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Cyanometalate information


Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands.[1] Most are anions. Cyanide is a highly basic and small ligand, hence it readily saturates the coordination sphere of metal ions. The resulting cyanometallate anions are often used as building blocks for more complex structures called coordination polymers, the best known example of which is Prussian blue, a common dyestuff.[2]

  1. ^ Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals; Academic Press: London, 1976. ISBN 0-12-638450-9.
  2. ^ *Dunbar, K. R. and Heintz, R. A., "Chemistry of Transition Metal Cyanide Compounds: Modern Perspectives", Progress in Inorganic Chemistry, 1997, 45, 283-391.

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Cyanometalate

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Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. Most are anions. Cyanide is a highly...

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Prussian blue

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ferricyanide ((FeIII(CN)6)3−) are particularly stable and non-toxic polymeric cyanometalates due to the strong iron coordination to cyanide ions. Although cyanide...

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η2-nitrile ligands are intermediates that preceded oxidative addition. Cyanometalate – coordination compounds containing cyanide ligands (coordinating via...

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electron-rich species Fe2(CNEt)9, νC≡N = 2060, 1920, 1701, 1652 cm−l. Cyanometalate - coordination compounds containing cyanide ligands (coordinating via...

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