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Organic sulfide information


General structure of a sulfide with the blue marked functional group.

In organic chemistry, a sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity R−S−R' as shown on right. Like many other sulfur-containing compounds, volatile sulfides have foul odors.[1] A sulfide is similar to an ether except that it contains a sulfur atom in place of the oxygen. The grouping of oxygen and sulfur in the periodic table suggests that the chemical properties of ethers and sulfides are somewhat similar, though the extent to which this is true in practice varies depending on the application.

  1. ^ Cremlyn, R. J. (1996). An Introduction to Organosulfur Chemistry. Chichester: John Wiley and Sons. ISBN 0-471-95512-4.

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Organic sulfide

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In organic chemistry, a sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity R−S−R' as shown on right...

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Hydrogen sulfide

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this sulfide and its mineral salts, and uses it as a signalling molecule. Hydrogen sulfide is often produced from the microbial breakdown of organic matter...

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Sulfide

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of sulfide salts are corrosive. Sulfide also refers to large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen...

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Sodium sulfide

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Sodium sulfide is a chemical compound with the formula Na2S, or more commonly its hydrate Na2S·9H2O. Both the anhydrous and the hydrated salts in pure...

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Dimethyl sulfide

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Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH3)2S. The simplest thioether, it is a flammable liquid that...

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Polyphenylene sulfide

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Polyphenylene sulfide (PPS) is an organic polymer consisting of aromatic rings linked by sulfides. Synthetic fiber and textiles derived from this polymer...

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Lithium sulfide

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Lithium sulfide is the inorganic compound with the formula Li2S. It crystallizes in the antifluorite motif, described as the salt (Li+)2S2−. It forms...

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Organic compound

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authorities define an organic compound as a chemical compound that contains a carbon–hydrogen or carbon–carbon bond; others consider an organic compound to be...

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Sulfur cycle

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of organic sulfur into inorganic forms, such as hydrogen sulfide (H2S), elemental sulfur, as well as sulfide minerals. Oxidation of hydrogen sulfide, sulfide...

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Sodium hydrosulfide

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hydrolysis by atmospheric moisture. In contrast with sodium sulfide (Na2S), which is insoluble in organic solvents, NaSH, being a 1:1 electrolyte, is more soluble...

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Sulfur compounds

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polysulfanes, H2Sx where x= 2, 3, and 4. Ultimately, reduction of sulfur produces sulfide salts: 16 Na + S8 → 8 Na2S The interconversion of these species is exploited...

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Carbonyl sulfide

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the release of carbonyl sulfide from small organic molecules has been identified as a strategy for delivering hydrogen sulfide, which is gaseous signaling...

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Diethyl sulfide

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Polyene Cyclizations". Organic Syntheses. 88: 54. doi:10.15227/orgsyn.088.0054. C.Hansson (2007). "cis-Dichloridobis(diethyl sulfide-κS)platinum(II) at 295...

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Sulfide mineral

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The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S2−2) as the major anion. Some sulfide minerals are economically important...

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Selenide

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with oxidation number of −2. Similar to sulfide, selenides occur both as inorganic compounds and as organic derivatives, which are called organoselenium...

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Sulfoxide

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It is a polar functional group. Sulfoxides are oxidized derivatives of sulfides. Examples of important sulfoxides are alliin, a precursor to the compound...

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Sulfur

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nonpolar organic solvents, such as benzene and toluene. Under normal conditions, sulfur hydrolyzes very slowly to mainly form hydrogen sulfide and sulfuric...

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Thiol

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or UV light. Halide displacement, using the suitable organic halide and sodium hydrogen sulfide has also been used. Another method entails the alkylation...

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Thiodiglycol

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bis(2-chloroethyl)sulfide and can be detected in the urine of casualties. E. M. Faber and G. E. Miller (1932). "β-Thiodiglycol". Organic Syntheses. 12: 68...

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Diphenyl sulfide

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"GESTIS-Stoffdatenbank". "Diphenyl sulfide". Hartman, W. W.; Smith, L. A.; Dickey, J. B. (1934). "Diphenyl Sulfide". Organic Syntheses. 14: 36. doi:10.15227/orgsyn...

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Swern oxidation

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reaction. Dimethyl sulfide, a byproduct of the Swern oxidation, is one of the most notoriously unpleasant odors known in organic chemistry. Humans can...

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Borane dimethylsulfide

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BH3·S(CH3)2. It is an adduct between borane molecule (BH3) and dimethyl sulfide molecule (S(CH3)2). It is a complexed borane reagent that is used for hydroborations...

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Divinyl sulfide

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Sulfoxide". Organic Syntheses. 64: 157. doi:10.15227/orgsyn.064.0157. Daniel S. Reno; Richard J. Pariza (1997). "Phenyl Vinyl Sulfide". Organic Syntheses...

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Potassium sulfide

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Potassium sulfide is an inorganic compound with the formula K2S. The colourless solid is rarely encountered, because it reacts readily with water, a reaction...

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Chemosynthesis

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methane) and nutrients into organic matter using the oxidation of inorganic compounds (e.g., hydrogen gas, hydrogen sulfide) or ferrous ions as a source...

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Organosulfur chemistry

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sulfoxide, R−S(O)−R, is the S-oxide of a sulfide ("sulfide oxide"), a sulfone, R−S(O)2−R, is the S,S-dioxide of a sulfide, a thiosulfinate, R−S(O)−S−R, is the...

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Chloromethyl methyl sulfide

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"Chloromethyl methyl sulfide". pubchem.ncbi.nlm.nih.gov. Tsai, Yeun-Min (2001). "Chloromethyl Methyl Sulfide". Encyclopedia of Reagents for Organic Synthesis. doi:10...

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Hydrodesulfurization

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wide range of organic sulfur compounds, including thiols, thiophenes, organic sulfides and disulfides, and many others. These organic sulfur compounds...

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