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Niobium disulfide information


Niobium disulfide

NbS2 exfoliated layer

NbS2 structure
Names
IUPAC name
niobium(IV) sulfde, niobium disulfde
Identifiers
CAS Number
  • 12136-97-9 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 9980003
PubChem CID
  • 11805338
CompTox Dashboard (EPA)
  • DTXSID50473068 Edit this at Wikidata
InChI
  • Key: VRSMQRZDMZDXAU-UHFFFAOYSA-N
  • InChI=1S/Nb.2S
SMILES
  • S=[Nb]=S
Properties
Chemical formula
NbS2
Molar mass 157.038 g/mol[1]
Appearance Black crystals[1]
Density 4.4 g/cm3[1]
Magnetic susceptibility (χ)
+120·10−6 cm3/mol[2]
Structure[3]
Crystal structure
Trigonal, hR9, No. 160
Space group
R3m
Lattice constant
a = 0.333 nm, b = 0.333 nm, c = 1.78 nm
α = 90°, β = 90°, γ = 120°
Formula units (Z)
3
Related compounds
Other anions
Niobium diselenide, Niobium ditelluride
Other cations
Vanadium disulfide, Tantalum disulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Niobium disulfide is the chemical compound with the formula NbS2. It is a black layered solid that can be exfoliated into ultrathin grayish sheets similar to other transition metal dichalcogenides. These layers exhibit superconductivity, where the transition temperature increases from ca. 2 to 6 K with the layer thickness increasing from 6 to 12 nm, and then saturates with thickness.[4]

  1. ^ a b c Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. p. 4.76. ISBN 0-8493-0486-5.
  2. ^ Lee, P.A. (6 December 2012). Optical and Electrical Properties. Springer Science & Business Media. p. 446. ISBN 978-94-010-1478-6.
  3. ^ Rajora, O. S.; Curzon, A. E. (1987). "The preparation and X‐ray diffraction study of the layer materials NbSxSe2−x for 0 ≦ x ≦ 2". Physica Status Solidi A. 99: 65–72. doi:10.1002/pssa.2210990108.
  4. ^ Yan, Rusen; Khalsa, Guru; Schaefer, Brian T.; Jarjour, Alexander; Rouvimov, Sergei; Nowack, Katja C.; Xing, Huili G.; Jena, Debdeep (2019). "Evolution of superconductivity in ultrathin NbS2". Applied Physics Express. 12 (2): 023008. arXiv:1803.06097. doi:10.7567/1882-0786/aaff89.

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Niobium disulfide

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Niobium disulfide is the chemical compound with the formula NbS2. It is a black layered solid that can be exfoliated into ultrathin grayish sheets similar...

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Chalcogenide

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described as M4+(E22−)(E2−) (where E = S, Se, Te). A well known example is niobium triselenide. Amorphous MoS3 is produced by treatment of tetrathiomolybdate...

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Sulfur

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and 50 °C (122 °F). Sulfur is insoluble in water but soluble in carbon disulfide and, to a lesser extent, in other nonpolar organic solvents, such as benzene...

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Carbon compounds

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common metals and their alloys: aluminum, chromium, magnesium, molybdenum, niobium, thorium, titanium, tungsten, uranium, vanadium, zinc, and zirconium. For...

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Materials for use in vacuum

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between Molybdenum Disulfide & Tungsten Disulfide" (PDF). Retrieved 2015-09-08. "Applied Tungstenite: Aerospace: Tungsten Disulfide WS2 dry film Lubricant...

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List of inorganic compounds

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Ni(SO3NH2)2 Nickel(II) sulfide – NiS Niobium(IV) fluoride – NbF4 Niobium(V) fluoride – NbF5 Niobium oxychloride – NbOCl3 Niobium pentachloride – NbCl5 Dinitrogen...

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Tungsten trisulfide

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through hot acidified solution of tungstenates. Reaction of tungsten disulfide and elemental sulfur on heating: WS 2 + S ⟶ WS 3 {\displaystyle {\ce {WS2...

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Molybdenum

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compound is molybdenum disulfide MoS2. From the perspective of commerce, the most important compounds are molybdenum disulfide (MoS 2) and molybdenum...

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Germanium

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However this metal was later recognized to be an alloy of the elements niobium and tantalum. The name "neptunium" was later given to the synthetic element...

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Tantalum diselenide

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transition metal dichalcogenides. In contrast to molybdenum disulfide (MoS2) or rhenium disulfide (ReS2), tantalum diselenide does not occur spontaneously...

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Allotropes of phosphorus

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unaware of their true nature. P4 is soluble in benzene, oils, carbon disulfide, and disulfur dichloride. The white allotrope can be produced using several...

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Selenium

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with aqueous selenous acid to produce selenium disulfide: H2SeO3 + 2 H2S → SeS2 + 3 H2O Selenium disulfide consists of 8-membered rings. It has an approximate...

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Iodine

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achieve in binary iodides, the maximum known being in the pentaiodides of niobium, tantalum, and protactinium. Iodides can be made by reaction of an element...

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List of semiconductor materials

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"Electronic and optical properties of single crystal SnS2: An earth-abundant disulfide photocatalyst". Journal of Materials Chemistry A. 4 (4): 1312–1318. doi:10...

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Strengthening mechanisms of materials

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et al. conducted atom probe tomograph and observed the aggregation of niobium atoms to the dislocations. The segregation energy was calculated to be...

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List of CAS numbers by chemical compound

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NbI5 niobium(V) iodide 13779–92–5 NbN niobium(III) nitride 24621–21–4 NbO niobium(II) oxide 12034–57–0 NbO2 niobium(IV) oxide 12034–59–2 NbS2 niobium(IV)...

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Protactinium

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Greenwood, p. 1269 Iyer, P. N.; Smith, A. J. (1971). "Double oxides containing niobium, tantalum or protactinium. IV. Further systems involving alkali metals"...

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Carbon

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2 O 2 → 3 Fe(s) + 4 CO 2(g). Carbon reacts with sulfur to form carbon disulfide, and it reacts with steam in the coal-gas reaction used in coal gasification:...

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Technetium

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high magnetic penetration depth, greater than any other element except niobium. Technetium is located in the seventh group of the periodic table, between...

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Titanium

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1021/cr040698p. PMID 16771446. McKelvy, M.J.; Glaunsinger, W.S. (1995). "Titanium Disulfide". Inorganic Syntheses. Vol. 30. pp. 28–32. doi:10.1002/9780470132616.ch7...

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Iridium

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reacts directly with sulfur at atmospheric pressure to yield iridium disulfide. Iridium has two naturally occurring stable isotopes, 191Ir and 193Ir...

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Iodine compounds

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achieve in binary iodides, the maximum known being in the pentaiodides of niobium, tantalum, and protactinium. Iodides can be made by reaction of an element...

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Index of chemistry articles

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Nikolay Nikolaevich Semenov Nils Gabriel Sefström Niobite Niobite-tantalite Niobium nitrate Nitric acid Nitric oxide nitrogen Nitrogen dioxide Nitroglycerine...

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Fullerene

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used as a graphite-like lubricant, tungsten (WS2), titanium (TiS2) and niobium (NbS2). These materials were found to be stable up to at least 350 tons/cm2...

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Rhenium

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up to 0.2% in the mineral molybdenite (which is primarily molybdenum disulfide), the major commercial source, although single molybdenite samples with...

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Glossary of chemical formulae

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13517-26-5 NbBr5 niobium(V) bromide 13478-45-0 NbCl3 niobium(III) chloride 13569-59-0 NbCl5 niobium(V) chloride 10026-12-7 NbI5 niobium(V) iodide 13779-92-5...

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Phosphorus

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garlicky. White phosphorus is insoluble in water but soluble in carbon disulfide. Thermal decomposition of P4 at 1100 K gives diphosphorus, P2. This species...

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