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Methanethiol information


Methanethiol
Methanethiol
Ball-and-stick model of the methanethiol molecule
Ball-and-stick model of the methanethiol molecule
Space-filling model of the methanethiol molecule
Space-filling model of the methanethiol molecule
Names
Preferred IUPAC name
Methanethiol
Other names
Methyl mercaptan
Mercaptomethane
Methiol
Thiomethyl alcohol/Thiomethanol
Methylthiol
Identifiers
CAS Number
  • 74-93-1 checkY
3D model (JSmol)
  • Interactive image
3DMet
  • B00105
ChEBI
  • CHEBI:16007 checkY
ChemSpider
  • 855 checkY[chemspiders]
ECHA InfoCard 100.000.748 Edit this at Wikidata
EC Number
  • 200-822-1
KEGG
  • C00409 checkY
PubChem CID
  • 878
RTECS number
  • PB4375000
UNII
  • 2X8406WW9I checkY
UN number 1064
CompTox Dashboard (EPA)
  • DTXSID5026382
InChI
  • InChI=1S/CH3SH/c1-2/h2H,1H3 ☒N
    Key: LSDPWZHWYPCBBB-UHFFFAOYSA-N checkY
  • InChI=1/CH3SH/c1-2/h2H,1H3
    Key: LSDPWZHWYPCBBB-UHFFFAOYAW
SMILES
  • SC
Properties
Chemical formula
CH3SH
Molar mass 48.11 g·mol−1
Appearance colorless gas[1]
Odor Distinctive, like that of rotten cabbage or eggs
Density 0.9 g/mL (liquid at 0°C)[1]
Melting point −123 °C (−189 °F; 150 K)
Boiling point 5.95 °C (42.71 °F; 279.10 K)
Solubility in water
2%
Solubility alcohol, ether
Vapor pressure 1.7 atm (20°C)[1]
Acidity (pKa) ~10.4
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H220, H331, H410
Precautionary statements
P210, P261, P271, P273, P304+P340, P311, P321, P377, P381, P391, P403, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
4
4
1
Flash point −18 °C; 0 °F; 255 K[1]
Autoignition
temperature
364 °C; 687 °F; 637 K[3]
Explosive limits 3.9%-21.8%[1]
Lethal dose or concentration (LD, LC):
LD50 (median dose)
60.67 mg/kg (mammal)[2]
LC50 (median concentration)
3.3 ppm (mouse, 2 hr)
675 ppm (rat, 4 hr)[2]
NIOSH (US health exposure limits):
PEL (Permissible)
C 10 ppm (20 mg/m3)[1]
REL (Recommended)
C 0.5 ppm (1 mg/m3) [15-minute][1]
IDLH (Immediate danger)
150 ppm[1]
Related compounds
Related compounds
Ethanethiol

Hydrogen sulfide

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Methanethiol /ˌmɛθ.n.ˈθ.ɒl/ (also known as methyl mercaptan) is an organosulfur compound with the chemical formula CH
3
SH
. It is a colorless gas with a distinctive putrid smell. It is a natural substance found in the blood, brain and feces of animals (including humans), as well as in plant tissues. It also occurs naturally in certain foods, such as some nuts and cheese. It is one of the chemical compounds responsible for bad breath and the smell of flatus. Methanethiol is the simplest thiol and is sometimes abbreviated as MeSH. It is very flammable.

  1. ^ a b c d e f g h NIOSH Pocket Guide to Chemical Hazards. "#0425". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ a b "Methyl mercaptan". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  3. ^ "Sigma Aldrich Methanethiol SDS". Sigma Aldrich. Millipore Sigma. Retrieved Nov 1, 2022.

and 26 Related for: Methanethiol information

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Methanethiol

Last Update:

Methanethiol /ˌmɛθ.eɪn.ˈθaɪ.ɒl/ (also known as methyl mercaptan) is an organosulfur compound with the chemical formula CH 3SH. It is a colorless gas with...

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Methionine

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derived from aspartic acid, while the sulfur may come from cysteine, methanethiol, or hydrogen sulfide. First, aspartic acid is converted via β-aspartyl...

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Dimethyl sulfide

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dimethylsulfoniopropionate (DMSP), and is also produced by the bacterial metabolism of methanethiol. DMS originates primarily from DMSP, a major secondary metabolite in...

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Sodium methanethiolate

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sodium thiomethoxide (CH3SNa, MeSNa) is the sodium conjugate base of methanethiol. This compound is commercially available as a white solid. It is a powerful...

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Methanethiol oxidase

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In enzymology, a methanethiol oxidase (EC 1.8.3.4) is an enzyme that catalyzes the chemical reaction methanethiol + O2 + H2O ⇌ {\displaystyle \rightleftharpoons...

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Thiol

Last Update:

identical to naming an alcohol and is used by the IUPAC, e.g. CH3SH would be methanethiol. The word mercaptan replaces alcohol in the name of the equivalent alcohol...

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Aroma compound

Last Update:

mercaptan; CH2=CHCH2SH) (garlic volatiles and garlic breath) (Methylthio)methanethiol (CH3SCH2SH), the "mouse thiol", found in mouse urine and functions as...

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Dimethylsulfoniopropionate

Last Update:

bacteria convert methanethiol to DMS.[citation needed] DMS is also taken up by marine bacteria, but not as rapidly as methanethiol. Although DMS usually...

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Structural analog

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consumption. Alcohols Methanol Silanol, a structural analog of methanol Methanethiol, a structural analog of methanol Phenethylamines Phenethylamine Amphetamine...

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Human feces

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from the following odorant volatiles: Methyl sulfides methylmercaptan/methanethiol (MM) dimethyl sulfide (DMS) dimethyl disulfide (DMDS) dimethyl trisulfide...

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Allyl methyl sulfide

Last Update:

prepared by the reaction of allyl chloride with sodium hydroxide and methanethiol. CH2=CHCH2Cl + NaOH (aq) + CH3SH → CH2=CHCH2SCH3 + NaCl + H2O Eric Block...

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Sulfide

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descriptor for such SH-containing compounds is thiol or mercaptan, i.e. methanethiol, or methyl mercaptan. Confusion arises from the different meanings of...

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Hydrogen peroxide

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E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Ethanol

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E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Water

Last Update:

E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Flatulence

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sulfur compounds. Hydrogen sulfide, methyl mercaptan (also known as methanethiol), dimethyl sulfide, dimethyl disulfide and dimethyl trisulfide are present...

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Asparagus

Last Update:

Some of the volatile organic compounds responsible for the smell are: methanethiol dimethyl sulfide dimethyl disulfide bis(methylthio)methane dimethyl sulfoxide...

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Potassium chloride

Last Update:

E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Organic compound

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E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Methaneselenol

Last Update:

1995 (E = Te), 2606 (E = S), and 3710 cm−1 (E = O) for methanetellurol, methanethiol, and methanol. Zeng, Huawei; Wu, Min; Botnen, James H. (2009). "Methylselenol...

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Methyl group

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E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Carbon dioxide

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E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Dimethyl disulfide

Last Update:

help pollinate this plant. DMDS can be produced by the oxidation of methanethiol, e.g. with iodine: 2 CH3SH + I2 → CH3SSCH3 + 2 HI Important reactions...

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Stink bomb

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release the stink. Some common components are: Organosulfur compounds Methanethiol (used rarely; it is a gas and therefore more difficult to handle than...

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Molecule

Last Update:

E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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Ammonia

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E-Cyanomethanimine Cyclopropenone Diacetylene Ethylene Formamide HC4N Ketenimine Methanethiol Methanol Methyl isocyanide Pentynylidyne Propynal Protonated cyanoacetylene...

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