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Arsenic acid information


Arsenic acid
Structural formula
Ball-and-stick model
Names
IUPAC name
Arsoric acid[1]
Other names
  • Desiccant L-10
  • Orthoarsenic acid
  • Trihydrogen arsenate
  • Zotox
Identifiers
CAS Number
  • 7778-39-4 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:18231 checkY
ChEMBL
  • ChEMBL2374288
ChemSpider
  • 229 checkY
ECHA InfoCard 100.029.001 Edit this at Wikidata
EC Number
  • 231-901-9
KEGG
  • C01478 checkY
PubChem CID
  • 234
RTECS number
  • CG0700000
UNII
  • N7CIZ75ZPN checkY
UN number 1553, 1554
CompTox Dashboard (EPA)
  • DTXSID1034341 Edit this at Wikidata
InChI
  • InChI=1S/AsH3O4/c2-1(3,4)5/h(H3,2,3,4,5) checkY
    Key: DJHGAFSJWGLOIV-UHFFFAOYSA-N checkY
  • InChI=1/AsH3O4/c2-1(3,4)5/h(H3,2,3,4,5)
    Key: DJHGAFSJWGLOIV-UHFFFAOYAY
SMILES
  • O[As+](O)([O-])O
Properties
Chemical formula
H3AsO4
Molar mass 141.942 g·mol−1
Appearance White translucent or colorless crystals, hygroscopic
Density 2.5 g/cm3
Melting point 35.5 °C (95.9 °F; 308.6 K)
Boiling point 120 °C (248 °F; 393 K) decomposes
Solubility in water
16.7 g/(100 mL)
Solubility soluble in ethanol
Vapor pressure 55 hPa (50 °C)
Acidity (pKa) pKa1 = 2.19
pKa2 = 6.94
pKa3 = 11.5
Conjugate base Arsenate
Structure
Molecular shape
Tetrahedral at arsenic atom
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Extremely toxic, carcinogenic, corrosive
GHS labelling:
Pictograms
GHS05: CorrosiveGHS06: ToxicGHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Signal word
Danger
Hazard statements
H301, H312, H314, H331, H350, H361, H410
Precautionary statements
P201, P202, P260, P261, P264, P270, P271, P273, P280, P281, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P308+P313, P310, P311, P312, P321, P322, P330, P363, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
4
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
48 mg/kg (rat, oral)

6 mg/kg (rabbit, oral)

Related compounds
Other cations
Sodium arsenate
Related compounds
  • Arsenous acid
  • Arsenic pentoxide
  • Phosphoric acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references
Three bottles of arsenic acid from the Great Exhibition: impure, pure and distilled.

Arsenic acid or arsoric acid is the chemical compound with the formula H3AsO4. More descriptively written as AsO(OH)3, this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized. Its hemihydrate form (2H3AsO4·H2O) does form stable crystals. Crystalline samples dehydrate with condensation at 100 °C.[2]

  1. ^ "Arsenic acid".
  2. ^ Holleman, A. F.; Wiberg, E. (2001). Inorganic Chemistry. San Diego: Academic Press. ISBN 0-12-352651-5.

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Arsenic acid

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Arsenic acid or arsoric acid is the chemical compound with the formula H3AsO4. More descriptively written as AsO(OH)3, this colorless acid is the arsenic...

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Arsenic

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Arsenic makes arsenic acid with concentrated nitric acid, arsenous acid with dilute nitric acid, and arsenic trioxide with concentrated sulfuric acid;...

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Arsenic poisoning

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Arsenic poisoning (or arsenicosis) is a medical condition that occurs due to elevated levels of arsenic in the body. If arsenic poisoning occurs over...

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Arsenic contamination of groundwater

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with the arsenic. Arsenic contaminated water typically contains arsenous acid and arsenic acid or their derivatives. Their names as "acids" is a formality;...

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Arsanilic acid

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Arsanilic acid, also known as aminophenyl arsenic acid or aminophenyl arsonic acid, is an organoarsenic compound, an amino derivative of phenylarsonic acid whose...

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Arsenous acid

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molecule consisting of three hydroxyl groups bonded to arsenic. The 1H NMR spectrum of arsenous acid solutions consists of a single signal consistent with...

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Organoarsenic chemistry

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the environment and human health. The parent compounds are arsane and arsenic acid. Despite their toxicity, organoarsenic biomolecules are well known. Surprising...

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Arsenic trioxide

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as ozone, hydrogen peroxide, and nitric acid does it yield arsenic pentoxide, As 2O 5 or its corresponding acid: 2 HNO3 + As2O3 + 2 H2O → 2 H3AsO4 + N2O3...

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Arsenic pentoxide

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distilling nitric acid from a mixture of potassium nitrate and arsenic trioxide. Previously Paracelsus heated a mixture of arsenic trioxide and potassium...

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Arsenic biochemistry

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Arsenic biochemistry refers to biochemical processes that can use arsenic or its compounds, such as arsenate. Arsenic is a moderately abundant element...

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Gallic acid

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putida. Oxidative coupling of gallic acid with arsenic acid, permanganate, persulfate, or iodine yields ellagic acid, as does reaction of methyl gallate...

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Arsenate

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arsenic acid H3AsO4), dihydrogen arsenate (H2AsO−4), hydrogen arsenate (HAsO2−4), or arsenate (AsO3−4). Trihydrogen arsenate is also known as arsenic...

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Skraup reaction

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violent, is typically conducted in the presence of ferrous sulfate. Arsenic acid may be used instead of nitrobenzene and the former is better since the...

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Ellagic acid

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the first person to synthesize ellagic acid by heating gallic acid with arsenic acid or silver oxide. Ellagic acid is found in oak species such as the North...

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Oxyacid

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An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one...

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Acid dissociation constant

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In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted K a {\displaystyle K_{a}} ) is a quantitative...

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Gallium arsenide

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with a hydroxamic acid ("HA"), for example: GaAs + H 2O 2 + "HA" → "GaA" complex + H 3AsO 4 + 4 H 2O This reaction produces arsenic acid. GaAs can be used...

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Arsenopyrite

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dissolved in nitric acid, it releases elemental sulfur. When arsenopyrite is heated, it produces sulfur and arsenic vapor. With 46% arsenic content, arsenopyrite...

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Arsenic compounds

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As2O3 ("white arsenic") and As2O5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts...

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Cacodylic acid

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SO3 + H2O Cacodylic acid is highly toxic by ingestion, inhalation, or skin contact. The U.S. EPA states that all forms of arsenic are a serious risk to...

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Arsenic trisulfide

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Arsenic trisulfide is the inorganic compound with the formula As2S3. It is a dark yellow solid that is insoluble in water. It also occurs as the mineral...

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Sodium arsenate

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dodecahydrate Na3AsO4.12H2O. The compound can be obtained by neutralizing arsenic acid: H3AsO4 + 3 NaOH → Na3AsO4 + 3 H2O The salt (as its dodecahydrate) is...

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Arsenic trichloride

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of hydrochloric acid and arsenic(III) sulfide. As2S3 + 6 HCl → 2 AsCl3 + 3 H2S Hydrolysis gives arsenous acid and hydrochloric acid: AsCl3 + 3 H2O →...

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Realgar

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-ɡər/ ree-AL-gar, -⁠gər), also known as ″arsenic blende″, ″ruby sulphur″ or ″ruby of arsenic″, is an arsenic sulfide mineral with the chemical formula...

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Arsine

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3 BCl3 As reported in 1775, Carl Scheele reduced arsenic(III) oxide with zinc in the presence of acid. This reaction is a prelude to the Marsh test. Alternatively...

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Chromated copper arsenate

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acid, copper oxide, and arsenic acid (USDA, 1980), with pH 1.6–2.5. The mixture is infused into wood at high pressure. In the treated wood, arsenic is...

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Marsh test

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Scheele discovered a way to change arsenic trioxide to garlic-smelling arsine gas (AsH3), by treating it with nitric acid (HNO3) and combining it with zinc...

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List of copper salts

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acid) Copper(II) arsenate Cu3(AsO4)2 Arsenate (arsenic acid) Copper(II) azide Cu(N3)2 Azide (hydrazoic acid) Copper(II) acetylacetonate Cu(O2C5H7)2 Acetylacetonate...

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