Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties. Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures.[4]
^Fomon, S. (1920). Medicine and the Allied Sciences. D. Appleton. p. 148.
^ ab"Safety (MSDS) data for perchloric acid, 70%". msds.chem.ox.ac.uk. 2 July 2008. Archived from the original on 2 July 2008. Retrieved 24 February 2022.
^Trummal, Aleksander; Lipping, Lauri; Kaljurand, Ivari; Koppel, Ilmar A.; Leito, Ivo (6 May 2016). "Acidity of Strong Acids in Water and Dimethyl Sulfoxide". The Journal of Physical Chemistry A. 120 (20). American Chemical Society (ACS): 3663–3669. Bibcode:2016JPCA..120.3663T. doi:10.1021/acs.jpca.6b02253. ISSN 1089-5639. PMID 27115918. S2CID 29697201.
^"Perchloric Acid | Environmental Health & Safety | Michigan State University". ehs.msu.edu. Retrieved 2023-11-02.
Perchloricacid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric...
acid (HNO3); these are also known as bench acids. Mineral acids range from superacids (such as perchloricacid) to very weak ones (such as boric acid)...
These include nitric acid, perchloricacid, chloric acid, chromic acid, and concentrated sulfuric acid, among others. Oxidizing acids, being strong oxidizing...
chlorine oxide is the anhydride of perchloricacid. It is produced by the careful distillation of perchloricacid in the presence of the dehydrating agent...
chloride and dioxygen. It crystallizes in the rhombic crystal system. Perchloricacid is made by treating NaClO4 with HCl. Ammonium perchlorate and potassium...
with a base. Perbromic acid is unstable and cannot be formed by displacement of chlorine from perchloricacid, as periodic acid is prepared; it can only...
ether. It is a strong acid with a weakly coordinating, non-oxidizing conjugate base. It is structurally similar to perchloricacid, but lacks the hazards...
Sulfamic acid, also known as amidosulfonic acid, amidosulfuric acid, aminosulfonic acid, sulphamic acid and sulfamidic acid, is a molecular compound with...
Chlorine forms four oxoacids: hypochlorous acid (HOCl), chlorous acid (HOClO), chloric acid (HOClO2), and perchloricacid (HOClO3). As can be seen from the redox...
"superacid" was first used in 1927 when James Bryant Conant found that perchloricacid could protonate ketones and aldehydes to form salts in nonaqueous solution...
acetic acid of a very strong acid, such as perchloricacid. Acetic acid injection into a tumor has been used to treat cancer since the 1800s. Acetic acid is...
perchloricacid (HClO4), aqueous hydrochloric acid (HCl) and aqueous nitric acid (HNO3) are all completely ionized, and are all equally strong acids....
compound containing the perchlorate ion, ClO−4, the conjugate base of perchloricacid (ionic perchlorate). As counterions, there can be metal cations, quaternary...
of hypochlorous acid for disinfection purposes. Dichlorine monoxide: the corresponding acidic oxide Hypofluorous acidPerchloricacid Harris, Daniel C...
good yield by treating furfural with a mixture of hydrazoic acid (HN3) and perchloricacid (HClO4) in the presence of magnesium perchlorate in the benzene...
than previously known single-component strong acids like triflic acid or perchloricacid. In certain cases, like the nearly perhalogenated derivatives mentioned...
needs of different laboratory practices, ranging from the handling of perchloricacid and radionuclides to tall floor-mounted models and models equipped...
assumed to be adopt a tetrahedral structure akin to that for perchloricacid. As a strong acid, HMnO4 is deprotonated to form the intensely purple coloured...
employed in Diels–Alder reactions, where it is proposed that the Lewis acidic Li+ binds to Lewis basic sites on the dienophile, thereby accelerating the...
and Determination of the Alkali Metals Using PerchloricAcid. V. PerchloricAcid and Chloroplatinic Acid in the Determination of Small Amounts of Potassium...
ClO−4. Hydronium perchlorate is produced by the reaction of anhydrous perchloricacid and water in a 1:1 molar ratio: HClO4 + H2O → [H3O]+ClO−4 A more analytically...
well. A small amount of sulfuric acid can be used as a catalyst, but often also perchloricacid. However, acetic acid is usually also formed as a by-product...