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Molybdenum trioxide information


Molybdenum trioxide
Names
IUPAC name
Molybdenum trioxide
Other names
Molybdic anhydride
Molybdite
Molybdic trioxide
Molybdenum(VI) oxide
Identifiers
CAS Number
  • 1313-27-5 anhydrous checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:30627
ChemSpider
  • 14118
ECHA InfoCard 100.013.823 Edit this at Wikidata
EC Number
  • 215-204-7
PubChem CID
  • 14802
UNII
  • 22FQ3F03YS checkY
UN number 3288
CompTox Dashboard (EPA)
  • DTXSID7020899 Edit this at Wikidata
InChI
  • InChI=1S/Mo.3O
    Key: JKQOBWVOAYFWKG-UHFFFAOYSA-N
SMILES
  • O=[Mo](=O)=O
Properties
Chemical formula
MoO3
Molar mass 143.95 g·mol−1
Appearance yellow solid
Odor odorless
Density 4.70 g/cm3[1]
Melting point 802 °C (1,476 °F; 1,075 K)[1]
Boiling point 1,155 °C (2,111 °F; 1,428 K)(sublimes)[1]
Solubility in water
1.066 g/L (18 °C)
4.90 g/L (28 °C)
20.55 g/L (70 °C)
Band gap >3 eV (direct)[2]
Magnetic susceptibility (χ)
+3.0·10−6 cm3/mol[3]
Structure[4]
Crystal structure
Orthorhombic, oP16
Space group
Pnma, No. 62
Lattice constant
a = 1.402 nm, b = 0.37028 nm, c = 0.39663 nm
Formula units (Z)
4
Coordination geometry
see text
Thermochemistry[5]
Heat capacity (C)
75.0 J K−1 mol−1
Std molar
entropy (S298)
77.7 J K−1 mol−1
Std enthalpy of
formation fH298)
−745.1 kJ/mol
Gibbs free energy fG)
-668.0 kJ/mol
Hazards[7]
GHS labelling:
Pictograms
GHS07: Exclamation markGHS08: Health hazard
Signal word
Warning
Hazard statements
H319, H335, H351
Precautionary statements
P201, P202, P261, P264, P271, P280, P281, P304+P340, P305+P351+P338, P308+P313, P312, P337+P313, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability (yellow): no hazard codeSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
3
0
OX
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
125 mg.kg (rat, oral)[citation needed]
2689 mg/kg (rat, oral)[6]
LDLo (lowest published)
120 mg Mo/kg (rat, oral)
120 mg Mo/kg (guinea pig, oral)[6]
LC50 (median concentration)
>5840 mg/m3 (rat, 4 hr)[6]
Related compounds
Other cations
Chromium trioxide
Tungsten trioxide
Related molybdenum oxides
Molybdenum dioxide
"Molybdenum blue"
Related compounds
Molybdic acid
Sodium molybdate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Molybdenum trioxide describes a family of inorganic compounds with the formula MoO3(H2O)n where n = 0, 1, 2. The anhydrous compound is produced on the largest scale of any molybdenum compound since it is the main intermediate produced when molybdenum ores are purified. The anhydrous oxide is a precursor to molybdenum metal, an important alloying agent. It is also an important industrial catalyst.[8] It is a yellow solid, although impure samples can appear blue or green.

Molybdenum trioxide occurs as the rare mineral molybdite.

  1. ^ a b c Haynes, p. 4.77
  2. ^ Balendhran, Sivacarendran; Walia, Sumeet; Nili, Hussein; Ou, Jian Zhen; Zhuiykov, Serge; Kaner, Richard B.; Sriram, Sharath; Bhaskaran, Madhu; Kalantar-zadeh, Kourosh (2013-08-26). "Two-Dimensional Molybdenum Trioxide and Dichalcogenides". Advanced Functional Materials. 23 (32): 3952–3970. doi:10.1002/adfm.201300125. S2CID 95301280.
  3. ^ Haynes, p. 4.134
  4. ^ Åsbrink, S.; Kihlborg, L.; Malinowski, M. (1988). "High-pressure single-crystal X-ray diffraction studies of MoO3. I. Lattice parameters up to 7.4 GPa". J. Appl. Crystallogr. 21 (6): 960–962. doi:10.1107/S0021889888008271.
  5. ^ Haynes, p. 5.15
  6. ^ a b c "Molybdenum (soluble compounds, as Mo)". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  7. ^ "Molybdenum trioxide". PubChem.
  8. ^ Roger F. Sebenik; et al. (2005). "Molybdenum and Molybdenum Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a16_655. ISBN 978-3527306732.

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Molybdenum trioxide

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Molybdenum trioxide describes a family of inorganic compounds with the formula MoO3(H2O)n where n = 0, 1, 2. The anhydrous compound is produced on the...

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Molybdenum

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are molybdenum disulfide (MoS 2) and molybdenum trioxide (MoO 3). The black disulfide is the main mineral. It is roasted in air to give the trioxide: 2...

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Molybdenum oxide

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Molybdenum oxide may refer to: Molybdenum(IV) oxide (molybdenum dioxide, MoO 2) Molybdenum(VI) oxide (molybdenum trioxide, MoO 3) Other stoichiometric...

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Trioxide

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structure. Carbon trioxide, CO3 Chromium trioxide, CrO3 Molybdenum trioxide, MoO3 Rhenium trioxide, ReO3 Selenium trioxide, SeO3 Sulfur trioxide, SO3 Tellurium...

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Tungsten trioxide

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Tungsten(VI) oxide, also known as tungsten trioxide is a chemical compound of oxygen and the transition metal tungsten, with formula WO3. The compound...

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Molybdenum dichloride dioxide

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uncertain structure. The compound is most easily prepared by treatment molybdenum trioxide with concentrated hydrochloric acid: MoO3 + 2 HCl → MoO2Cl2 + H2O...

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Ammonium orthomolybdate

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formula (NH4)2MoO4. It is a white solid that is prepared by treating molybdenum trioxide with aqueous ammonia. Upon heating these solutions, ammonia is lost...

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Molybdenum dioxide

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MoO2 into the volatile species MoO2I2. Molybdenum dioxide is a constituent of "technical molybdenum trioxide" produced during the industrial processing...

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Molybdenum disulfide

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strain. Molybdenum disulfide is stable in air and attacked only by aggressive reagents. It reacts with oxygen upon heating forming molybdenum trioxide: 2 MoS...

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Molybdic acid

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Molybdic acid refers to hydrated forms of molybdenum trioxide and related species. The monohydrate (MoO3·H2O) and the dihydrate (MoO3·2H2O) are well characterized...

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Hydrodeoxygenation

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hydrogen pressures have recently attracted a lot of attention. Bulk molybdenum trioxide (MoO3) was used as catalyst and found to completely deoxygenate cellulose...

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Oxide

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this way, MoS2 (molybdenite) is converted to molybdenum trioxide, the precursor to virtually all molybdenum compounds: 2 MoS 2 + 7 O 2 ⟶ 2 MoO 3 + 4 SO...

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Ammonium dimolybdate

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gives ADM. Upon heating, solid ammonium dimolybdate decomposes to molybdenum trioxide: (NH4)2Mo2O7 → 2 MoO3 + 2 NH3 + H2O In terms of its chemical structure...

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Molybdenum oxytetrachloride

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treating molybdenum pentachloride with oxygen. It also arises by chlorination of molybdenum trioxide: MoO3 + 2 SOCl2 → MoOCl4 + 2 SO2 Molybdenum dichloride...

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Maleic anhydride

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controlled to prevent the mixture from igniting. Vanadium pentoxide and molybdenum trioxide are the catalysts used for the benzene route, whereas vanadium phosphate...

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IARC group 2B

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4'-bis(dimethylamino)benzophenone) Microcystin-LR Mirex Mitomycin C Mitoxantrone Molybdenum trioxide 3-Monochloro-1,2-propanediol (3-MCPD) Monocrotaline...

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Thompson Creek Metals

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to produce molybdenum sulfide concentrate. It is then roasted at the Company’s Langeloth Metallurgical Facility into molybdenum trioxide, ferromolybdenum...

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List of inorganic compounds

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disulfide – MoS2 Molybdenum hexacarbonyl – Mo(CO)6 Molybdenum hexafluoride – MoF6 Molybdenum tetrachloride – MoCl4 Molybdenum trioxide – MoO3 Molybdic...

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Metal aromaticity

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energy turns out to be comparable to that of bulk tungsten trioxide and molybdenum trioxide. The photoelectric signal is also broad which suggests a large...

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Molybdenum ditelluride

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Molybdenum(IV) telluride, molybdenum ditelluride or just molybdenum telluride is a compound of molybdenum and tellurium with formula MoTe2, corresponding...

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Molybdate

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heptamolybdate Heptamolybdate with space filling oxygen atoms When MoO3, molybdenum trioxide is dissolved in alkali solution the simple MoO2−4 anion is produced:...

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Molybdite

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Molybdite is the naturally occurring mineral form of molybdenum trioxide MoO3. It occurs as yellow to greenish needles and crystallizes in the orthorhombic...

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California Proposition 65 list of chemicals

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59122-46-2 Mitomycin C 50-07-7 Mitoxantrone hydrochloride 70476-82-3 Molybdenum trioxide 1313-27-5 Molinate 2212-67-1 MON 4660 (dichloroacetyl-1-oxa-4-azaspiro(4...

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Flux method

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Bismuth (III) Oxide 817 1890 Indium 157 2072 Lithium Oxide 1438 2600 Tin 232 2602 Molybdenum Trioxide 802 1152 Lead 328 1749 Potassium Fluoride 858 1502...

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Ammonium heptamolybdate

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is one of the more common molybdenum compounds. Ammonium heptamolybdate is easily prepared by dissolving molybdenum trioxide in an excess of aqueous ammonia...

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Tungsten diarsenide

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temperatures, tungsten diarsenide reacts with air to form tungsten trioxide and arsenic trioxide. Erik Lassner, Wolf-Dieter Schubert (2012). Tungsten Properties...

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Tungsten

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elevated temperatures (i.e., when red-hot) it reacts with oxygen to form the trioxide compound tungsten(VI), WO3. It will, however, react directly with fluorine...

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Glossary of chemical formulae

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chloride 13478-18-7 MoCl5 molybdenum(V) chloride 10241-05-1 MoO2 molybdenum(IV) oxide 18868-43-4 MoO3 Molybdenum trioxide 1313-27-5 MoO42− molybdate...

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