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Methenium information


Methenium
Names
Preferred IUPAC name
Methylium[1]
Other names
Methyl cation; Carbanylium
Identifiers
CAS Number
  • 14531-53-4 checkY
3D model (JSmol)
  • Interactive image
Beilstein Reference
1839325
ChEBI
  • CHEBI:29437
ChemSpider
  • 559136
Gmelin Reference
48893
PubChem CID
  • 644094
UNII
  • IM9JMM7N0Y checkY
CompTox Dashboard (EPA)
  • DTXSID301319120
InChI
  • InChI=1S/CH3/h1H3/q+1
    Key: JUHDUIDUEUEQND-UHFFFAOYSA-N
SMILES
  • [CH3+]
Properties
Chemical formula
CH3+
Molar mass 15.034 g·mol−1
Related compounds
Related isoelectronic
borane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

In organic chemistry, methenium (also called methylium, carbenium,[2] methyl cation, or protonated methylene) is a cation with the formula CH+
3
. It can be viewed as a methylene radical (:CH
2
) with an added proton (H+
), or as a methyl radical (•CH
3
) with one electron removed. It is a carbocation and an enium ion, making it the simplest of the carbenium ions.[3]

  1. ^ International Union of Pure and Applied Chemistry (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. The Royal Society of Chemistry. p. 1089. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
  2. ^ "Ions, Free Radicals, and Radical-Ion", Nomenclature of Organic Compounds, Advances in Chemistry, vol. 126, AMERICAN CHEMICAL SOCIETY, June 1974, pp. 216–224, doi:10.1021/ba-1974-0126.ch028, ISBN 978-0841201910
  3. ^ Cite error: The named reference Golob was invoked but never defined (see the help page).

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Methenium

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In organic chemistry, methenium (also called methylium, carbenium, methyl cation, or protonated methylene) is a cation with the formula CH+ 3. It can...

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Onium ion

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diphenylcarbenium, (C6H5)2CH+ (di-substituted methenium) triphenylcarbenium, (C6H5)3C+ (tri-substituted methenium) carbynium ions (protonated carbynes) have...

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CH3

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CH3 may refer to: Channel 3 (band) Channel 3 (Thai television network) Methenium (methyl cation) Methyl group (in chemistry) Methyl radical (in chemistry)...

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Methane

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mostly as unstable species in low-pressure gas mixtures. These include methenium or methyl cation CH+3, methane cation CH+4, and methanium or protonated...

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Carbocation

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a positively charged carbon atom. Among the simplest examples are the methenium CH+ 3, methanium CH+ 5 and vinyl C 2H+ 3 cations. Occasionally, carbocations...

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Methanium

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34–46. Bibcode:2017CPL...672...34S. doi:10.1016/j.cplett.2017.01.045. Methenium Ammonium Ethanium Chemistry, International Union of Pure and Applied (2009)...

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Methyl radical

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quite corrosive to metals. Its first ionization potential (yielding the methenium ion, CH+ 3) is 9.837±0.005 eV. The carbon centre in methyl can bond with...

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Radical anion

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radical species. For example, the methanol radical cation fragments into a methenium cation CH3+ and a hydroxyl radical. In naphthalene the unfragmented radical...

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Carbenium ion

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or 3. (Ions with zero carbons attached to the ionized carbon, such as methenium, CH+ 3, are usually included in the primary class). Stability typically...

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adults during a Phase 2 trial. Astronomers detect, for the first time, methenium, CH3+ (and/or carbon cation, C+), basic ingredients of life as we know...

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Trifluoromethyl cation

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fluorine atoms as substituents in place of its hydrogen atoms. Compared to methenium (the simplest carbenium ion), trifluoromethyl cation is more stable due...

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Ethanium

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pressure (about 2 mmHg). The electron beam first creates methanium and methenium ions. The former rapidly transfer their proton to ethane: CH+ 5 + C 2H...

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