Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
Fluorine azide or triazadienyl fluoride is a yellow green gas composed of nitrogen and fluorine with formula FN3.[1] Its properties resemble those of ClN3, BrN3, and IN3.[2] The bond between the fluorine atom and the nitrogen is very weak, leading to this substance being very unstable and prone to explosion.[3] Calculations show the F–N–N angle to be around 102° with a straight line of 3 nitrogen atoms.[4]
The gas boils at –30° and melts at –139 °C.[5]
It was first made by John F. Haller in 1942.[6]
^Gipstein, Edward; John F. Haller (1966). "Absorption Spectrum of Fluorine Azide". Applied Spectroscopy. 20 (6): 417–418. Bibcode:1966ApSpe..20..417G. doi:10.1366/000370266774386470. ISSN 0003-7028. S2CID 96337253.
^Saxena, P. B. (2007-01-01). Chemistry of Interhalogen Compounds. Discovery Publishing House. p. 96. ISBN 9788183562430. Retrieved 16 June 2014.
^Rademacher, Paul; Andreas J. Bittner; Gabriele Schatte; Helge Willner (1988). "Photoelectron Spectrum and Electronic Structure of Triazadienyl Fluoride, N3F". Chemische Berichte. 121 (3): 555–557. doi:10.1002/cber.19881210325. ISSN 0009-2940.
^Peters, Nancy J. S.; Leland C. Allen; Raymond A. Firestone (1988). "Fluorine azide and fluorine nitrate: structure and bonding". Inorganic Chemistry. 27 (4): 755–758. doi:10.1021/ic00277a035. ISSN 0020-1669.
^Cite error: The named reference Gholivand1987 was invoked but never defined (see the help page).
^Lowe, Derek (21 October 2008). "Things I Won't Work With: Triazadienyl Fluoride". In the Pipeline. Retrieved 15 June 2014.
Fluorineazide or triazadienyl fluoride is a yellow green gas composed of nitrogen and fluorine with formula FN3. Its properties resemble those of ClN3...
decomposition. Azide decomposition offers a less-efficient but more pure technique: fluorineazide (which can be formed in situ via reaction of atomic fluorine with...
first identified in 1952 as the thermal decomposition product of the fluorineazide (FN3). It has the structure F−N=N−F and exists in both cis and trans...
dissociate at room temperature and above to give the radical NF2•. Fluorineazide (FN3) is very explosive and thermally unstable. Dinitrogen difluoride...
azide is prepared by passing chlorine gas over silver azide, or by an addition of acetic acid to a solution of sodium hypochlorite and sodium azide....
azide (IN3) is an explosive inorganic compound, which in ordinary conditions is a yellow solid. Formally, it is an inter-pseudohalogen. Iodine azide can...
dissociate at room temperature and above to give the radical NF2•. Fluorineazide (FN3) is very explosive and thermally unstable. Dinitrogen difluoride...
Bromine azide is an explosive inorganic compound with the formula BrN3. It has been described as a crystal or a red liquid at room temperature.[citation...
hydroperoxide and fluorine in the presence of cesium fluoride". Inorganic Chemistry. 11 (1): 193–195. doi:10.1021/ic50107a047. Journal of Fluorine Chemistry....
Fluorine and chlorine are more electrophilic and are more aggressive halogenating agents. Bromine is a weaker halogenating agent than both fluorine and...
other than fluorines, such as benzene rings, are also allowed on the cyclooctyne. This reaction has been used successfully to probe for azides in living...
atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate...
to a specific halogenoalkane. Haloalkanes containing carbon bonded to fluorine, chlorine, bromine, and iodine results in organofluorine, organochlorine...
The azo and azide groups respectively, connected to organic/inorganic compounds (e.g. silver azide AgN3, lead azide Pb(N3)2, ammonium azide NH4N3) III...
ligation with organic azides, copper-catalyzed Huisgen cycloaddition of azides, and strain promoted Huisgen cycloaddition of azides. The nucleophilic lysine...
compound is a molecule which contains two or more different halogen atoms (fluorine, chlorine, bromine, iodine, or astatine) and no atoms of elements from...
groups such as fluorine increase rate by decreasing LUMO energy and the HOMO-LUMO gap. This leads to a greater charge transfer from the azide to the fluorinated...
Lithium azide is the lithium salt of hydrazoic acid. It is an unstable and toxic compound that decomposes into lithium and nitrogen when heated. It can...
17 of the periodic table. Its properties are thus similar to those of fluorine, chlorine, and iodine, and tend to be intermediate between those of the...
hemoglobin and certain cytochromes in a manner analogous to cyanide and azide. The two principal sulfur oxides are obtained by burning sulfur: S + O2...
carbon-fluorine bonds in perfluoroalkanes, which are usually unreactive due to fluorine’s high electronegativity and the strength of the carbon-fluorine bond...
fourth halogen, being a member of group 17 in the periodic table, below fluorine, chlorine, and bromine; it is the heaviest stable member of its group....
dangerously explosive silver compounds are silver azide, AgN3, formed by reaction of silver nitrate with sodium azide, and silver acetylide, Ag2C2, formed when...
having partially filled octets and therefore acting as Lewis acids. note 1 Fluorine is too electronegative to be bonded to magnesium; it becomes an ionic salt...
room temperature. Some examples of which are solid nitrogen, triazane, azide anion and triazoles. Even longer series with eight nitrogen atoms or more...
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