Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Disilane is a chemical compound with chemical formula Si2H6 that was identified in 1902 by Henri Moissan and Samuel Smiles (1877–1953). Moissan and Smiles reported disilane as being among the products formed by the action of dilute acids on metal silicides. Although these reactions had been previously investigated by Friedrich Woehler and Heinrich Buff between 1857 and 1858, Moissan and Smiles were the first to explicitly identify disilane. They referred to disilane as silicoethane. Higher members of the homologous series SinH2n+2 formed in these reactions were subsequently identified by Carl Somiesky (sometimes spelled "Karl Somieski") and Alfred Stock.
At standard temperature and pressure, disilane is a colourless, acrid gas. Disilane and ethane have similar structures, although disilane is much more reactive. Other compounds of the general formula Si2X6 (X = hydrogen, halogen, alkyl, aryl, and mixtures of these groups) are called disilanes. Disilane is a group 14 hydride.
^John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99th ed.). CRC Press. pp. 4–47. ISBN 978-1138561632.
Disilane is a chemical compound with chemical formula Si2H6 that was identified in 1902 by Henri Moissan and Samuel Smiles (1877–1953). Moissan and Smiles...
experimentally. Silicon can form sigma bonds to other silicon atoms (and disilane is the parent of this class of compounds). However, it is difficult to...
Alvarez, S (2002). "Hexakis(silyl)palladium(VI) or palladium(II with eta2-disilane ligands?". Angewandte Chemie International Edition in English. 41 (11):...
'tricarbane', and 'tetracarbane' as recommended for analogues of silane, 'disilane'; phosphane, 'triphosphane'; and sulfane, 'tetrasulfane'.{{cite book}}:...
'tricarbane', and 'tetracarbane' as recommended for analogues of silane, 'disilane'; phosphane, 'triphosphane'; and sulfane, 'tetrasulfane'." "Ethane – Compound...
which thermal stability decreasing as n increases (e.g. silane SiH4 and disilane Si2H6), as are cyclosilanes (e.g. cyclopentasilane Si5H10 and cyclohexasilane...
silane) (should not be called siliconium disilanium, Si2H+7 (protonated disilane) further silanium cations, Si nH+ 2n+3 (protonated silanes) germonium,...
also) includes silane itself but also compounds with Si-Si bonds including disilane and longer chains. Silanes with one, two, three, or four Si-H bonds are...
Methane Germane Stannane Plumbane Related compounds Phenylsilane Vinylsilane Disilane Trisilane Except where otherwise noted, data are given for materials in...
'tricarbane', and 'tetracarbane' as recommended for analogues of silane, 'disilane'; phosphane, 'triphosphane'; and sulfane, 'tetrasulfane'. Lide, David R...
5 to 10% shorter than the Si-Si single bond lengths of corresponding disilanes. A peculiarity of disilenes is the trans-bending of the substituents,...
sodium fluoride: 6 NaH + 2 BF3 → B2H6 + 6 NaF Si–Si and S–S bonds in disilanes and disulfides are also reduced. A series of reduction reactions, including...
that link the silicene hexagons use disilyne bonding alternating with disilane bonding, analogous to polyyne. Phillip F. Schewe & Ben Stein (3 September...
3-bis(2,6-diisopropylphenyl)imidazolium fluoride. In combination with disilane, germanium tetrafluoride is used for in the synthesis of SiGe. Germanium(IV)...
polymerizes. As it is heated more silane is produced, and at 178°C it yields disilane. When heated to over 250°C it decomposes to a silicon hydrogen polymer...
monosilane (SiH4) and disilane (Si2H6). Polysilicon hydrides are intermediates in the high-temperature conversion of mono- and disilane to silicon and hydrogen...
extended compared to the gas phase Si-Si bond length of 2.331Å in the parent disilane H3SiSiH3. Despite the long bond length, superdisilane exhibits thermal...
(fire diamond) 2 4 1 Related compounds Related compounds Dimethyl ether Disilane Silane Silanol Trisilane Except where otherwise noted, data are given for...
as SiH 4 and SiHCl 3 by Charles Friedel and Albert Ladenburg in 1867. Disilane (Si 2H 6) followed in 1902, when it was first made by Henri Moissan and...
They motivated this goals from recent reactivity study of silylene and disilane activating CO and isolating intermediate, hypothesizing that silica-ketenyl...
pyrolysis has been found to be more endothermic than the pyrolysis of disilane. This difference is attributed to the greater strength of the Ge-H bond...
110 °C in xylene thereby releasing its strain energy[clarification needed]. Disilane Disilyne McCarthy, M. C.; Yu, Z.; Sari, L.; Schaefer, H. F.; Thaddeus,...
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