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Partial oxidation information


Partial oxidation (POX) is a type of chemical reaction. It occurs when a substoichiometric fuel-air mixture is partially combusted in a reformer, creating a hydrogen-rich syngas which can then be put to further use, for example in a fuel cell. A distinction is made between thermal partial oxidation (TPOX) and catalytic partial oxidation (CPOX).

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Partial oxidation

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Partial oxidation (POX) is a type of chemical reaction. It occurs when a substoichiometric fuel-air mixture is partially combusted in a reformer, creating...

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Methane reformer

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reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen...

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Hydrogen

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dominate commercially: steam reforming often coupled to water-gas shift, partial oxidation of hydrocarbons, and water electrolysis. Hydrogen is mainly produced...

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Redox

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reduction–oxidation or oxidation–reduction: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the...

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Steam reforming

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can essentially be performed at a net enthalpy of zero (ΔH = 0). Partial oxidation (POX) occurs when a sub-stoichiometric fuel-air mixture is partially...

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Industrial catalysts

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distribution and the effect of oxygen partial pressure. Combined reforming is a combination of partial oxidation and steam reforming and is the last reaction...

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Alcohol oxidation

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Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters...

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Gallic acid

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It is a white solid, although samples are typically brown owing to partial oxidation. Salts and esters of gallic acid are termed "gallates". Its name is...

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Hydrogen production

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partial oxidation reaction occurs when a substoichiometric fuel-air mixture or fuel-oxygen is partially combusted in a reformer or partial oxidation reactor...

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Acetaldehyde

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ripe fruit, and is produced by plants. It is also produced by the partial oxidation of ethanol by the liver enzyme alcohol dehydrogenase and is a contributing...

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Oxide

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Important and prevalent nonmetal oxides are carbon dioxide and carbon monoxide. These species form upon full or partial oxidation of carbon or hydrocarbons....

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Catalytic reforming

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K; Degenstein, N; Schmidt, L (2006-08-15). "Syngas by catalytic partial oxidation of methane on rhodium: Mechanistic conclusions from spatially resolved...

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Syngas

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rebuilt to run on wood gas). Syngas is produced by steam reforming or partial oxidation of natural gas or liquid hydrocarbons, or coal gasification. C + H2O...

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Carbon monoxide

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source for carbon monoxide. Carbon monoxide is produced from the partial oxidation of carbon-containing compounds; it forms when there is not enough...

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Allam power cycle

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MILES; ALLAM, RODNEY JOHN; FETVEDT, JEREMY ERON US20130205746A1 Partial oxidation reaction with closed cycle quench 2013-02-11 2013-08-15 PALMER LABS...

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Formaldehyde

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formaldehyde also entail oxidation of methanol or methyl iodide. Formaldehyde is produced industrially by the catalytic oxidation of methanol. The most common...

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Catalytic oxidation

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sulfur trioxide which is obtained by oxidation of sulfur dioxide. Food-grade phosphates are generated via oxidation of white phosphorus. Carbon monoxide...

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Membrane reactor

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oxygen from air, to methanol by the partial oxidation 2CH4 + O2 → {\displaystyle \rightarrow } 2CH3OH. The partial pressure of oxygen has to be low to...

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Sodium benzoate

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benzoic acid (C6H5COOH), which is itself produced commercially by partial oxidation of toluene with oxygen. Sodium benzoate can be decarboxylated with...

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Hydrocarbon

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{H}}_{2n+2}+\left({{3n+1} \over 2}\right){\ce {O2->}}n{\ce {CO2}}+(n+1){\ce {H2O}}} Partial oxidation characterizes the reactions of alkenes and oxygen. This process is...

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Phenol

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is the cumene process, also called Hock process. It involves the partial oxidation of cumene (isopropylbenzene) via the Hock rearrangement: Compared...

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Glossary of fuel cell terms

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the catalyst. Catalytic partial oxidation In catalytic partial oxidation (CPOX) the use of a catalyst for partial oxidation reduces the required temperature...

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Oxidative coupling

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1016/S0040-4039(00)88151-4. Zhang, Q. (2003). "Recent Progress in Direct Partial Oxidation of Methane to Methanol". J. Natural Gas Chem. 12: 81–89. Olah, G....

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Shilov system

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bond activation and oxidation which preferentially activates stronger C-H bonds over weaker C-H bonds for an overall partial oxidation. The Shilov system...

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Combustion

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matter and gases. Partially oxidized compounds are also a concern; partial oxidation of ethanol can produce harmful acetaldehyde, and carbon can produce...

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Gas to liquids

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process, methane (main component of natural gas) may be subjected to partial oxidation which yields a raw synthesis gas mixture of mostly carbon dioxide...

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Hydrogen sulfide

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elemental sulfur. This conversion, called the Claus process, involves partial oxidation to sulfur dioxide. The latter reacts with hydrogen sulfide to give...

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Dehydrogenation

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Shih-Hung (2005-05-10). "Nanocluster iron oxide-silica aerogel catalysts for methanol partial oxidation". Applied Catalysis A: General. 285 (1): 196–204...

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