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Barium hydroxide information


Barium hydroxide
Identifiers
CAS Number
  • 17194-00-2 checkY
  • 22326-55-2 (monohydrate) checkY
  • 12230-71-6 (octahydrate) checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:32592 checkY
ChemSpider
  • 26408 checkY
ECHA InfoCard 100.037.470 Edit this at Wikidata
EC Number
  • 241-234-5
Gmelin Reference
846955
PubChem CID
  • 28387
RTECS number
  • CQ9200000
UNII
  • 1OHB71MYBK checkY
  • P27GID97XM (monohydrate) checkY
  • L5Q5V03TBN (octahydrate) checkY
CompTox Dashboard (EPA)
  • DTXSID10892155 Edit this at Wikidata
InChI
  • InChI=1S/Ba.2H2O/h;2*1H2/q+2;;/p-2 checkY
    Key: RQPZNWPYLFFXCP-UHFFFAOYSA-L checkY
  • InChI=1/Ba.2H2O/h;2*1H2/q+2;;/p-2
    Key: RQPZNWPYLFFXCP-NUQVWONBAR
SMILES
  • [Ba+2].[OH-].[OH-]
Properties
Chemical formula
Ba(OH)2
Molar mass 171.34 g/mol (anhydrous)
189.355 g/mol (monohydrate)
315.46 g/mol (octahydrate)
Appearance white solid
Density 3.743 g/cm3 (monohydrate)
2.18 g/cm3 (octahydrate, 16 °C)
Melting point 78 °C (172 °F; 351 K) (octahydrate)
300 °C (monohydrate)
407 °C (anhydrous)
Boiling point 780 °C (1,440 °F; 1,050 K)
Solubility in water
mass of BaO (not Ba(OH)2):
1.67 g/100 mL (0 °C)
3.89 g/100 mL (20 °C)
4.68 g/100 mL (25 °C)
5.59 g/100 mL (30 °C)
8.22 g/100 mL (40 °C)
11.7 g/100 mL (50 °C)
20.94 g/100 mL (60 °C)
101.4 g/100 mL (100 °C)[citation needed]
Solubility in other solvents low
Basicity (pKb) 0.15 (first OH), 0.64 (second OH)[1]
Magnetic susceptibility (χ)
−53.2·10−6 cm3/mol
Refractive index (nD)
1.50 (octahydrate)
Structure
Crystal structure
octahedral
Thermochemistry[2]
Std enthalpy of
formation fH298)
−944.7 kJ·mol−1
Enthalpy of fusion fHfus)
16 kJ·mol−1
Hazards
GHS labelling:
Pictograms
GHS05: CorrosiveGHS07: Exclamation mark
Signal word
Danger
Hazard statements
H302, H314, H332, H412
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
1
1
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
308 mg/kg (rat, oral)
Safety data sheet (SDS) Fisher Scientific
Related compounds
Other anions
Barium oxide
Barium peroxide
Other cations
Calcium hydroxide
Strontium hydroxide
Supplementary data page
Barium hydroxide (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

  1. ^ "Sortierte Liste: pKb-Werte, nach Ordnungszahl sortiert. - Das Periodensystem online" (in German).
  2. ^ Lide, David R., ed. (2009). CRC Handbook of Chemistry and Physics (90th ed.). Boca Raton, Florida: CRC Press. ISBN 978-1-4200-9084-0.

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Barium hydroxide

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Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal...

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Barium chloride

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crystallized as colorless crystals. Barium chloride can in principle be prepared by the reaction between barium hydroxide or barium carbonate with hydrogen chloride...

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Endothermic process

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fusion of elements heavier than iron in supernovae Dissolving together barium hydroxide and ammonium chloride Dissolving together citric acid and baking soda...

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Hydroxide

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pure water), as are the hydroxides of the heavier alkaline earths: calcium hydroxide, strontium hydroxide, and barium hydroxide. A solution or suspension...

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Barium

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comparison). Barium hydroxide ("baryta") was known to alchemists, who produced it by heating barium carbonate. Unlike calcium hydroxide, it absorbs very...

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Radium hydroxide

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Radium hydroxide is a caustic, toxic, and corrosive substance. It is significantly more toxic than barium hydroxide (Ba(OH)2) and strontium hydroxide (Sr(OH)2)...

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Radium

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hydroxide (Ra(OH)2) is the most readily soluble among the alkaline earth hydroxides and is a stronger base than its barium congener, barium hydroxide...

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Calcium hydroxide

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Calcium hydroxide (traditionally called slaked lime) is an inorganic compound with the chemical formula Ca(OH)2. It is a colorless crystal or white powder...

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Magnesium hydroxide

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Magnesium hydroxide is an inorganic compound with the chemical formula Mg(OH)2. It occurs in nature as the mineral brucite. It is a white solid with low...

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Barium chromate

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chromate analog of baryte, BaSO4. It can be synthesized by reacting barium hydroxide or barium chloride with potassium chromate. Ba ( OH ) 2 + K 2 CrO 4 ⟶ BaCrO...

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Barium cyanide

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Barium cyanide is a chemical compound with the formula Ba(CN)2. It is synthesized by the reaction of hydrogen cyanide and barium hydroxide in water or...

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Barium borate

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temperatures. Barium borate can be prepared by reaction of an aqueous solution of boric acid with barium hydroxide. The prepared γ-barium borate contains...

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Barium ferrate

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precipitate, reducing the coprecipitation of barium hydroxide and barium carbonate as impurities. Barium ferrate is an oxidizing agent and is used as...

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Strontium hydroxide

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Strontium hydroxide, Sr(OH)2, is a caustic alkali composed of one strontium ion and two hydroxide ions. It is synthesized by combining a strontium salt...

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List of inorganic compounds

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chromate – BaCrO4 Barium ferrate – BaFeO4 Barium ferrite – BaFe12O19 Barium fluoride – BaF2 Barium hydroxide – Ba(OH)2 Barium iodide – BaI2 Barium manganate –...

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Ethylene oxide

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temperature, and beside sodium hydroxide or potassium hydroxide, calcium hydroxide, barium hydroxide, magnesium hydroxide or carbonates of alkali or alkaline...

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Baralyme

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Baralyme is a mixture of 80% calcium hydroxide and 20% barium hydroxide compounds that is used as an alternative to soda lime to absorb the exhaled carbon...

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Strong electrolyte

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Caesium hydroxide CsOH Calcium hydroxide Ca(OH)2 Strontium hydroxide Sr(OH)2 Barium hydroxide Ba(OH)2 Lithium diisopropylamide (LDA) C6H14LiN Lithium diethylamide...

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Barium perchlorate

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follows: perchloric acid and barium hydroxide or carbonate; potassium perchlorate and hydrofluosilicic acid followed with barium carbonate; boiling solution...

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Basic oxide

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produce calcium hydroxide: CaO + H2O → Ca(OH)2 Strontium oxide reacts with water to produce strontium hydroxide: SrO + H2O → Sr(OH)2 Barium oxide reacts...

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Radium compounds

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hydroxide (Ra(OH)2) is the most readily soluble among the alkaline earth hydroxides and is a stronger base than its barium congener, barium hydroxide...

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Reichert value

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saponified fat. (The hydroxide solution used in such a titration is typically made from sodium hydroxide, potassium hydroxide, or barium hydroxide.) This number...

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Polenske value

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saponified fat. (The hydroxide solution used in such a titration is typically made from sodium hydroxide, potassium hydroxide, or barium hydroxide.) It is measure...

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Cyclopentanone

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cyclic ketone is a colorless volatile liquid. Upon treatment with barium hydroxide at elevated temperatures, adipic acid undergoes ketonization to give...

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Salt metathesis reaction

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reactions to take place. For example barium thiocyanate forms when boiling a slurry of copper(I) thiocyanate and barium hydroxide in water: Ba(OH) 2 + 2CuCNS →...

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Ammonium chloride

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chloride with other chemicals are endothermic, such as its reaction with barium hydroxide and its dissolving in water. The dominant application of ammonium chloride...

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Adipic acid

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suited for intramolecular condensation reactions. Upon treatment with barium hydroxide at elevated temperatures, it undergoes ketonization to give cyclopentanone...

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