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Lithium bromide information


Lithium bromide

__ Li+     __ Br
Names
IUPAC name
Lithium bromide
Identifiers
CAS Number
  • 7550-35-8 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 74049 checkY
ECHA InfoCard 100.028.582 Edit this at Wikidata
EC Number
  • 231-439-8
PubChem CID
  • 82050
RTECS number
  • OJ5755000
UNII
  • 864G646I84 checkY
CompTox Dashboard (EPA)
  • DTXSID20892222 Edit this at Wikidata
InChI
  • InChI=1S/BrH.Li/h1H;/q;+1/p-1 checkY
    Key: AMXOYNBUYSYVKV-UHFFFAOYSA-M checkY
  • InChI=1/BrH.Li/h1H;/q;+1/p-1
    Key: AMXOYNBUYSYVKV-REWHXWOFAS
SMILES
  • [Li+].[Br-]
Properties
Chemical formula
LiBr
Molar mass 86.845 g/mol[1]
Appearance White hygroscopic solid[1]
Density 3.464 g/cm3[1]
Melting point 550 °C (1,022 °F; 823 K)[1]
Boiling point 1,300 °C (2,370 °F; 1,570 K)[1]
Solubility in water
143 g/100 mL (0 °C)
166.7 g/100 mL (20 °C)
266 g/100 mL (100 °C)[2]
Solubility soluble in methanol, ethanol,[1] ether,[1] acetone
slightly soluble in pyridine
Magnetic susceptibility (χ)
−34.3·10−6 cm3/mol[3]
Refractive index (nD)
1.7843 (589 nm)[4]
Structure[5]
Crystal structure
Cubic, Pearson symbol cF8, No. 225
Space group
Fm3m
Lattice constant
a = 0.5496 nm
Thermochemistry[6]
Std molar
entropy (S298)
74.3 J/mol K
Std enthalpy of
formation fH298)
-351.2 kJ/mol
Gibbs free energy fG)
-342.0 kJ/mol
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H315, H317, H319[7]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Flash point Not-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
1800 mg/kg (oral, rat)[8]
Related compounds
Other anions
Lithium fluoride
Lithium chloride
Lithium iodide
Other cations
Sodium bromide
Potassium bromide
Rubidium bromide
Caesium bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.[9]

  1. ^ a b c d e f g Haynes, p. 4.70
  2. ^ Haynes, p. 5.169
  3. ^ Haynes, p. 4.128
  4. ^ Haynes, p. 10.249
  5. ^ Seifert, H.-J.; Dau, E. (1972). "Über die Systeme Alkalimetallbromid/Mangan(II)-bromid". Zeitschrift für Anorganische und Allgemeine Chemie. 391 (3): 302–312. doi:10.1002/zaac.19723910311.
  6. ^ Haynes, p. 5.25
  7. ^ Lithium bromide. SIgma Aldrich
  8. ^ Chambers, Michael. "ChemIDplus – 7550-35-8 – AMXOYNBUYSYVKV-UHFFFAOYSA-M – Lithium bromide – Similar structures search, synonyms, formulas, resource links, and other chemical information". chem.sis.nlm.nih.gov. Retrieved 3 April 2018.
  9. ^ Wietelmann, Ulrich and Bauer, Richard J. (2005) "Lithium and Lithium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry Wiley-VCH: Weinheim. doi:10.1002/14356007.a15_393.pub2

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