Oxidative coupling in chemistry is a coupling reaction of two molecular entities through an oxidative process. Usually oxidative couplings are catalysed by a transition metal complex like in classical cross-coupling reactions, although the underlying mechanism is different due to the oxidation process that requires an external (or internal) oxidant.[1][2] Many such couplings utilize dioxygen as the stoichiometric oxidant but proceed by electron transfer.[3]
^Ignacio Funes-Ardoiz; Feliu Maseras (2018). "Oxidative Coupling Mechanisms: Current State of Understanding". ACS Catalysis. 8 (2): 1161–1172. doi:10.1021/acscatal.7b02974.
^IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"). Compiled by A. D. McNaught and A. Wilkinson. Blackwell Scientific Publications, Oxford (1997). doi:10.1351/goldbook
and 24 Related for: Oxidative coupling information
Oxidativecoupling in chemistry is a coupling reaction of two molecular entities through an oxidative process. Usually oxidativecouplings are catalysed...
Oxidativecoupling of phenols is a chemical reaction wherein two phenolic compounds are coupled via an oxidative process. Oxidative phenol couplings are...
the oxidative addition step breaks the carbon-halogen bond where the palladium is now bound to both the halogen (X) as well as the R1 group. Oxidative addition...
The oxidativecoupling of methane (OCM) is a potential chemical reaction studied in the 1980s for the direct conversion of natural gas, primarily consisting...
with substrates following standard oxidative addition relative rates (I>OTf>Br>>Cl). The actual mechanism of oxidative addition is unresolved, though there...
Fenghai; Clift, Michael D.; Thomson, Regan J. (September 2012). "OxidativeCoupling of Enolates, Enol Silanes, and Enamines: Methods and Natural Product...
oxidized by air. The oxidation is catalyzed by the enzyme gallate dioxygenase, an enzyme found in Pseudomonas putida. Oxidativecoupling of gallic acid with...
Oxidative phosphorylation uses these molecules and O2 to produce ATP, which is used throughout the cell whenever energy is needed. During oxidative phosphorylation...
{Cu(OAc)2}}][{\ce {pyridine}}]R-\!{\equiv }\!-\!{\equiv }\!-R}}} The oxidativecoupling of alkynes has been used to synthesize a number of fungal antibiotics...
Oxidative addition and reductive elimination are two important and related classes of reactions in organometallic chemistry. Oxidative addition is a process...
reactive vinyl halides to Pd0 oxidative addition, and their use is therefore most frequent for Sonogashira cross-coupling reactions due to the usually...
components of the cell, including proteins, lipids, and DNA. Oxidative stress from oxidative metabolism causes base damage, as well as strand breaks in...
to many kinds of reactions including amine oxidation, aromatization, oxidativecoupling, and thiol oxidation. In Geobacteraceae sp., MnO2 functions as...
cross coupling reactions. One difference between copper and palladium is that copper can undergo single-electron transfer processes. Oxidativecoupling is...
rate-determining oxidative addition occurs more slowly than with nickel catalyst systems. Current understanding of the mechanism for the nickel-catalyzed coupling is...
chemical reaction widely used in organic synthesis. The reaction involves the coupling of two organic groups, one of which is carried as an organotin compound...
containing moieties of the phenolic ferulic acid that can undergo oxidativecoupling (in the same way as lignin units) forming crosslinks between arabinoxylan...
styrene. In the presence of base and copper(II) salts, it undergoes oxidativecoupling to give diphenylbutadiyne. In the presence of metal catalysts, it...
household food covering. Polyphenylene oxide (PPO), which is obtained from the free-radical, step-growth oxidativecoupling polymerization of 2,6-xylenol, has...
derived by oxidativecoupling of monolignols. Thus, most lignans feature a C18 cores, resulting from the dimerization of C9 precursors. The coupling of the...
one-electron oxidations, leading to crosslinking. For example, laccases play a role in the formation of lignin by promoting the oxidativecoupling of monolignols...
elimination reaction of various oximes derived from cinnamaldehyde, and oxidativecoupling of benzene to acrylonitrile. "Cinnamonitrile". pubchem.ncbi.nlm.nih...
acid cycle Electrochemical gradient Glycolysis Oxidative phosphorylation Mitchell P (July 1961). "Coupling of phosphorylation to electron and hydrogen transfer...
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