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Anation information


In coordination chemistry, anation is the "replacement of the ligand water by an anion in a coordination entity."[1] The term is however used more loosely to include displacement of any neutral ligand by an anion.[2] The reaction is pervasive in coordination chemistry. The reverse reaction, displacement of an anionic ligand by water, is called aquation.

  1. ^ IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "anation". doi:10.1351/goldbook.AT06766
  2. ^ Cite error: The named reference Ghosh was invoked but never defined (see the help page).

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Anation

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In coordination chemistry, anation is the "replacement of the ligand water by an anion in a coordination entity." The term is however used more loosely...

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Octahedral molecular geometry

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ligand replaces a coordinated water molecule the reaction is called an anation. The reverse reaction, water replacing an anionic ligand, is called aquation...

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Associative substitution

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resulting in net substitution. An illustrative process comes from the "anation" (reaction with an anion) of chromium(III) hexaaquo complex: [Cr(H2O)6]3+...

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Dissociative substitution

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dissociative interchange, abbreviated Id. An illustrative process comes from the "anation" (reaction with an anion) of cobalt(III) complexes: [ Co ( NH 3 ) 5 ( H...

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