is an inorganic compound with the chemical formula PN. Containing only phosphorus and nitrogen, this material is classified as a binary nitride. From the Lewis structure perspective, it can be represented with a P-N triple bond with a lone pair on each atom. It is isoelectronic with N2, CO, P2, CS and SiO.
The compound is highly unstable in standard conditions, tending to rapidly self polymerize. It can be isolated within argon and krypton matrices at 10 K (−263.1 °C).[1] Due to its instability, documentation of reactions with other molecules is limited.[2] Most of its reactivity has thus far been probed and studied at transition metal centers. [3][4]
Phosphorus mononitride was the first identified phosphorus compound in the interstellar medium[5] and is even thought to be an important molecule in the atmospheres of Jupiter and Saturn.[6][7]
^Atkins, Robert M.; Timms, Peter L. (1977). "The matrix infrared spectrum of PN and SiS". Spectrochimica Acta Part A: Molecular Spectroscopy. 33 (9): 853–857. Bibcode:1977AcSpA..33..853A. doi:10.1016/0584-8539(77)80083-4. ISSN 0584-8539.
^Qian, Weiyu; Wende, Raffael C.; Schreiner, Peter R.; Mardyukov, Artur (2023-04-18). "Selective Preparation of Phosphorus Mononitride (P≡N) from Phosphinoazide and Reversible Oxidation to Phosphinonitrene". Angewandte Chemie International Edition. 62 (23): e202300761. doi:10.1002/anie.202300761. ISSN 1433-7851. PMID 36877095.
^Martinez, Jorge L.; Lutz, Sean A.; Beagan, Daniel M.; Gao, Xinfeng; Pink, Maren; Chen, Chun-Hsing; Carta, Veronica; Moënne-Loccoz, Pierre; Smith, Jeremy M. (2020-09-01). "Stabilization of the Dinitrogen Analogue, Phosphorus Nitride". ACS Central Science. 6 (9): 1572–1577. doi:10.1021/acscentsci.0c00944. ISSN 2374-7943. PMC 7517109. PMID 32999932.
^Courtemanche, Marc-André; Transue, Wesley J.; Cummins, Christopher C. (2016-12-21). "Phosphinidene Reactivity of a Transient Vanadium P≡N Complex". Journal of the American Chemical Society. 138 (50): 16220–16223. doi:10.1021/jacs.6b10545. ISSN 0002-7863. PMID 27958729.
^Turner, B. E.; Bally, John (1987-10-01). "Detection of Interstellar PN: The First Identified Phosphorus Compound in the Interstellar Medium". The Astrophysical Journal. 321: L75. Bibcode:1987ApJ...321L..75T. doi:10.1086/185009. ISSN 0004-637X.
^Viana, Rommel B.; Pereira, Priscila S. S.; Macedo, Luiz G. M.; Pimentel, André S. (2009-09-18). "A quantum chemical study on the formation of phosphorus mononitride". Chemical Physics. 363 (1): 49–58. Bibcode:2009CP....363...49V. doi:10.1016/j.chemphys.2009.07.008. ISSN 0301-0104.
^Yung, Yuk L.; DeMore, William B. (1999-03-11), "Origins", Photochemistry of Planetary Atmospheres, Oxford University Press, doi:10.1093/oso/9780195105018.003.0007, ISBN 978-0-19-510501-8, retrieved 2023-11-28
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