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Hydrogen bromide information


Hydrogen bromide
Skeletal formula of hydrogen bromide with the explicit hydrogen and a measurement added
Ball-and-stick model of hydrogen bromide
Ball-and-stick model of hydrogen bromide
Names
IUPAC name
Hydrogen bromide
Preferred IUPAC name
Bromane[1]
Identifiers
CAS Number
  • 10035-10-6 checkY
3D model (JSmol)
  • Interactive image
Beilstein Reference
3587158
ChEBI
  • CHEBI:47266 checkY
ChEMBL
  • ChEMBL1231461 ☒N
ChemSpider
  • 255 checkY
ECHA InfoCard 100.030.090 Edit this at Wikidata
EC Number
  • 233-113-0
KEGG
  • C13645 ☒N
MeSH Hydrobromic+Acid
PubChem CID
  • 260
RTECS number
  • MW3850000
UNII
  • 3IY7CNP8XJ ☒N
UN number 1048
CompTox Dashboard (EPA)
  • DTXSID0029713 Edit this at Wikidata
InChI
  • InChI=1S/BrH/h1H checkY
    Key: CPELXLSAUQHCOX-UHFFFAOYSA-N checkY
SMILES
  • Br
Properties
Chemical formula
HBr
Molar mass 80.91 g/mol
Appearance Colorless gas
Odor Acrid
Density 3.307 g/L (25 °C)[2]
Melting point −86.9 °C (−124.4 °F; 186.2 K)
Boiling point −66.8 °C (−88.2 °F; 206.3 K)
Solubility in water
221 g/100 mL (0 °C)
204 g/100 mL (15 °C)
193 g/100 mL (20 °C)
130 g/100 mL (100 °C)
Solubility Soluble in alcohol, organic solvents
Vapor pressure 2.308 MPa (at 21 °C)
Acidity (pKa) −8.8 (±0.8);[3] ~−9[4]
Basicity (pKb) ~23
Conjugate acid Bromonium
Conjugate base Bromide
Refractive index (nD)
1.325[citation needed]
Structure
Molecular shape
Linear
Dipole moment
820 mD
Thermochemistry
Heat capacity (C)
350.7 mJ/(K·g)
Std molar
entropy (S298)
198.696–198.704 J/(K·mol)[5]
Std enthalpy of
formation fH298)
−36.45...−36.13 kJ/mol[5]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Highly corrosive
GHS labelling:
Pictograms
GHS05: Corrosive GHS07: Exclamation mark
Signal word
Danger
Hazard statements
H314, H335
Precautionary statements
P261, P280, P305+P351+P338, P310
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard COR: Corrosive; strong acid or base. E.g. sulfuric acid, potassium hydroxide
3
0
0
COR
Lethal dose or concentration (LD, LC):
LC50 (median concentration)
2858 ppm (rat, 1 h)
814 ppm (mouse, 1 h)[7]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 3 ppm (10 mg/m3)[6]
REL (Recommended)
TWA 3 ppm (10 mg/m3)[6]
IDLH (Immediate danger)
30 ppm[6]
Safety data sheet (SDS) hazard.com

physchem.ox.ac.uk

Related compounds
Related compounds
Hydrogen fluoride
Hydrogen chloride
Hydrogen iodide
Hydrogen astatide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves in water, forming hydrobromic acid, which is saturated at 68.85% HBr by weight at room temperature. Aqueous solutions that are 47.6% HBr by mass form a constant-boiling azeotrope mixture that boils at 124.3 °C (255.7 °F). Boiling less concentrated solutions releases H2O until the constant-boiling mixture composition is reached.

Hydrogen bromide, and its aqueous solution, hydrobromic acid, are commonly used reagents in the preparation of bromide compounds.

Molecular structure and dipole moment of hydrogen bromide (HBr)
  1. ^ Favre, Henri A.; Powell, Warren H., eds. (2014). Nomenclature of Organic Chemistry: IUPAC Recommendations and Preferred Names 2013. Cambridge: The Royal Society of Chemistry. p. 131. ISBN 9781849733069.
  2. ^ Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0487-3.
  3. ^ Trummal, Aleksander; Lipping, Lauri; Kaljurand, Ivari; Koppel, Ilmar A; Leito, Ivo (2016). "Acidity of Strong Acids in Water and Dimethyl Sulfoxide". The Journal of Physical Chemistry A. 120 (20): 3663–9. Bibcode:2016JPCA..120.3663T. doi:10.1021/acs.jpca.6b02253. PMID 27115918. S2CID 29697201.
  4. ^ Perrin, D. D. Dissociation constants of inorganic acids and bases in aqueous solution. Butterworths, London, 1969.
  5. ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. ISBN 978-0-618-94690-7.
  6. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0331". National Institute for Occupational Safety and Health (NIOSH).
  7. ^ "Hydrogen bromide". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).

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Hydrogen bromide

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oxidation of traces of bromide (Br−) to bromine (Br2). Ammonium bromide can be prepared by the direct action of hydrogen bromide on ammonia. NH3 + HBr...

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other alkali metal bromides. Lithium hydroxide and hydrobromic acid (aqueous solution of hydrogen bromide) will precipitate lithium bromide in the presence...

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reason, experimentalists avoid brownish samples. Cyanogen bromide is hydrolyzed to form hydrogen cyanate and hydrobromic acid: ( CN ) Br + H 2 O ⟶ HOCN +...

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Halogen

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hydrogen known as the hydrogen halides: hydrogen fluoride (HF), hydrogen chloride (HCl), hydrogen bromide (HBr), hydrogen iodide (HI), and hydrogen astatide...

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Hydrogen halide

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hydrogen chloride. Hydrogen chloride, in the form of hydrochloric acid, is a major component of gastric acid. Hydrogen fluoride, chloride and bromide...

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HBR

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Henley Boat Races Housing Bank of Rwanda Hydrogen bromide (HBr) Hydrobromic acid, a solution of hydrogen bromide in water Harbor This disambiguation page...

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for most organic compounds are hypothetical. For instance, carbon and hydrogen will not directly react to form methane (CH4), so that the standard enthalpy...

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chloride analogue, thionyl chloride. It is prepared by the action of hydrogen bromide on thionyl chloride, a characteristic reaction where a stronger acid...

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of hydrogen chloride Hydrogen bromide Hydrochloride, organic salts of hydrochloric acid Hydrochlorination, addition reaction with alkenes "hydrogen chloride...

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Chemical reaction

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attacking particle. For example, in the electrophilic addition of hydrogen bromide, an electrophile (proton) attacks the double bond forming a carbocation...

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Arsonium

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arsonium bromide (AsH+ 4Br− ) and arsonium iodide (AsH+ 4I− ), which can be synthesized by reacting arsine with hydrogen bromide or hydrogen iodide. Or...

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Zinc bromide

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by reaction of zinc metal and bromine. Sublimation in a stream of hydrogen bromide also gives the anhydrous derivative. ZnBr2 crystallizes in the same...

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Deuterium bromide

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Electrophile

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List of inorganic compounds

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