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Permanganic acid information


Permanganic acid
Permanganic acid
Names
IUPAC name
Permanganic acid
Other names
Manganic(VII) acid
Hydroxy(trioxo)manganese
Hydrogen permanganate
Identifiers
CAS Number
  • 13465-41-3
  • 24653-70-1 (dihydrate)
3D model (JSmol)
  • Interactive image
ChemSpider
  • 374116
ECHA InfoCard 100.033.346 Edit this at Wikidata
EC Number
  • 236-695-4
PubChem CID
  • 422689
CompTox Dashboard (EPA)
  • DTXSID40920531 Edit this at Wikidata
InChI
  • InChI=1S/Mn.H2O.3O/h;1H2;;;/q+1;;;;/p-1
    Key: ZJBYBXHCMWGGRR-UHFFFAOYSA-M
SMILES
  • O=[Mn](=O)(=O)O
Properties
Chemical formula
HMnO4
Molar mass 119.94 g mol−1
Appearance Violet
Acidity (pKa) about -4.6 to -2.3 [1][2]
Conjugate base Permanganate
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Oxidant, Corrosive
Related compounds
Other cations
Potassium permanganate
Sodium permanganate
Calcium permanganate
Related compounds
Pertechnetic acid
Perrhenic acid
Perchloric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Permanganic acid (or manganic(VII) acid) is the inorganic compound with the formula HMnO4. This strong oxoacid has been isolated as its dihydrate. It is the conjugate acid of permanganate salts. It is the subject of few publications and its characterization as well as its uses are very limited.

  1. ^ Stewart, R.; Mocek, M.M. (1963). "The Mechanisms of Permanganate Oxidation VII: The Oxidation of Fluoral Hydrate". Canadian Journal of Chemistry. 41 (5): 1160–9. doi:10.1139/v63-164.
  2. ^ Bailey, N.; Carrington, A.; Lott, K.A.K.; Symons, M.C.R (1960). "Structure and Reactivity of the Oxyanions of Transition Metals Part VII: Acidities and Spectra of Protonated Oxyanions". Journal of the Chemical Society (Resumed): 290–7. doi:10.1039/JR9600000290.

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Permanganic acid

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Permanganic acid (or manganic(VII) acid) is the inorganic compound with the formula HMnO4. This strong oxoacid has been isolated as its dihydrate. It...

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organic compound. It was first described in 1860. It is the acid anhydride of permanganic acid. The crystalline form of this chemical compound is dark green...

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with water forming nitric acid: N2O5 + H2O → 2 HNO3 Manganese heptoxide, which reacts with water forming permanganic acid: Mn2O7 + H2O → 2 HMnO4 Aluminium...

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two forms: orthoperiodic acid, with the chemical formula H5IO6, and metaperiodic acid, which has the formula HIO4. Periodic acid was discovered by Heinrich...

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compound with the manganate(VII) ion, MnO− 4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII)...

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the century Morse published a series of papers on the preparation of permanganic acid. This led him to study osmotic pressure. In the first half of the 20th...

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impurities play a role in the mechanism. Permanganic acid can be prepared by the reaction of dilute sulfuric acid with a solution barium permanganate, the...

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Pertechnetic acid

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reacting Tc metal or TcO2 with strong oxidizing acids, such as nitric acid, mixture of concentrated sulfuric acid with hydrogen peroxide or aqua regia. The...

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is no longer produced on an industrial scale. Olsen, J. C. (1900). Permanganic Acid by Electrolysys. Easton, PA: The Chemical Publishing Company. Garry...

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acid is the chemical compound with the formula Re2O7(H2O)2. It is obtained by evaporating aqueous solutions of Re2O7. Conventionally, perrhenic acid is...

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