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Copper hydride information


Copper hydride
Names
IUPAC name
Copper hydride
Other names
Copper(I) hydride
Cuprous hydride
Hydridocopper(I)
Cuprane
poly[cuprane(1)]
Identifiers
CAS Number
  • 13517-00-5
3D model (JSmol)
  • Interactive image
ChemSpider
  • 2582262 ☒N
ECHA InfoCard 100.229.864 Edit this at Wikidata
EC Number
  • 803-023-1
PubChem CID
  • 3335333
CompTox Dashboard (EPA)
  • DTXSID50391571 Edit this at Wikidata
InChI
  • InChI=1S/Cu.H checkY
    Key: JJFLDSOAQUJVBF-UHFFFAOYSA-N checkY
SMILES
  • [CuH]
Properties
Chemical formula
CuH
Molar mass 64.554 g·mol−1
Melting point 100 °C (212 °F; 373 K)[1]
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS07: Exclamation mark
Signal word
Warning
Hazard statements
H228, H315, H319, H335
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1 mg/m3 (as Cu)[2]
REL (Recommended)
TWA 1 mg/m3 (as Cu)[2]
IDLH (Immediate danger)
TWA 100 mg/m3 (as Cu)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Copper hydride is an inorganic compound with the chemical formula CuHn where n ~ 0.95.[3] It is a red solid, rarely isolated as a pure composition, that decomposes to the elements.[4] Copper hydride is mainly produced as a reducing agent in organic synthesis and as a precursor to various catalysts.[5]

  1. ^ Cite error: The named reference Fitzsimons1995 was invoked but never defined (see the help page).
  2. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0150". National Institute for Occupational Safety and Health (NIOSH).
  3. ^ Jordan, Abraham J.; Lalic, Gojko; Sadighi, Joseph P. (2016-07-25). "Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity". Chemical Reviews. 116 (15): 8318–8372. doi:10.1021/acs.chemrev.6b00366. ISSN 0009-2665. PMID 27454444.
  4. ^ Aldridge, Simon; Downs, Anthony J. (2001). "Hydrides of the Main-Group Metals: New Variations on an Old Theme". Chem. Rev. 101 (11): 3305–3366. doi:10.1021/cr960151d. PMID 11840988.
  5. ^ Donnerer, Christian; Scheler, Thomas; Gregoryanz, Eugene (4 April 2013). "High-pressure synthesis of noble metal hydrides". The Journal of Chemical Physics. 138 (13): 134507. Bibcode:2013JChPh.138m4507D. doi:10.1063/1.4798640. PMID 23574244. Archived from the original on 24 June 2013. Retrieved 20 June 2013.

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