Organosulfur chemistry is the study of the properties and synthesis of organosulfur compounds, which are organic compounds that contain sulfur.[1] They are often associated with foul odors, but many of the sweetest compounds known are organosulfur derivatives, e.g., saccharin. Nature is abound with organosulfur compounds—sulfur is vital for life. Of the 20 common amino acids, two (cysteine and methionine) are organosulfur compounds, and the antibiotics penicillin and sulfa drugs both contain sulfur. While sulfur-containing antibiotics save many lives, sulfur mustard is a deadly chemical warfare agent. Fossil fuels, coal, petroleum, and natural gas, which are derived from ancient organisms, necessarily contain organosulfur compounds, the removal of which is a major focus of oil refineries.
Sulfur shares the chalcogen group with oxygen, selenium, and tellurium, and it is expected that organosulfur compounds have similarities with carbon–oxygen, carbon–selenium, and carbon–tellurium compounds.
A classical chemical test for the detection of sulfur compounds is the Carius halogen method.
^Block, E. (1978). Reactions of Organosulfur Compounds. Academic Press. ISBN 0-12-107050-6.
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Organosulfurchemistry is the study of the properties and synthesis of organosulfur compounds, which are organic compounds that contain sulfur. They are...
chemistry and discussed under titles such as organosulfurchemistry, organometallic chemistry, organophosphorus chemistry and organosilicon chemistry...
In organosulfurchemistry, a sulfonate is a salt, anion or ester of a sulfonic acid. Its formula is R−S(=O)2−O−, containing the functional group −S(=O)2−O−...
natural gas, skunk scent, bad breath, grapefruit, and garlic are due to organosulfur compounds. Hydrogen sulfide gives the characteristic odor to rotting...
In organosulfurchemistry, organosulfates are a class of organic compounds sharing a common functional group with the structure R−O−SO−3. The SO4 core...
Introduction to OrganosulfurChemistry. Chichester: John Wiley and Sons. ISBN 978-0-471-95512-2. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the...
Allicin is an organosulfur compound obtained from garlic. When fresh garlic is chopped or crushed, the enzyme alliinase converts alliin into allicin, which...
In organosulfurchemistry, a mesylate is any salt or ester of methanesulfonic acid (CH3SO3H). In salts, the mesylate is present as the CH3SO−3 anion. When...
chloride and one of the most common, and it is used as a precursor to organosulfur compounds. It is a highly corrosive and toxic substance, and it reacts...
In organosulfurchemistry, sulfenamides (also spelled sulphenamides) are a class of organosulfur compounds characterized by the general formula R−S−N(−R)2...
In organic chemistry, thioketones (from Ancient Greek θεῖον (theion) 'sulfur'; also known as thiones or thiocarbonyls) are organosulfur compounds related...
In organosulfurchemistry, sulfinamide is a functional group with the structure R−S(=O)−NR2 (where R = alkyl or aryl). This functionality is composed of...
ISBN 978-0-521-21489-6. Cremlyn R. J. (1996). An Introduction to OrganosulfurChemistry. Chichester: John Wiley and Sons. ISBN 0-471-95512-4. Wilson, R...
In organic chemistry, a sulfone is a organosulfur compound containing a sulfonyl (R−S(=O)2−R’) functional group attached to two carbon atoms. The central...
In organic chemistry, a sulfide (British English sulphide) or thioether is an organosulfur functional group with the connectivity R−S−R' as shown on right...
2022. Block, Eric; Deorazio, Russell (1994). "Chemistry in a salad bowl: Comparative organosulfurchemistry of garlic, onion and shiitake mushrooms" (PDF)...
In organosulfurchemistry, a sulfonyl group can refer either to a functional group found primarily in sulfones, or to a substituent obtained from a sulfonic...
In organosulfurchemistry, a Bunte salt is an archaic name for salts with the formula RSSO3–Na+. They are also called S-alkylthiosulfates or S-arylthiosulfates...
to OrganosulfurChemistry John Wiley and Sons: Chichester (1996). ISBN 0-471-95512-4 Garcia-Valverde M., Torroba T. (2006). "Heterocyclic chemistry of...
was discovered by Rudolf Pummerer [de], who reported it in 1909. Organosulfurchemistry Polonovski reaction ― similar reaction involving an amine oxide...
acidic than hydrogen sulfide, but the pKa has not been reported. In organosulfurchemistry, hydrogen disulfide adds to alkenes to give disulfides and thiols...
In organosulfurchemistry, thioacetals are the sulfur (thio-) analogues of acetals (R−CH(−OR)2). There are two classes: the less-common monothioacetals...
In organic chemistry, thioesters are organosulfur compounds with the molecular structure R−C(=O)−S−R’. They are analogous to carboxylate esters (R−C(=O)−O−R’)...
49 due to a heart problem. The organosulfur compounds of urine were his starting point into the physiological chemistry. He identified the source for aromatic...
In organic chemistry, a thiol (/ˈθaɪɒl/; from Ancient Greek θεῖον (theion) 'sulfur'), or thiol derivative, is any organosulfur compound of the form R−SH...
In organosulfurchemistry, thiosulfinate is a functional group consisting of the linkage R-S(O)-S-R (R are organic substituents). Thiolsulfinates are also...
Crystal Chemistry. 25 (10): 2094–2101. Bibcode:1969AcCrB..25.2094L. doi:10.1107/S0567740869005188. Cremlyn, R. J. (1996). An Introduction to Organosulfur Chemistry...
the chemistry of organosulfur and organoselenium compounds, Allium chemistry (the chemistry of garlic, onion, and other alliums), and the chemistry of...
converted to molybdenum disulfide by the action of hydrogen sulfide. In organosulfurchemistry, sulfiding is often called thiation. The preparation of thioamides...
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