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Lithium azide information


Lithium azide

  Li+       N3
Lithium azide unit cell[1]
Names
IUPAC name
lithium azide
Identifiers
CAS Number
  • 19597-69-4
3D model (JSmol)
  • Interactive image
ChemSpider
  • 79536
ECHA InfoCard 100.039.237 Edit this at Wikidata
PubChem CID
  • 88163
CompTox Dashboard (EPA)
  • DTXSID8066509 Edit this at Wikidata
InChI
  • InChI=1S/Li.N3/c;1-3-2/q+1;-1
SMILES
  • [Li+].[N-]=[N+]=[N-]
Properties
Chemical formula
LiN3
Molar mass 48.96 g·mol−1
Melting point 115 °C (239 °F; 388 K)
Solubility in water
36.12 g/100 g (10 °C)
62.07 g/100 g (15.5 °C)
66.41 g/100 g (16 °C)[2]
Solubility 20.26 g/100 g (16 °C, ethanol)[2]
Hazards
GHS labelling:
Pictograms
GHS06: Toxic
Safety data sheet (SDS) External SDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Lithium azide is the lithium salt of hydrazoic acid. It is an unstable and toxic compound that decomposes into lithium and nitrogen when heated.

  1. ^ Pringle, G. E.; Noakes, D. E. (February 1968). "The crystal structures of lithium, sodium and strontium azides". Acta Crystallogr. B. 24 (2): 262–269. doi:10.1107/S0567740868002062.
  2. ^ a b Hála, Jiri. "IUPAC-NIST Solubility Data Series. 79. Alkali and Alkaline Earth Metal Pseudohalides" (PDF). nist.gov. Archived from the original (PDF) on 1 February 2018. Retrieved 31 January 2018.

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Lithium azide

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Lithium azide is the lithium salt of hydrazoic acid. It is an unstable and toxic compound that decomposes into lithium and nitrogen when heated. It can...

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Sodium azide

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of halides. The azide functional group can thereafter be converted to an amine by reduction with either SnCl2 in ethanol or lithium aluminium hydride...

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Organic azide

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compound. The azide source is most often sodium azide (NaN3), although lithium azide (LiN3) has been demonstrated. Aliphatic alcohols give azides via a variant...

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Hydrazoic acid

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explosive and readily interact with the alkyl iodides. Azides of heavier alkali metals (excluding lithium) or alkaline earth metals are not explosive, but decompose...

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Ammonium azide

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Ammonium azide is the chemical compound with the formula [NH4]N3, being the salt of ammonia and hydrazoic acid. Like other inorganic azides, this colourless...

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Lithium aluminium hydride

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Lithium aluminium hydride, commonly abbreviated to LAH, is an inorganic compound with the chemical formula Li[AlH4] or LiAlH4. It is a white solid, discovered...

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Rubidium azide

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Rubidium azide is an inorganic compound with the formula RbN3. It is the rubidium salt of the hydrazoic acid HN3. Like most azides, it is explosive. Rubidium...

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Barium azide

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submerged in ethanol.[citation needed] Barium azide can be used to make azides of magnesium, sodium, potassium, lithium, rubidium and zinc with their respective...

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Strontium azide

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Noakes, D. E. (18 April 1967). "The Crystal Structures of Lithium, Sodium, and Strontium Azides". Acta Crystallographica. B24 (2): 262–269. doi:10.1107/S0567740868002062...

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Solubility table

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Pb(OH)4 7.229×10−11 Lithium acetate LiC2H3O2 31.2 35.1 40.8 50.6 68.6 Lithium azide LiN3 61.3 64.2 67.2 71.2 75.4 86.6 100 Lithium benzoate LiC7H5O2 38...

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Alkali metal

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corresponding alkali metal azide, which yields the metal for sodium, potassium, rubidium, and caesium and the nitride for lithium.: 77  Lithium salts have to be...

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Fluorine azide

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Fluorine azide or triazadienyl fluoride is a yellow green gas composed of nitrogen and fluorine with formula FN3. Its properties resemble those of ClN3...

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Nitrogen

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names of many nitrogen compounds, such as hydrazine and compounds of the azide ion. Finally, it led to the name "pnictogens" for the group headed by nitrogen...

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Iodine azide

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azide (IN3) is an explosive inorganic compound, which in ordinary conditions is a yellow solid. Formally, it is an inter-pseudohalogen. Iodine azide can...

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List of CAS numbers by chemical compound

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4111–54–0 LiNH2 lithium amide 7782–89–0 LiNO3 lithium nitrate 7790–69–4 LiN3 lithium azide 19597–69–4 LiNbO3 lithium niobate 12031–63–9 LiOH lithium hydroxide...

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List of inorganic compounds

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Americium(III) iodide − AmI3 Americium dioxide – AmO2 Ammonia – NH3 Ammonium azide – [NH4]N3 Ammonium bicarbonate – [NH4]HCO3 Ammonium bisulfate – [NH4]HSO4...

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Trimethylsilyl chloride

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bromide, trimethylsilyl iodide, trimethylsilyl cyanide, trimethylsilyl azide, and trimethylsilyl trifluoromethanesulfonate (TMSOTf). These compounds...

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Boron triazide

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2 B(N3)3 + 3 H2O → 6 HN3 + B2O3 Reaction with other azides like sodium azide or lithium azide yields the corresponding tetraazidoborate complexes. B(N3)3...

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Homoleptic azido compounds

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compounds in which the only anion or ligand is the azide group, -N3. The breadth of homoleptic azide compounds spans nearly the entire periodic table....

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Gas generator

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US might contain 130 grams of sodium azide. Similar gas generators are used for fire suppression. Sodium azide decomposes exothermically to sodium and...

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Hydrosilanes

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PMHS. In one study triethylsilane is used in the conversion of a phenyl azide to an aniline: In this reaction ACCN is a radical initiator and an aliphatic...

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Quinuclidone

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2-quinuclidone is a six-step affair starting from norcamphor the final step being an azide - ketone Schmidt reaction (38% yield): This compound rapidly reacts with...

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Nitride

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to but distinct from nitride is pernitride diatomic anion (N2−2) and the azide triatomic anion (N3-). Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry...

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Electrophilic amination

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hydride Azo compounds: H2/Pd Triazenes: sodium borohydride Azides: H2/Pd, H2/Pt, lithium aluminum hydride, triphenylphosphine Conversion to other nitrogen-containing...

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Haloalkane

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Haloalkanes react with ionic nucleophiles (e.g. cyanide, thiocyanate, azide); the halogen is replaced by the respective group. This is of great synthetic...

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Silyl enol ether

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one-carbon ring contractions. These reactions employ electron-deficient sulfonyl azides, which undergo chemoselective, uncatalyzed [3+2] cycloaddition to the silyl...

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Sodium oxide

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the crude product. A second method involves heating a mixture of sodium azide and sodium nitrate: 5 NaN3 + NaNO3 → 3 Na2O + 8 N2 Burning sodium in air...

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