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Pyrophoricity information


A substance is pyrophoric (from Greek: πυροφόρος, pyrophoros, 'fire-bearing') if it ignites spontaneously in air at or below 54 °C (129 °F) (for gases) or within 5 minutes after coming into contact with air (for liquids and solids).[1] Examples are organolithium compounds and triethylborane. Pyrophoric materials are often water-reactive as well and will ignite when they contact water or humid air. They can be handled safely in atmospheres of argon or (with a few exceptions) nitrogen. Class D fire extinguishers are designated for use in fires involving pyrophoric materials. A related concept is hypergolicity, in which two compounds spontaneously ignite when mixed.

  1. ^ GHS, seventh revised version. https://www.unece.org/fileadmin/DAM/trans/danger/publi/ghs/ghs_rev07/English/ST_SG_AC10_30_Rev7e.pdf

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Pyrophoricity

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creation of sparks from metals is based on the pyrophoricity of small metal particles, and pyrophoric alloys are made for this purpose. Practical applications...

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Triethylaluminium

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formula Al2(C2H5)6 (abbreviated as Al2Et6 or TEA). This colorless liquid is pyrophoric. It is an industrially important compound, closely related to trimethylaluminium...

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Spall

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debris Frangibility Friability Misnay–Schardin effect Ore dressing Pyrophoricity Runit Island Whipple shield "How M1 Tanks Work: Sabot". 7 May 2002....

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Depleted uranium

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MR-1018/7-OSD. Chapter: "PYROPHORIC METALS: Uranium". Archived from the original on 7 March 2008. in Primer on Spontaneous Heating and Pyrophoricity. DOE Handbook...

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Gulf War

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the long term safety of depleted uranium exists, including claims of pyrophoric, genotoxic, and teratogenic heavy metal effects. Many have cited its use...

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Spontaneous combustion

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autoignition. It is distinct from (but has similar practical effects to) pyrophoricity, in which a compound needs no self-heat to ignite. The correct storage...

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Silane

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moisture and to the catalytic effects of container surfaces causes its pyrophoricity. Above 420 °C, silane decomposes into silicon and hydrogen; it can therefore...

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Diborane

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chemical compound with the formula B2H6. It is a toxic, colorless, and pyrophoric gas with a repulsively sweet odor. Given its simple formula, borane is...

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Aluminium

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tools). Aluminium is used because of its corrosion resistance, non-pyrophoricity, and mechanical strength. The great majority (about 90%) of aluminium...

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Sodium

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temperature, the coolant does not solidify in the pipes. In this case, the pyrophoricity of potassium requires extra precautions to prevent and detect leaks...

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Plutonium

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PMC 5485009. PMID 28371148. "Primer on Spontaneous Heating and PyrophoricityPyrophoric Metals – Plutonium". Washington (DC): U.S. Department of Energy...

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Lead

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chemically inert in the air. Finely powdered lead, as with many metals, is pyrophoric, and burns with a bluish-white flame. Fluorine reacts with lead at room...

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M202 FLASH

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often mistaken for napalm [citation needed], is in fact TPA (thickened pyrophoric agent). TPA is triethylaluminum (TEA) thickened with polyisobutylene,...

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Ferrocerium

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Ferrocerium (also known in Europe as Auermetall) is a synthetic pyrophoric alloy of mischmetal (cerium, lanthanum, neodymium, other trace lanthanides and...

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Arsenic

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simplest arsenic compounds is the trihydride, the highly toxic, flammable, pyrophoric arsine (AsH3). This compound is generally regarded as stable, since at...

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Trimethylaluminium

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as Al2Me6 or TMA), as it exists as a dimer. This colorless liquid is pyrophoric. It is an industrially important compound, closely related to triethylaluminium...

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Coal

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9 September 2005. Lyman, Robert M.; Volkmer, John E. (March 2001). "Pyrophoricity (spontaneous combustion) of Powder River Basin coals: Considerations...

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Fire striker

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angle in order to cleave or shave off small particles of metal. The pyrophoricity of the steel results in the shavings oxidising in the air. The molten...

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Phosphorus

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also called yellow phosphorus. White phosphorus is highly flammable and pyrophoric (self-igniting) in air; it faintly glows green and blue in the dark when...

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NFPA 704

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readily (e.g., gasoline, acetylene, propane, hydrogen gas, diborane). Includes pyrophoric substances. Flash point below room temperature at 22.8 °C (73 °F)....

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Iron

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of iron. Iron is by far the most reactive element in its group; it is pyrophoric when finely divided and dissolves easily in dilute acids, giving Fe2+...

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Lithium

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solution form. These reagents are highly reactive, and are sometimes pyrophoric. Like its inorganic compounds, almost all organic compounds of lithium...

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Autoignition temperature

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ignite in a normal atmosphere at naturally ambient temperatures are termed pyrophoric. Autoignition temperatures of liquid chemicals are typically measured...

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Ghost in the Shell

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Kidōtai: Arise - Alternative Architecture. An additional fifth OVA titled Pyrophoric Cult, originally premiering in the Alternative Architecture broadcast...

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Falcon 9

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Every Merlin engine produces 854 kN (192,000 lbf) of thrust. They use a pyrophoric mixture of triethylaluminum-triethylborane (TEA-TEB) as an engine igniter...

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Alkali metal

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KC36, KC48 and finally KC60. KC8 is a very strong reducing agent and is pyrophoric and explodes on contact with water. While the larger alkali metals (K...

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Fire extinguisher

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/ PYROKYL is a specialty variation of sodium bicarbonate for fighting pyrophoric (ignites on contact with air) liquid fires. In addition to sodium bicarbonate...

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Potassium

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Potassium is a chemical element; it has symbol K (from Neo-Latin kalium) and atomic number 19. It is a silvery white metal that is soft enough to easily...

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Strontium

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color with the formation of the oxide. Finely powdered strontium metal is pyrophoric, meaning that it will ignite spontaneously in air at room temperature...

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