Dispersion stabilized molecules are molecules where the London dispersion force (LDF), a non-covalent attractive force between atoms and molecules, plays a significant role in promoting the molecule's stability. Distinct from steric hindrance, dispersion stabilization has only recently been considered in depth by organic and inorganic chemists after earlier gaining prominence in protein science and supramolecular chemistry.[1] Although usually weaker than covalent bonding and other forms of non-covalent interactions like hydrogen bonding, dispersion forces are known to be a significant if not dominating stabilizing force in certain organic, inorganic, and main group molecules, stabilizing otherwise reactive moieties and exotic bonding.
^Liptrot, David J.; Power, Philip P. (2017-01-11). "London dispersion forces in sterically crowded inorganic and organometallic molecules". Nature Reviews Chemistry. 1 (1): 1–12. doi:10.1038/s41570-016-0004. ISSN 2397-3358.
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