Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Lithium borohydride (LiBH4) is a borohydride and known in organic synthesis as a reducing agent for esters. Although less common than the related sodium borohydride, the lithium salt offers some advantages, being a stronger reducing agent and highly soluble in ethers, whilst remaining safer to handle than lithium aluminium hydride.[3]
^Sigma-Aldrich Product Detail Page.
^J-Ph. Soulie, G. Renaudin, R. Cerny, K. Yvon (2002-11-18). "Lithium boro-hydride LiBH4: I. Crystal structure". Journal of Alloys and Compounds. 346 (1–2): 200–205. doi:10.1016/S0925-8388(02)00521-2.{{cite journal}}: CS1 maint: multiple names: authors list (link)
^Luca Banfi, Enrica Narisano, Renata Riva, Ellen W. Baxter, "Lithium Borohydride" e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001, John Wiley & Sons. doi:10.1002/047084289X.rl061.pub2.
and 26 Related for: Lithium borohydride information
Lithiumborohydride (LiBH4) is a borohydride and known in organic synthesis as a reducing agent for esters. Although less common than the related sodium...
Borohydrides find wide use as reducing agents in organic synthesis. The most important borohydrides are lithiumborohydride and sodium borohydride, but...
soluble and nonreactive with certain molten salts such as lithium fluoride, lithiumborohydride, and sodium hydride. With a molar mass of 7.95 g/mol, it...
Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, is an inorganic compound with the formula NaBH4 (sometimes written...
stronger reducing agent than lithiumborohydride and lithium aluminium hydride. LiBHEt3 is prepared by the reaction of lithium hydride (LiH) and triethylborane...
Commons has media related to lithium aluminium hydride. Hydride Sodium borohydride Sodium hydride Sigma-Aldrich Co., Lithium aluminium hydride. Retrieved...
passivating lithium tetrafluoroborate layer on the reactant. Alternatively, a small amount of diborane product can be added to form lithiumborohydride, which...
inorganic materials families have been studied, including LiPON, lithiumborohydride, glassy, semi-crystalline, and crystalline sulfides, NASICON structured...
chloride and lithiumborohydride in a sealed tube at 120 °C: BeCl2 + 2 Li[BH4] → Be[BH4]2 + 2 LiCl The chemical formula of beryllium borohydride can be written...
for the non-catalytic conversion to amines include lithium aluminium hydride, lithiumborohydride, diborane, or elemental sodium in alcohol solvents....
Wittig was the first to synthesize a cyanoborohydride by treating lithiumborohydride with hydrogen cyanide in 1951. The corresponding compound, sodium...
effect this reaction include metal hydrides such as lithium aluminium hydride, or lithiumborohydride in mixed solvents of tetrahydrofuran and methanol...
Iron metal Lithium aluminium hydride (Note: Hydroxylamines and oximes are typical impurities.) Lithiumborohydride or sodium borohydride and trimethylsilyl...
aluminium borohydride: UF4 + 2 Al(BH4)3 → U(BH4)4 + 2 Al(BH4)F2 It may also be prepared by the solid-state reaction of uranium tetrachloride with lithium borohydride:...
group, nitrile, ester). In their handling properties, lithium aluminium hydride and sodium borohydride (and their derivatives) strongly differ. NaBH4 is far...
Another method is by reacting lithiumborohydride with iodine. As well as boron triiodide, this reaction also produces lithium iodide, hydrogen and hydrogen...
lithiumborohydride (LiBH4) as a catalyst (or reaction of borane–tetrahydrofuran or borane–(dimethyl sulfide) in the presence of sodium borohydride):...
often effected using stoichiometric hydride reagents such as sodium borohydride or lithium aluminium hydride. Oxidizing agent Reducing agent Transfer hydrogenation...
including sodium aluminium hydride, NaAlH4 ), lithium aluminium hydride, LiAlH4, and lithiumborohydride, (LiBH4). Complex metal hydrides are often soluble...
Compounds susceptible to hydrolysis often undergo protonolysis. The borohydride anion is susceptible to reaction with even weak acids, resulting protonolysis...
mild hydride-reducing agents, such as sodium borohydride, potassium borohydride, and lithiumborohydride to dihydroartemisinin (a lactol) in over 90%...
amalgam (Zn(Hg)) (reagent for Clemmensen reduction) Diborane Sodium borohydride (Na BH4) Ferrous compounds that contain the Fe2+ ion, such as iron(II)...
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