Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Bismuthine (IUPAC name: bismuthane) is the chemical compound with the formula BiH3. As the heaviest analogue of ammonia (a pnictogen hydride), BiH3 is unstable, decomposing to bismuth metal well below 0 °C. This compound adopts the expected pyramidal structure with H–Bi–H angles of around 90°.[1]
The term bismuthine may also refer to a member of the family of organobismuth(III) species having the general formula BiR 3, where R is an organic substituent. For example, Bi(CH3)3 is trimethylbismuthine.
^W. Jerzembeck; H. Bürger; L. Constantin; L. Margulès; J. Demaison; J. Breidung; W. Thiel (2002). "Bismuthine BiH3: Fact or Fiction? High-Resolution Infrared, Millimeter-Wave, and Ab Initio Studies". Angew. Chem. Int. Ed. 41 (14): 2550–2552. doi:10.1002/1521-3773(20020715)41:14<2550::AID-ANIE2550>3.0.CO;2-B. PMID 12203530. Archived from the original on 2013-01-05.
Bismuthine (IUPAC name: bismuthane) is the chemical compound with the formula BiH3. As the heaviest analogue of ammonia (a pnictogen hydride), BiH3 is...
colourless gas, is the most stable phosphorus hydride Arsine, stibine, and bismuthine are highly toxic, thermally unstable, and colourless gases. No appreciable...
to antimony, bismuth does not form a stable hydride. Bismuth hydride, bismuthine (BiH 3), is an endothermic compound that spontaneously decomposes at room...
(SDS) ICSC 0694 Related compounds Other cations Ammonia Arsine Stibine Bismuthine Related compounds Trimethylphosphine Triphenylphosphine Except where otherwise...
Like its lighter homologues ammonia, phosphine, arsine, stibine, and bismuthine, moscovine (McH3) is expected to have a trigonal pyramidal molecular geometry...
arsenic would. Bismuth (Bi), which also gives a false positive by forming bismuthine (BiH3), similarly can be distinguished by how it resists attack by both...
3 ppm Related compounds Related hydrides Ammonia; phosphine; stibine; bismuthine Supplementary data page Arsine (data page) Except where otherwise noted...
Triphosphane Diphosphene Hexaphosphabenzene Arsine Diarsane Triarsane Stibine Bismuthine Except where otherwise noted, data are given for materials in their standard...
danger) 5 ppm Related compounds Related compounds Ammonia Phosphine Arsine Bismuthine Triphenylstibine Except where otherwise noted, data are given for materials...
Senderova, and M. T. Yanchenko. It is one of the oxidation products of bismuthine, it is extremely rare. Zavaritskite is formed secondarily as a weathering...
from ammonia-borane to the bismuth(I) center, forming a highly unstable bismuthine intermediate. Subsequent reductive elimination transfers the two hydrogen...
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