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Hydroperoxyl information


Hydroperoxyl
Ball-and-stick model of the hydroperoxyl radical
Names
Preferred IUPAC name
Hydroperoxyl
Systematic IUPAC name
Dioxidanyl
Other names
Peroxyl radical, hydrogen superoxide, hydrogen dioxide
Identifiers
CAS Number
  • 3170-83-0 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:25935
ChemSpider
  • 454055 checkY
Gmelin Reference
506
PubChem CID
  • 520535
CompTox Dashboard (EPA)
  • DTXSID30894777 Edit this at Wikidata
InChI
  • InChI=1S/HO2/c1-2/h1H checkY
    Key: OUUQCZGPVNCOIJ-UHFFFAOYSA-N checkY
SMILES
  • [O]O
Properties
Chemical formula
HO2
Molar mass 33.006 g·mol−1
Acidity (pKa) 4.88[1]
Basicity (pKb) 9.12 (basicity of superoxide ion)
Conjugate base Superoxide anion
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

The hydroperoxyl radical, also known as the hydrogen superoxide, is the protonated form of superoxide with the chemical formula HO2, also written HOO. This species plays an important role in the atmosphere and as a reactive oxygen species in cell biology.[2]

  1. ^ Bielski, Benon H. J.; Cabelli, Diane E.; Arudi, Ravindra L.; Ross, Alberta B. (1985). "Reactivity of HO2/O
    2
    Radicals in Aqueous Solution". J. Phys. Chem. Ref. Data. 14 (4): 1041–1091. Bibcode:1985JPCRD..14.1041B. doi:10.1063/1.555739.
  2. ^ Heard, Dwayne E.; Pilling, Michael J. (2003). "Measurement of OH and HO2 in the Troposphere". Chemical Reviews. 103 (12): 5163–5198. doi:10.1021/cr020522s. PMID 14664647.

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base, initially forming the hydroperoxyl radical (HO2). The superoxide anion, O−2, and its protonated form, hydroperoxyl, are in equilibrium in an aqueous...

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polyoxides. The compound is prepared by a chemical reaction between hydroperoxyl radicals (HO2•) at low temperatures: 2 H O 2 ∙ → 2 H 2 O 4 {\displaystyle...

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refers to the hydroperoxide anion (−OOH) and its salts, and the neutral hydroperoxyl radical (•OOH) consist of an unbond hydroperoxy group. When R is organic...

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Ferrous

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Molecule

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