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Zirconium tetrafluoride information


Zirconium(IV) fluoride
Zirconium(IV) fluoride
Names
IUPAC names
Zirconium(IV) fluoride
Zirconium tetrafluoride
Identifiers
CAS Number
  • 7783-64-4 checkY
  • 15298-38-1 (monohydrate)
3D model (JSmol)
  • Interactive image
ChemSpider
  • 74196 checkY
ECHA InfoCard 100.029.107 Edit this at Wikidata
EC Number
  • 232-018-1
PubChem CID
  • 82216
UNII
  • 1XHF39056H
CompTox Dashboard (EPA)
  • DTXSID5064831 Edit this at Wikidata
InChI
  • InChI=1S/4FH.Zr/h4*1H;/q;;;;+4/p-4 checkY
    Key: OMQSJNWFFJOIMO-UHFFFAOYSA-J checkY
  • InChI=1/4FH.Zr/h4*1H;/q;;;;+4/p-4
    Key: OMQSJNWFFJOIMO-XBHQNQODAN
SMILES
  • F[Zr](F)(F)F
Properties
Chemical formula
ZrF4
Molar mass 167.21 g/mol
Appearance white crystalline powder
Density 4.43 g/cm3 (20 °C)
Melting point 910 °C (1,670 °F; 1,180 K)
Solubility in water
1.32 g/100mL (20 °C)
1.388 g/100mL (25 °C)
Structure
Crystal structure
Monoclinic, mS60
Space group
C12/c1, No. 15
Hazards
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
98 mg/kg (oral, mouse)
98 mg/kg (oral, rat)[1]
Safety data sheet (SDS) External MSDS
Related compounds
Other anions
Zirconium(IV) chloride
Zirconium(IV) bromide
Zirconium(IV) iodide
Other cations
Titanium(IV) fluoride
Hafnium(IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Zirconium(IV) fluoride describes members of a family inorganic compounds with the formula (ZrF4(H2O)x. All are colorless, diamagnetic solids. Anhydrous Zirconium(IV) fluoride' is a component of ZBLAN fluoride glass.[2]

  1. ^ "Zirconium compounds (as Zr)". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  2. ^ Nielsen, Ralph (2000). "Zirconium and Zirconium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a28_543. ISBN 3527306730.

and 28 Related for: Zirconium tetrafluoride information

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Zirconium tetrafluoride

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hydrofluoric acid to solutions of zirconium nitrate precipitates solid monohydrate. Hydrates of zirconium tetrafluoride can be dehydrated by heating under...

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Tetrafluoride

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Tungsten tetrafluoride, WF4 Uranium tetrafluoride, UF4, a green crystalline solid Vanadium tetrafluoride, VF4 Xenon tetrafluoride, XeF4 Zirconium tetrafluoride...

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Hafnium tetrafluoride

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Hafnium tetrafluoride is the inorganic compound with the formula HfF4. It is a white solid. It adopts the same structure as zirconium tetrafluoride, with...

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List of inorganic compounds

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Zirconium orthosilicate – ZrSiO4 Zirconium nitride – ZrN Zirconium tetrafluoride – ZrF4 Zirconium tetrahydroxide – H4O4Zr Zirconium tungstate – ZrW2O8 Zirconyl...

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Thorium

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also known. Thorium tetrafluoride has a monoclinic crystal structure like those of zirconium tetrafluoride and hafnium tetrafluoride, where the Th4+ ions...

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Berkelium

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yellow-green ionic solid and is isotypic with uranium tetrafluoride or zirconium tetrafluoride. Berkelium(III) fluoride (BkF3) is also a yellow-green...

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Thorium compounds

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monoclinic crystal structure and is isotypic with zirconium tetrafluoride and hafnium tetrafluoride, where the Th4+ ions are coordinated with F− ions...

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Glossary of chemical formulae

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F4U uranium tetrafluoride 10049-14-6 F4W tungsten tetrafluoride 13766-47-7 F4Xe xenon tetrafluoride 13709-61-0 F4Zr zirconium tetrafluoride 7783-64-4 F5I...

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Tetrabromide

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Uranium tetrabromide, UBr4 Zirconium tetrabromide, ZrBr4 Acetylene tetrabromide or Tetrabromoethane (TBE), C2H2Br4 tetrafluoride tetrachloride tetraiodide...

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Jacques Lucas

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Poulain Marcel, Lucas Jacques, Brun Pierre, « Fluoride glasses with zirconium tetrafluoride. Optical properties of a neodymium-doped glass », Materials Research...

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Fluorine

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trifluorides. Covalent bonding first comes to prominence in the tetrafluorides: those of zirconium, hafnium and several actinides are ionic with high melting...

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Nuclear fuel

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uranium aluminum, uranium zirconium, uranium silicon, uranium molybdenum, uranium zirconium hydride (UZrH), and uranium zirconium carbonitride. Any of the...

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Fluorine compounds

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solvents. The tetrafluorides show a mixture of ionic and covalent bonding. Zirconium, hafnium, plus many of the actinides form tetrafluorides with an ionic...

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Carbon compounds

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potassium thiocyanate (KSCN). The common carbon halides are carbon tetrafluoride (CF4), carbon tetrachloride (CCl4), carbon tetrabromide (CBr4), carbon...

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Noble gas

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atoms such as fluorine or oxygen, as in xenon difluoride (XeF 2), xenon tetrafluoride (XeF 4), xenon hexafluoride (XeF 6), xenon tetroxide (XeO 4), and sodium...

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Plutonium

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and chloroform. Metallic plutonium is produced by reacting plutonium tetrafluoride with barium, calcium or lithium at 1200 °C. Metallic plutonium is attacked...

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Silicon

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through the heating of recently isolated potassium metal with silicon tetrafluoride, but they did not purify and characterize the product, nor identify...

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Tin

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three heavier members are volatile molecular compounds, whereas the tetrafluoride is polymeric. All four halides are known for Sn(II) also: SnF2, SnCl...

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List of CAS numbers by chemical compound

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phosphate 13308–51–5 B2Cl4 diboron tetrachloride 13701–67–2 B2F4 diboron tetrafluoride 13965–73–6 B2H6 diboron hexahydride 19287–45–7 B2O3 diboron trioxide...

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Iodine

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[IO]+. It may be fluorinated by fluorine, bromine trifluoride, sulfur tetrafluoride, or chloryl fluoride, resulting iodine pentafluoride, which also reacts...

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Fernald Feed Materials Production Center

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MTU of intermediate compounds, such as uranium trioxide and uranium tetrafluoride. Fernald came under criticism in 1984 when it was learned that the plant...

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Lanthanum

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sulfuric acid, evolving carbon dioxide, hydrogen fluoride, and silicon tetrafluoride: the product is then dried and leached with water, leaving the early...

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Hafnium tetrachloride

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HfCl4 + CO2 Chlorination of hafnium carbide above 250 °C. Hafnium and zirconium occur together in minerals such as zircon, cyrtolite and baddeleyite....

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Praseodymium

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Br2 (g) → 2 PrBr3 (s) [green] 2 Pr (s) + 3 I2 (g) → 2 PrI3 (s) The tetrafluoride, PrF4, is also known, and is produced by reacting a mixture of sodium...

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Nuclear fuel cycle

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with four parts hydrogen fluoride resulting in more water and uranium tetrafluoride. Finally the end product of uranium hexafluoride is created by simply...

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Fluoride volatility

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Most difluorides and trifluorides have high boiling points, while most tetrafluorides and monofluorides fall in between. The term "fluoride volatility" is...

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Organofluorine chemistry

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oxygen-containing groups into fluorides. The usual reagent is sulfur tetrafluoride: RCO2H + SF4 → RCF3 + SO2 + HF A more convenient alternative to SF4...

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Niobium

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polymers with Nb-Nb bonds; for example, the black hygroscopic niobium tetrafluoride (NbF4) and brown niobium tetrachloride (NbCl4). Anionic halide compounds...

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