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Hydrogen sulfide information


Hydrogen sulfide
Skeletal formula of hydrogen sulfide with two dimensions
Ball-and-stick model of hydrogen sulfide
Ball-and-stick model of hydrogen sulfide
Spacefill model of hydrogen sulfide
Spacefill model of hydrogen sulfide
  Sulfur, S
  Hydrogen, H
Names
Systematic IUPAC name
Hydrogen sulfide[1]
Other names
  • Dihydrogen monosulfide
  • Sour gas
  • Dihydrogen sulfide
  • Sewer gas
  • Egg gas
  • Sulfane
  • Sulfurated hydrogen
  • Sulfureted hydrogen
  • Sulfuretted hydrogen
  • Sulfur hydride
  • Hydrosulfuric acid
  • Hydrothionic acid
  • Thiohydroxic acid
  • Sulfhydric acid
Identifiers
CAS Number
  • 7783-06-4 checkY
3D model (JSmol)
  • Interactive image
3DMet
  • B01206
Beilstein Reference
3535004
ChEBI
  • CHEBI:16136 checkY
ChEMBL
  • ChEMBL1200739 ☒N
ChemSpider
  • 391 checkY
ECHA InfoCard 100.029.070 Edit this at Wikidata
EC Number
  • 231-977-3
Gmelin Reference
303
KEGG
  • C00283 checkY
MeSH Hydrogen+sulfide
PubChem CID
  • 402
RTECS number
  • MX1225000
UNII
  • YY9FVM7NSN checkY
UN number 1053
CompTox Dashboard (EPA)
  • DTXSID4024149 Edit this at Wikidata
InChI
  • InChI=1S/H2S/h1H2 checkY
    Key: RWSOTUBLDIXVET-UHFFFAOYSA-N checkY
  • InChI=1/H2S/h1H2
    Key: RWSOTUBLDIXVET-UHFFFAOYAJ
SMILES
  • S
Properties
Chemical formula
H2S
Molar mass 34.08 g·mol−1
Appearance Colorless gas
Odor Foul, pungent, like that of rotten eggs
Density 1.539 g.L−1 (0°C)[2]
Melting point −85.5[3] °C (−121.9 °F; 187.7 K)
Boiling point −59.55[3] °C (−75.19 °F; 213.60 K)
Solubility in water
3.980 g dm−3 (at 20 °C) [4]
Vapor pressure 1740 kPa (at 21 °C)
Acidity (pKa) 7.0[5][6]
Conjugate acid Sulfonium
Conjugate base Bisulfide
Magnetic susceptibility (χ)
−25.5·10−6 cm3/mol
Refractive index (nD)
1.000644 (0 °C)[2]
Structure
Point group
C2v
Molecular shape
Bent
Dipole moment
0.97 D
Thermochemistry
Heat capacity (C)
1.003 J K−1 g−1
Std molar
entropy (S298)
206 J mol−1 K−1[7]
Std enthalpy of
formation fH298)
−21 kJ mol−1[7]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable and highly toxic
GHS labelling:
Pictograms
GHS02: FlammableGHS06: ToxicGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H220, H330, H400
Precautionary statements
P210, P260, P271, P273, P284, P304+P340, P310, P320, P377, P381, P391, P403, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
4
4
0
Flash point −82.4 °C (−116.3 °F; 190.8 K)[10]
Autoignition
temperature
232 °C (450 °F; 505 K)
Explosive limits 4.3–46%
Lethal dose or concentration (LD, LC):
LC50 (median concentration)
  • 713 ppm (rat, 1 hr)
  • 673 ppm (mouse, 1 hr)
  • 634 ppm (mouse, 1 hr)
  • 444 ppm (rat, 4 hr)[9]
LCLo (lowest published)
  • 600 ppm (human, 30 min)
  • 800 ppm (human, 5 min)[9]
NIOSH (US health exposure limits):
PEL (Permissible)
C 20 ppm; 50 ppm [10-minute maximum peak][8]
REL (Recommended)
C 10 ppm (15 mg/m3) [10-minute][8]
IDLH (Immediate danger)
100 ppm[8]
Related compounds
Related hydrogen chalcogenides
  • Water
  • Hydrogen selenide
  • Hydrogen telluride
  • Hydrogen polonide
  • Hydrogen disulfide
  • Sulfanyl
Related compounds
Phosphine
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Hydrogen sulfide is a chemical compound with the formula H2S. It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs.[11] Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777.[12]

Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or its salts are ingested in high amounts,[clarification needed] damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death.[13][14] Despite this, the human body produces small amounts of this sulfide and its mineral salts, and uses it as a signalling molecule.[15]

Hydrogen sulfide is often produced from the microbial breakdown of organic matter in the absence of oxygen, such as in swamps and sewers; this process is commonly known as anaerobic digestion, which is done by sulfate-reducing microorganisms. It also occurs in volcanic gases, natural gas deposits, and sometimes in well-drawn water.

  1. ^ "Hydrogen Sulfide - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology Information.
  2. ^ a b Patnaik, Pradyot (2002). Handbook of Inorganic Chemicals. McGraw-Hill. ISBN 978-0-07-049439-8.
  3. ^ a b William M. Haynes (2016). CRC Handbook of Chemistry and Physics (97th ed.). Boca Raton: CRC Press. pp. 4–87. ISBN 978-1-4987-5429-3.
  4. ^ "Hydrogen sulfide". pubchem.ncbi.nlm.nih.gov.
  5. ^ Perrin, D.D. (1982). Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution (2nd ed.). Oxford: Pergamon Press.
  6. ^ Bruckenstein, S.; Kolthoff, I.M., in Kolthoff, I.M.; Elving, P.J. Treatise on Analytical Chemistry, Vol. 1, pt. 1; Wiley, NY, 1959, pp. 432–433.
  7. ^ a b Zumdahl, Steven S. (2009). Chemical Principles (6th ed.). Houghton Mifflin Company. p. A23. ISBN 978-0-618-94690-7.
  8. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0337". National Institute for Occupational Safety and Health (NIOSH).
  9. ^ a b "Hydrogen sulfide". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  10. ^ "Hydrogen sulfide". npi.gov.au.
  11. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  12. ^ Smith, Roger P. (2010). "A Short History of Hydrogen Sulfide". American Scientist. 98 (1): 6. doi:10.1511/2010.82.6.
  13. ^ Shackelford, R. E.; Li, Y.; Ghali, G. E.; Kevil, C. G. (2021). "Bad Smells and Broken DNA: A Tale of Sulfur-Nucleic Acid Cooperation". Antioxidants. 10 (11): 1820. doi:10.3390/antiox10111820. PMC 8614844. PMID 34829691.
  14. ^ Reiffenstein, R. J.; Hulbert, W. C.; Roth, S. H. (1992). "Toxicology of Hydrogen Sulfide". Annual Review of Pharmacology and Toxicology. 32: 109–134. doi:10.1146/annurev.pa.32.040192.000545. PMID 1605565.
  15. ^ Bos, E. M; Van Goor, H; Joles, J. A; Whiteman, M; Leuvenink, H. G (2015). "Hydrogen sulfide: Physiological properties and therapeutic potential in ischaemia". British Journal of Pharmacology. 172 (6): 1479–1493. doi:10.1111/bph.12869. PMC 4369258. PMID 25091411.

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reduced hydrogen sulfide production. Also, evidence suggests that colonic hydrogen sulfide is largely present in bound forms, probably sulfides of iron...

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Hydrogen sulfide chemosynthesis is a form of chemosynthesis which uses hydrogen sulfide. It is common in hydrothermal vent microbial communities Due to...

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is natural gas or any other gas containing significant amounts of hydrogen sulfide (H2S). Natural gas is usually considered sour if there are more than...

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threshold for hydrogen sulfide is 8-10 μg/L, with levels above this imparting a distinct rotten egg aroma to the wine. Hydrogen sulfide can further react...

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with hydrogen sulfide oceans, the source of the hydrogen sulfide could come from volcanoes, in which case it could be mixed in with a bit of hydrogen fluoride...

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product of the half-neutralization of hydrogen sulfide (H2S) with sodium hydroxide (NaOH). NaSH and sodium sulfide are used industrially, often for similar...

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to hydrogen sulfide (H2S) and elemental sulfur. The connection of atoms in the hydrogen disulfide molecule is H−S−S−H. The structure of hydrogen disulfide...

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Ethylene oxide

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acrylonitrile: HO–CH2CH2–CN → CH2=CH–CN + H2O When reacting with the hydrogen sulfide, ethylene oxide forms 2-mercaptoethanol and thiodiglycol, and with...

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Sulfuric acid

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produce sulfur dioxide: S + O2 → SO2 (−297 kJ/mol) or, alternatively, hydrogen sulfide (H2S) gas is incinerated to SO2 gas: 2 H2S + 3 O2 → 2 H2O + 2 SO2 (−1036 kJ/mol)...

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Oil refinery

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to hydrogen sulfide via catalytic hydrodesulfurization and removed from the product stream via amine gas treating. Using the Claus process, hydrogen sulfide...

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Hydrogen sulfide sensor

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Hydrogen sulfide (H2S) is a noxious gas characterized by its distinctive stench reminiscent of rotten eggs. It goes by several colloquial names, including...

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Chemosynthesis

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organic matter using the oxidation of inorganic compounds (e.g., hydrogen gas, hydrogen sulfide) or ferrous ions as a source of energy, rather than sunlight...

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Sulfur cycle

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inorganic forms, such as hydrogen sulfide (H2S), elemental sulfur, as well as sulfide minerals. Oxidation of hydrogen sulfide, sulfide, and elemental sulfur...

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Dimethyl sulfide

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of dimethyl sulfide, noting "On Earth, this is only produced by life." In industry dimethyl sulfide is produced by treating hydrogen sulfide with excess...

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Bisulfide

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bisulfide salts decompose to produce sulfide salts and hydrogen sulfide. At physiological pH, hydrogen sulfide is usually fully ionized to bisulfide...

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Girdler sulfide process

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hydrogen sulfide is lowered, and the concentration in the water raised. The deuterium in the hot loop slightly prefers to be in the hydrogen sulfide,...

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Corrosion

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active in the absence of oxygen (anaerobic); they produce hydrogen sulfide, causing sulfide stress cracking. In the presence of oxygen (aerobic), some...

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Silver sulfide

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Silver sulfide naturally occurs as the tarnish on silverware. When combined with silver, hydrogen sulfide gas creates a layer of black silver sulfide patina...

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Extinction event

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deep-water sulfate-reducing bacteria, causing massive emissions of hydrogen sulfide, which poisoned life on both land and sea and severely weakened the...

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Zinc sulfide

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synthesis from hydrogen sulfide gas and zinc vapour, and this is sold as FLIR-grade (Forward Looking Infrared), where the zinc sulfide is in a milky-yellow...

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Hydrogen sulfide is produced in small amounts by some cells of the mammalian body and has a number of biological signaling functions. Only two other such...

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oxides/hydroxides. This can begin when the sulfide is exposed to the atmosphere. The hydrolysis reaction generates gaseous hydrogen sulfide (H2S). More than six crystalline...

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