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Chloromethyl methyl sulfide information


Chloromethyl methyl sulfide
Names
Other names
methylthiomethyl chloride; MTMCl
Identifiers
CAS Number
  • 2373-51-5 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 16027
EC Number
  • 219-148-4
PubChem CID
  • 16916
InChI
  • InChI=1S/C2H5ClS/c1-4-2-3/h2H2,1H3
    Key: JWMLCCRPDOIBAV-UHFFFAOYSA-N
SMILES
  • CSCCl
Properties
Chemical formula
C2H5ClS
Molar mass 96.57 g·mol−1
Appearance colorless liquid
Density 1.1773 g cm−3
Boiling point 107 °C (225 °F; 380 K) 750 mmHg
Hazards
GHS labelling:[1]
Pictograms
GHS02: FlammableGHS07: Exclamation mark
Signal word
Danger
Hazard statements
H225, H315, H319, H335
Precautionary statements
P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, P501
Related compounds
Related compounds
Dimethyl sulfide; 2-Chloroethyl ethyl sulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Chloromethyl methyl sulfide is the organosulfur compound with the formula ClCH2SCH3. In terms of functional groups, it is a thioether and an alkyl chloride. The compound is structurally related to sulfur mustards, i.e., it is a potentially hazardous alkylating agent. The compound finds some use in organic chemistry as a protecting group. In the presence of base, it converts carboxylic acids (RCO2H) to esters RCO2CH2SCH3.[2] The compound is prepared by treatment of dimethylsulfide with sulfuryl chloride.[3]

  1. ^ "Chloromethyl methyl sulfide". pubchem.ncbi.nlm.nih.gov.
  2. ^ Tsai, Yeun-Min (2001). "Chloromethyl Methyl Sulfide". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rc119. ISBN 0471936235.
  3. ^ Bordwell, F. G.; Pitt, Burnett M. (1955). "The Formation of α-Chloro Sulfides from Sulfides and from Sulfoxides". Journal of the American Chemical Society. 77 (3): 572–577. doi:10.1021/ja01608a016.

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Chloromethyl methyl sulfide

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Chloromethyl methyl sulfide is the organosulfur compound with the formula ClCH2SCH3. In terms of functional groups, it is a thioether and an alkyl chloride...

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Dimethyl sulfide

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dimethyl sulfide by reduction of dimethylsulfoxide. With chlorinating agents such as sulfuryl chloride, dimethyl sulfide converts to chloromethyl methyl sulfide:...

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Mustard gas

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commonly used for the organosulfur chemical compound bis(2-chloroethyl) sulfide, which has the chemical structure S(CH2CH2Cl)2, as well as other species...

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acid 2-chloroethanol Chloroethyl chloroformate Chloroform Chloromethyl ether Chloromethyl methyl ether Chlorophacinone Chloroxuron Chlorthiophos Chromic...

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When conducted in the presence of hydrogen chloride, the product is the chloromethyl compound, as described in the Blanc chloromethylation. If the arene is...

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5000 Chloromethyl methyl ether 107-30-2 500 Chloropicrin 76-06-2 500 Chloropicrin and methyl bromide mixture None 1500 Chloropicrin and methyl chloride...

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bromoiodomethane 557-68-6 CH2BrNO2 bromonitromethane 563-70-2 CH2Cl chloromethyl radical 6806-86-6 CH2ClI chloroiodomethane 593-71-5 CH2ClNO2 chloronitromethane...

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palladium 1271-03-0 C8H10S benzyl methyl sulfide 766-92-7 C8H10S phenylethylthiol 4410-99-5 C8H10S2 benzyl methyl disulfide 699-10-5 C8H10Se ethylselenobenzene...

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2350 3 Butyl methyl ether UN 2351 3 Butyl nitrites UN 2352 3 Butyl vinyl ether, inhibited UN 2353 3 Butyryl chloride UN 2354 3 Chloromethyl ethyl ether...

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1-(2-Chloroethyl)-3-(4-methylcyclohexyl)-1-nitrosourea (Methyl-CCNU) 13909-09-6 Chloroform 67-66-3 Chloromethyl methyl ether 107-30-2 3-Chloro-2-methylpropene 563-47-3...

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