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Ester hydrolysis information


Ester hydrolysis is an organic reaction which hydrolyzes an ester to a carboxylic acid or carboxylate, and an alcohol. It can be performed with acid as catalyst, or with base as reagent.

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Ester hydrolysis

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Ester hydrolysis is an organic reaction which hydrolyzes an ester to a carboxylic acid or carboxylate, and an alcohol. It can be performed with acid as...

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Hydrolysis

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oldest commercially practiced example of ester hydrolysis is saponification (formation of soap). It is the hydrolysis of a triglyceride (fat) with an aqueous...

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Ethyl acetate

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solvent because it is prone to hydrolysis, transesterification, and condensations. Ethyl acetate is the most common ester in wine, being the product of...

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Ester

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but forms adducts. Esterification is a reversible reaction. Esters undergo hydrolysis under acidic and basic conditions. Under acidic conditions, the...

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Esterase

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is a class of enzyme that splits esters into an acid and an alcohol in a chemical reaction with water called hydrolysis (and as such, it is a type of hydrolase)...

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Retinoid

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(i.e. palmitate or stearate). After hydrolysis, retinol is taken up by the enterocytes. Retinyl ester hydrolysis requires the presence of bile salts that...

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Lye

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its grease-dissolving abilities. Lyes decompose greases via alkaline ester hydrolysis, yielding water-soluble residues that are easily removed by rinsing...

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Lipase

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class of enzymes that catalyzes the hydrolysis of fats. Some lipases display broad substrate scope including esters of cholesterol, phospholipids, and...

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Hydrolysis constant

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molecular, being formed by combination with H and OH groups (e.g., hydrolysis of an ester to an alcohol and a carboxylic acid). In inorganic chemistry, the...

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Saponification

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retouching is the only known restoration method. Soap Saponification value Ester hydrolysis "Saponification | chemical reaction". Encyclopedia Britannica. Retrieved...

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Atracurium besilate

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and ester hydrolysis as components of the in vivo metabolic processes. The initial in vitro studies appeared to indicate a major role for ester hydrolysis...

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Transesterification

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energies of the reactant and product. Depending on reaction conditions ester hydrolysis and/or esterification will also occur, which results in some amount...

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RNA hydrolysis

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this 2’ -OH group and thus is not susceptible to base-catalyzed hydrolysis. RNA hydrolysis occurs when the deprotonated 2’ OH of the ribose, acting as a...

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Acid value

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to prolonged high temperatures (ester thermolysis) or through exposure to acids or bases (acid/base ester hydrolysis). Transesterification of waste cooking...

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Sodium hydroxide

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decompose proteins and lipids in living tissues via amide hydrolysis and ester hydrolysis, which consequently cause chemical burns and may induce permanent...

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Hydroxide

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fluoride ion F−, and the amide ion NH− 2. Ester hydrolysis under alkaline conditions (also known as base hydrolysis) R1C(O)OR2 + OH− ⇌ R1CO(O)H + −OR2 ⇌ R1CO2−...

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Reactive distillation

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useful for equilibrium-limited reactions such as esterification and ester hydrolysis reactions. Conversion can be increased beyond what is expected by the...

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Saponifiable lipid

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saponification reaction. The fatty acids are released upon base-catalyzed ester hydrolysis to form ionized salts. The primary saponifiable lipids are free fatty...

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Tetrahedral carbonyl addition compound

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intermediate in esterification, transesterification, ester hydrolysis, formation and hydrolysis of amides and peptides, hydride reductions, and other...

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Ortho ester

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be cleaved in two steps under mild conditions, mildly acidic hydrolysis yields the ester of tris(hydroxymethyl)ethane which is then cleaved using e.g...

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Guvacine

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is the N-demethylated derivative of arecaidine and the product of ester hydrolysis of guvacoline, both of which are also found in areca nuts as well....

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Tetrafluorophenyl esters

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esters (SE, Hydroxysuccinimide- or NHS-ester), but TFP esters are less susceptible to spontaneous hydrolysis during conjugation reactions. TFP esters...

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Alan Fersht

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OCLC 646400491. Fersht, Alan Roy (1968). Intramolecular Catalysis of Ester Hydrolysis (PhD thesis). University of Cambridge. (subscription required) "Sweeping...

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Equilibrium constant

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Baes, C. F.; Mesmer, R. E. (1976). "Chapter 18. Survey of Hydrolysis Behaviour". The Hydrolysis of Cations. Wiley. pp. 397–430. Schwarzenbach, G.; Flaschka...

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Boronic acid

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with borate esters. For example, phenylboronic acid is produced from phenylmagnesium bromide and trimethyl borate followed by hydrolysis PhMgBr + B(OMe)3...

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Fluticasone furoate

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formulation and shelf-life stability. Ester Hydrolysis: The furoate ester group in fluticasone furoate is susceptible to hydrolysis under certain conditions, particularly...

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Methyl pivalate

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liquid, the methyl ester of pivalic acid. The ester is well known for being resistant to hydrolysis to the parent acid. Hydrolysis can be effected with...

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Lactone

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hydrolysis of esters and lactones are about the same, the entropy of the hydrolysis of lactones is less than the entropy of straight-chained esters....

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