Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Methyl hypochlorite is the simplest of the organic alkyl hypochlorites. It is an unstable compound that can be produced by the reaction of methanol with hypochlorous acid.[1] It was first synthesized by Sandmeyer in the 1880s.[2]
Methyl hypochlorite forms in the Earth's atmosphere by a reaction between ClO and CH3OO and is thought to be an important species in ozone destruction over the Arctic and Antarctic regions.[3]
^Taylor, M. C.; MacMullin, R. B.; Gammal, C. A. (February 1925). "Hypochlorous Acid and the Alkyl Hypochlorite". Journal of the American Chemical Society. 47 (2): 395–403. doi:10.1021/ja01679a017.
^Sandmeyer, Traugott (January 1886). "Ueber Aethyl- und Methylhypochlorit". Berichte der Deutschen Chemischen Gesellschaft. 19 (1): 857–861. doi:10.1002/cber.188601901196.
^Helleis, Frank; Crowley, John; Moortgat, Geert (15 August 1994). "Temperature dependent CH3OCl formation in the reaction between CH3O2 and ClO". Geophysical Research Letters. 21 (17): 1795–1798. Bibcode:1994GeoRL..21.1795H. doi:10.1029/94GL01280.
and 27 Related for: Methyl hypochlorite information
Methylhypochlorite is the simplest of the organic alkyl hypochlorites. It is an unstable compound that can be produced by the reaction of methanol with...
Sodium hypochlorite is an alkaline inorganic chemical compound with the formula NaOCl (also written as NaClO). It is commonly known in a dilute aqueous...
Calcium hypochlorite is an inorganic compound with chemical formula Ca(ClO)2, also written as Ca(OCl)2. It is a white solid, although commercial samples...
chlorine dissolves in water, and itself partially dissociates, forming hypochlorite anion, ClO−. HClO and ClO− are oxidizers, and the primary disinfection...
Silver hypochlorite is a chemical compound with the chemical formula AgOCl (also written as AgClO). It is an ionic compound of silver and the polyatomic...
Potassium hypochlorite is a chemical compound with the chemical formula KOCl, also written as KClO. It is the potassium salt of hypochlorous acid. It consists...
Barium hypochlorite is a chemical compound with the chemical formula Ba(OCl)2 (also written as Ba(ClO)2). It is the barium salt of hypochlorous acid. It...
Lithium hypochlorite is a chemical compound with the chemical formula of LiOCl. It is the lithium salt of hypochlorous acid. It consists of lithium cations...
Acetyl hypochlorite, also known as chlorine acetate, is a chemical compound with the formula CH3COOCl. It is a photosensitive colorless liquid that is...
completely, e.g. through the use of sodium hypochlorite (NaClO, common bleach) or hydrogen peroxide. Reduction of methyl violet occurs in microorganisms but...
to the steric protection provided by the four methyl groups adjacent to the aminoxyl group. These methyl groups serve as inert substituents, whereas any...
Bleaching with hypochlorite generates halogenated compounds in side reactions; chloroform is the main byproduct. Sodium hypochlorite solution (chlorine...
refer to: 1-Chloroethanol 2-Chloroethanol Chloromethyl methyl ether (CMME) Ethyl hypochlorite This set index page lists chemical structure articles associated...
sodium chlorite as oxidizer. To avoid complicated oxidation reactions the hypochlorite, which is formed in the reaction, has to be removed from the reaction...
resulted in the use of chlorides and hypochlorites of lime (calcium hypochlorite) and of sodium (sodium hypochlorite) in the boyauderies. The same chemicals...
in the haloform reaction as a test for methyl ketones. The Cl-O bond length in crystalline sodium hypochlorite pentahydrate, NaOCl·5H2O, is 1.686 Å, while...
this process hydrogen peroxide is used as an oxidant instead of sodium hypochlorite, which is traditionally used to generate hydrazine. The main advantage...
reaction. The halogen used may be chlorine, bromine, iodine or sodium hypochlorite. Fluoroform (CHF3) cannot be prepared by this method as it would require...
decarbonylated via a Hofmann rearrangement of the amide group, induced by hypochlorite: C6H4(C(O)NH2)CO2Na + HOCl → C6H4NH2CO2H + NaCl + CO2 A related method...
amine product. Several reagents can be substituted for bromine. Sodium hypochlorite, lead tetraacetate, N-bromosuccinimide, and (bis(trifluoroacetoxy)iodo)benzene...
the unique capability of easily oxidizing chloride and bromide ions to hypochlorite and hypobromite. Myeloperoxidase is present in mammalian neutrophils...
Chlorine can be further oxidized to other oxides and oxyanions including hypochlorite (ClO−, the active ingredient in chlorine bleach), chlorine dioxide (ClO2)...
example to remove traces or excess amounts of chlorine, bromine, iodine, hypochlorite salts, osmate esters, chromium trioxide and potassium permanganate. Sodium...
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