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Molybdenum dioxide information


Molybdenum dioxide
Names
IUPAC name
Molybdenum(IV) oxide
Other names
Molybdenum dioxide
Tugarinovite
Identifiers
CAS Number
  • 18868-43-4 checkY
ECHA InfoCard 100.038.746 Edit this at Wikidata
PubChem CID
  • 29320
CompTox Dashboard (EPA)
  • DTXSID10879986 DTXSID5042162, DTXSID10879986 Edit this at Wikidata
Properties
Chemical formula
MoO2
Molar mass 127.94 g/mol
Appearance brownish-violet solid
Density 6.47 g/cm3
Melting point 1,100 °C (2,010 °F; 1,370 K) decomposes
Solubility in water
insoluble
Solubility insoluble in alkalies, HCl, HF
slightly soluble in hot H2SO4
Magnetic susceptibility (χ)
+41.0·10−6 cm3/mol
Structure
Crystal structure
Distorted rutile (monoclinic)
Coordination geometry
Octahedral (MoIV); trigonal (O−II)
Hazards
Flash point Non-flammable
Related compounds
Other anions
Molybdenum disulfide
Other cations
Chromium(IV) oxide
Tungsten(IV) oxide
Related molybdenum oxides
"Molybdenum blue"
Molybdenum trioxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Molybdenum dioxide is the chemical compound with the formula MoO2. It is a violet-colored solid and is a metallic conductor. The mineralogical form of this compound is called tugarinovite, and is only very rarely found. The discovery and early studies of molybdenum dioxide date back to the late 18th and early 19th centuries. One of the notable figures in the history of molybdenum dioxide is the Hungarian chemist Jakob Joseph Winterl (1732–1809). Winterl, who was a professor of chemistry and botany at the University of Budapest, made significant contributions to the understanding of molybdenum compounds. In 1787, he proposed that copper was a compound of nickel, molybdenum, silica, and a volatile substance, showcasing his interest in molybdenum chemistry.[1]

  1. ^ Snelders, H. A. M. (July 1970). "The Influence of the Dualistic System of Jakob Joseph Winterl (1732–1809) on the German Romantic Era". Isis. 61 (2): 231–240. doi:10.1086/350622. ISSN 0021-1753.

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Molybdenum dioxide

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Molybdenum dioxide is the chemical compound with the formula MoO2. It is a violet-colored solid and is a metallic conductor. The mineralogical form of...

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Molybdenum dichloride dioxide

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other molybdenum compounds. Molybdenum dichloride dioxide is one of several oxychlorides of molybdenum. Gaseous molybdenum dichloride dioxide is a monomer...

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Molybdenum difluoride dioxide is the inorganic compound with the formula MoF2O2. It is a white, diamagnetic, volatile solid. Gaseous molybdenum difluoride...

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Molybdenum oxide

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Molybdenum oxide may refer to: Molybdenum(IV) oxide (molybdenum dioxide, MoO 2) Molybdenum(VI) oxide (molybdenum trioxide, MoO 3) Other stoichiometric...

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Moo2

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Molybdenum

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Molybdenum is a chemical element; it has symbol Mo (from Neo-Latin molybdaenum) and atomic number 42. The name derived from Ancient Greek Μόλυβδος molybdos...

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Molybdenum carbide

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Molybdenum carbide is an extremely hard, refractory, ceramic material, commercially used in tool bits for cutting tools. There are at least three reported...

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Molybdenum trioxide

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any molybdenum compound since it is the main intermediate produced when molybdenum ores are purified. The anhydrous oxide is a precursor to molybdenum metal...

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Molybdenum oxyfluoride

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Molybdenum diselenide

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Molybdenum oxychloride

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The molybdenum oxychlorides are a subset of metal oxyhalides. Molybdenum oxychloride may refer to: Molybdenum oxytetrachloride, MoOCl4 Molybdenum dichloride...

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Chemical reaction

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the enthalpy of a reaction, as for the carbon monoxide reduction of molybdenum dioxide: 2 CO ( g ) + MoO 2 ( s ) ⟶ 2 CO 2 ( g ) + Mo ( s ) {\displaystyle...

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Molybdenum oxytetrafluoride

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MoOF4(NCCH3) + 2 (CH3)3SiF Molybdenum oxytetrafluoride is susceptible to hydrolysis to give molybdenum difluoride dioxide. Edwards, A. J.; Steventon,...

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Oxide

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this way, MoS2 (molybdenite) is converted to molybdenum trioxide, the precursor to virtually all molybdenum compounds: 2 MoS 2 + 7 O 2 ⟶ 2 MoO 3 + 4 SO...

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Molybdenum disilicide

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Molybdenum oxytetrachloride

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Molybdenum dichloride dioxide "Molybdenum(VI) tetrachloride oxide". pubchem.ncbi.nlm.nih.gov. Mallock, Alan K. (1967). "Molybdenum(VI) Oxide Chloride"....

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Molybdenum ditelluride

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Molybdenum(IV) telluride, molybdenum ditelluride or just molybdenum telluride is a compound of molybdenum and tellurium with formula MoTe2, corresponding...

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Nanoflower

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silicon carbide (SiC) structures. Heating a molybdenum dioxide (MoO2) thin film on a piece of molybdenum foil surrounded by sulfur vapour. In supercapacitors...

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Chemical transport reaction

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constant is less favorable and the crystals grow. The reaction of molybdenum dioxide with the transporting agent iodine is an exothermic process, thus...

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List of inorganic compounds

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Hg(ONC)2 Molybdenum(II) bromide – MoBr2 Molybdenum(II) chloride – Mo6Cl12 Molybdenum(III) bromide – MoBr3 Molybdenum(III) chloride – MoCl3 Molybdenum(IV) carbide...

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Tungsten

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few species of bacteria and archaea. However, tungsten interferes with molybdenum and copper metabolism and is somewhat toxic to most forms of animal life...

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Period 5 element

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lead that has no stable isotopes (along with promethium), as well as molybdenum and iodine, two of the heaviest elements with a known biological role...

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Group 6 element

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members are chromium (Cr), molybdenum (Mo), tungsten (W), and seaborgium (Sg). These are all transition metals and chromium, molybdenum and tungsten are refractory...

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Sulfite

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polypropylene. Titanium can be alloyed with iron, aluminium, vanadium, and molybdenum, among other elements. The resulting titanium alloys are strong, lightweight...

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Technetium

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thorium ore (the most common source), or the product of neutron capture in molybdenum ores. This silvery gray, crystalline transition metal lies between manganese...

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Peter Jacob Hjelm

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acid, Hjelm chemically reduced molybdenum oxide with carbon in an oxygen-free atmosphere, resulting in carbon dioxide and a near-pure dark metal powder...

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Sulfide

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of the term "disulfide". Molybdenum disulfide (MoS2) consists of separated sulfide centers, in association with molybdenum in the formal +4 oxidation...

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