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Perchloric acid information


Perchloric acid
Perchloric acid Hydroxidotrioxidochlorine
Perchloric acid
Hydroxidotrioxidochlorine
Perchloric acid ydroxidotrioxidochlorine
Perchloric acid
ydroxidotrioxidochlorine
Names
Systematic IUPAC name
Perchloric acid
Other names
Hyperchloric acid[1]
Identifiers
CAS Number
  • 7601-90-3 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:29221 checkY
ChEMBL
  • ChEMBL1161634 checkY
ChemSpider
  • 22669 checkY
ECHA InfoCard 100.028.648 Edit this at Wikidata
EC Number
  • 231-512-4
PubChem CID
  • 24247
RTECS number
  • SC7500000
UNII
  • V561V90BG2 checkY
UN number 1873
CompTox Dashboard (EPA)
  • DTXSID8047004 Edit this at Wikidata
InChI
  • InChI=1S/ClHO4/c2-1(3,4)5/h(H,2,3,4,5) checkY
    Key: VLTRZXGMWDSKGL-UHFFFAOYSA-N checkY
  • InChI=1/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)
    Key: VLTRZXGMWDSKGL-UHFFFAOYAD
SMILES
  • O[Cl+3]([O-])([O-])[O-]
Properties
Chemical formula
HClO4
Molar mass 100.46 g/mol
Appearance colorless liquid
Odor odorless
Density 1.768 g/cm3
Melting point −17 °C (1 °F; 256 K) (72% aqueous solution)[2]
−112 °C (anhydrous)
Boiling point 203 °C (397 °F; 476 K) (azeotrope)[2]
Solubility in water
Miscible
Acidity (pKa) −15.2 (±2.0);[3] ≈ −10
Conjugate base Perchlorate
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Powerful oxidizer, highly corrosive
GHS labelling:
Pictograms
GHS03: Oxidizing GHS05: Corrosive GHS07: Exclamation mark GHS08: Health hazard
Signal word
Danger
Hazard statements
H271, H290, H302, H314, H373
Precautionary statements
P210, P280, P303+P361+P353, P304+P340, P305+P351+P338, P310, P371, P375, P380
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
3
0
3
OX
Flash point Non-flammable
Safety data sheet (SDS) ICSC 1006
Related compounds
Related compounds
Hydrochloric acid
Hypochlorous acid
Chlorous acid
Chloric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties. Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures.[4]

  1. ^ Fomon, S. (1920). Medicine and the Allied Sciences. D. Appleton. p. 148.
  2. ^ a b "Safety (MSDS) data for perchloric acid, 70%". msds.chem.ox.ac.uk. 2 July 2008. Archived from the original on 2 July 2008. Retrieved 24 February 2022.
  3. ^ Trummal, Aleksander; Lipping, Lauri; Kaljurand, Ivari; Koppel, Ilmar A.; Leito, Ivo (6 May 2016). "Acidity of Strong Acids in Water and Dimethyl Sulfoxide". The Journal of Physical Chemistry A. 120 (20). American Chemical Society (ACS): 3663–3669. Bibcode:2016JPCA..120.3663T. doi:10.1021/acs.jpca.6b02253. ISSN 1089-5639. PMID 27115918. S2CID 29697201.
  4. ^ "Perchloric Acid | Environmental Health & Safety | Michigan State University". ehs.msu.edu. Retrieved 2023-11-02.

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Perchloric acid

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Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric...

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Mineral acid

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acid (HNO3); these are also known as bench acids. Mineral acids range from superacids (such as perchloric acid) to very weak ones (such as boric acid)...

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Acid strength

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strong acids are hydrochloric acid ( HCl ) {\displaystyle {\ce {(HCl)}}} , perchloric acid ( HClO 4 ) {\displaystyle {\ce {(HClO4)}}} , nitric acid ( HNO...

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Oxidizing acid

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These include nitric acid, perchloric acid, chloric acid, chromic acid, and concentrated sulfuric acid, among others. Oxidizing acids, being strong oxidizing...

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Dichlorine heptoxide

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chlorine oxide is the anhydride of perchloric acid. It is produced by the careful distillation of perchloric acid in the presence of the dehydrating agent...

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Sodium perchlorate

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chloride and dioxygen. It crystallizes in the rhombic crystal system. Perchloric acid is made by treating NaClO4 with HCl. Ammonium perchlorate and potassium...

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Perbromic acid

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with a base. Perbromic acid is unstable and cannot be formed by displacement of chlorine from perchloric acid, as periodic acid is prepared; it can only...

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Fluoroboric acid

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ether. It is a strong acid with a weakly coordinating, non-oxidizing conjugate base. It is structurally similar to perchloric acid, but lacks the hazards...

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Sulfamic acid

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Sulfamic acid, also known as amidosulfonic acid, amidosulfuric acid, aminosulfonic acid, sulphamic acid and sulfamidic acid, is a molecular compound with...

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Chlorine

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Chlorine forms four oxoacids: hypochlorous acid (HOCl), chlorous acid (HOClO), chloric acid (HOClO2), and perchloric acid (HOClO3). As can be seen from the redox...

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Chloric acid

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hypochlorous acid, producing chloric acid and hydrogen chloride: 3 HClO → HClO3 + 2 HCl Chlorate Hypochlorous acid Chlorous acid Perchloric acid Oxidizing acid Dichlorine...

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Chlorine acid

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Chlorine acid can refer to: Hydrochloric acid, HCl Hypochlorous acid, HClO Chlorous acid, HClO2 Chloric acid, HClO3 Perchloric acid, HClO4 Chlorine acids Molecular...

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Magic acid

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"superacid" was first used in 1927 when James Bryant Conant found that perchloric acid could protonate ketones and aldehydes to form salts in nonaqueous solution...

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Oxyacid

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phosphorous acid P(OH)3 exists almost entirely as phosphonic acid HP(=O)(OH)2). Nevertheless, perchloric acid (HClO4), sulfuric acid (H2SO4), and nitric acid (HNO3)...

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Acetic acid

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acetic acid of a very strong acid, such as perchloric acid. Acetic acid injection into a tumor has been used to treat cancer since the 1800s. Acetic acid is...

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Fluoroantimonic acid

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> H0 > −28) Magic acid (H0 = −23) Carborane acid (H0 < −18) Fluorosulfuric acid (H0 = −15) Triflic acid (H0 = −15) Perchloric acid (H0 = −13) Of the above...

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Leveling effect

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perchloric acid (HClO4), aqueous hydrochloric acid (HCl) and aqueous nitric acid (HNO3) are all completely ionized, and are all equally strong acids....

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Perchlorate

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compound containing the perchlorate ion, ClO−4, the conjugate base of perchloric acid (ionic perchlorate). As counterions, there can be metal cations, quaternary...

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Acid

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are hydrochloric acid (HCl), hydroiodic acid (HI), hydrobromic acid (HBr), perchloric acid (HClO4), nitric acid (HNO3) and sulfuric acid (H2SO4). In water...

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Superacid

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9) Oleum (SO3:H2SO4, H0 = −14.5) Perchloric acid (HClO4, H0 = −13) Sulfuric acid (H2SO4, H0 = −11.9) Superbase Acid dissociation constant Hall NF, Conant...

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Hypochlorous acid

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of hypochlorous acid for disinfection purposes. Dichlorine monoxide: the corresponding acidic oxide Hypofluorous acid Perchloric acid Harris, Daniel C...

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Hydrazoic acid

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good yield by treating furfural with a mixture of hydrazoic acid (HN3) and perchloric acid (HClO4) in the presence of magnesium perchlorate in the benzene...

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Carborane acid

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than previously known single-component strong acids like triflic acid or perchloric acid. In certain cases, like the nearly perhalogenated derivatives mentioned...

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Fume hood

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needs of different laboratory practices, ranging from the handling of perchloric acid and radionuclides to tall floor-mounted models and models equipped...

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Permanganic acid

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assumed to be adopt a tetrahedral structure akin to that for perchloric acid. As a strong acid, HMnO4 is deprotonated to form the intensely purple coloured...

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Lithium perchlorate

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employed in Diels–Alder reactions, where it is proposed that the Lewis acidic Li+ binds to Lewis basic sites on the dienophile, thereby accelerating the...

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Chloroplatinic acid

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and Determination of the Alkali Metals Using Perchloric Acid. V. Perchloric Acid and Chloroplatinic Acid in the Determination of Small Amounts of Potassium...

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Hydronium perchlorate

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ClO−4. Hydronium perchlorate is produced by the reaction of anhydrous perchloric acid and water in a 1:1 molar ratio: HClO4 + H2O → [H3O]+ClO−4 A more analytically...

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Cellulose acetate

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well. A small amount of sulfuric acid can be used as a catalyst, but often also perchloric acid. However, acetic acid is usually also formed as a by-product...

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