Coordination sphere information

second coordination sphere consists of molecules and ions that attached in various ways to the first coordination sphere. The first coordination sphere refers...

chelation, complexation, and coordination. The central atom or ion, together with all ligands, comprise the coordination sphere. The central atoms or ion...

molecules. The latter are said to reside in the second coordination sphere. The second coordination sphere is not a well defined entity for ions with charge...

Chloride coordination sphere...

sulfate adopts the typical tetrahedral geometry. Structure of β-K2SO4. Coordination sphere of one of two types of K+ site. SO4 environment in β-K2SO4. It does...

protein. Two 2-histidines, 1 methionine and 1 cysteine present in the coordination sphere. Example for Type-I blue copper protein are plastocyanine , azurin...

said to reside in the second coordination sphere. However, for the alkali metal cations, the second coordination sphere is not well-defined as the +1...

occurrence in complexes found as discrete units in compounds and coordination spheres around atoms in crystals (where there is no discrete complex). IUPAC...

used in coordination chemistry. The template effects emphasizes the pre-organization provided by the coordination sphere, although the coordination modifies...

a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions. The resulting cyanometallate anions are often used...

Simon A. Cotton (2018). "Iron(III) Chloride and Its Coordination Chemistry". Journal of Coordination Chemistry. 71 (21): 3415–3443. doi:10.1080/00958972...

isotypic with MoS2, instead with W atoms situated in trigonal prismatic coordination sphere (in place of Mo atoms). Owing to this layered structure, WS2 forms...

reactivity to electron-deficient substrates. Furthermore, second coordination sphere hydrogen-bonding interactions give rise to faster reactions because...

rate determining step that involves release of a ligand from the coordination sphere of the metal undergoing substitution. The concentration of the substituting...

"density-gradient") centrifugation. It is isostructural with potassium salt. Coordination sphere of one of two types of Cs+ site in Cs2SO4. Environment of sulfate...

reactions often invoke ion-pairing of the entering anion in the second coordination sphere followed by dissociation of the aquo ligand. IUPAC, Compendium of...

Coordination sphere about an individual barium ion in Ba(OH)2.H2O....

that the later lanthanides have more water molecules in the second coordination sphere. Complexation with monodentate ligands is generally weak because...

1021/om00066a021. Schmidbaur, H. (1983). "Phosphorus Ylides in the Coordination Sphere of Transition Metals: An Inventory". Angewandte Chemie International...

from three histidine units. The fourth coordination site is occupied by a water molecule. The coordination sphere of the zinc ion is approximately tetrahedral...

bulk can prevent the coordination of certain ligands. Chiral ligands are useful for inducing asymmetry within the coordination sphere. Often the ligand is...

adopts the typical tetrahedral geometry. Structure of β-K2CrO4. Coordination sphere of one of two types of K+ site. The environment about the tetrahedral...

in coordination chemistry, metal ions (usually transition metal ions) exist in solution bound to ligands, In many cases, the coordination sphere defines...