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Organofluorine chemistry information


Some important organofluorine compounds. A: fluoromethane
B: isoflurane
C: a CFC
D: an HFC
E: triflic acid
F: Teflon
G: PFOS
H: fluorouracil
I: fluoxetine

Organofluorine chemistry describes the chemistry of organofluorine compounds, organic compounds that contain a carbon–fluorine bond. Organofluorine compounds find diverse applications ranging from oil and water repellents to pharmaceuticals, refrigerants, and reagents in catalysis. In addition to these applications, some organofluorine compounds are pollutants because of their contributions to ozone depletion, global warming, bioaccumulation, and toxicity. The area of organofluorine chemistry often requires special techniques associated with the handling of fluorinating agents.

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Organofluorine chemistry

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Organofluorine chemistry describes the chemistry of organofluorine compounds, organic compounds that contain a carbon–fluorine bond. Organofluorine compounds...

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Fluoride

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salts and hydrofluoric acid are the main fluorides of industrial value. Organofluorine compounds are pervasive. Many drugs, many polymers, refrigerants, and...

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Electrochemical fluorination

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electrofluorination, is a foundational organofluorine chemistry method for the preparation of fluorocarbon-based organofluorine compounds. The general approach...

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Methoxyflurane

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of organic chemistry at Cornell University, was co-opted to develop such materials, because of his expertise in organofluorine chemistry. Miller and...

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DuPont Central Research

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Sharts, Organic Fluorine Chemistry, 1969, W. A. Benjamin, Inc. R.E. Banks, B.E. Smart, and J.C. Tatlow, Organofluorine Chemistry: Principles and Commercial...

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Fluorine

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tetrafluoride is formally organic, but is included here rather than in the organofluorine chemistry section – where more complex carbon-fluorine compounds are discussed...

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Fluorine compounds

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The carbon–fluorine chemical bond of the organofluorine compounds is the strongest bond in organic chemistry. Along with the low polarizability of the...

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Hydrofluoric acid

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wafers. The principal use of hydrofluoric acid is in organofluorine chemistry. Many organofluorine compounds are prepared using HF as the fluorine source...

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Antimony trifluoride

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industrial applications, it is used as a reagent in inorganic and organofluorine chemistry. In solid SbF3, the Sb centres have octahedral molecular geometry...

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Chlorodifluoromethane

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completed by 2030. R-22 is a versatile intermediate in industrial organofluorine chemistry, e.g. as a precursor to tetrafluoroethylene. Worldwide production...

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Fluoride toxicity

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ISBN 978-0-19-960563-7. O'Hagan, David (March 2008). "Understanding organofluorine chemistry. An introduction to the C–F bond". Chemical Society Reviews. 37...

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Fluorocarbon

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refrigerants, drugs, and anesthetics. Perfluorocarbons or PFCs, are organofluorine compounds with the formula CxFy, meaning they contain only carbon and...

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Gauche effect

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1223–1229. doi:10.1021/jp046290d. David O'Hagan. Understanding organofluorine chemistry. An introduction to the C−F bond. Chem. Soc. Rev. 2008 doi:10.1039/b711844a...

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Hexafluoropropylene oxide

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Hexafluoropropylene oxide (HFPO) is an intermediate used in industrial organofluorine chemistry; specifically it is a monomer for fluoropolymers. This colourless...

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Fluoropolymer

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Perfluoromethylvinylether (PMVE) Organofluorine Organohalogen Fluorosurfactant Perfluorocycloalkene (PFCA) Iddon, Brian (1985). The Magic of Chemistry. Eastleigh:BDH....

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Perfluorinated compound

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A perfluorinated compound (PFC) or perfluoro compound is an organofluorine compound that lacks C-H bonds. Many perfluorinated compounds have properties...

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Gaseous diffusion

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of organic chemistry at Cornell University, to synthesize and develop such materials, because of his expertise in organofluorine chemistry. Miller and...

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Pyrazole

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Fluorine-Containing Agrochemicals". In Szabó, Kálmán; Selander, Nicklas (eds.). Organofluorine Chemistry. Wiley. pp. 363–395. doi:10.1002/9783527825158.ch11. ISBN 9783527347117...

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Fluoromethane

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point of fluoromethane is at 44.9 °C (318.1 K) and 6.280 MPa. Organofluorine chemistry Halomethanes Record in the GESTIS Substance Database of the Institute...

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Robert Haszeldine

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was a British chemist. He is best known for his contributions to organofluorine chemistry, such as the discovery/invention of triflic acid. He was educated...

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Pydiflumetofen

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Fluorine-Containing Agrochemicals". In Szabó, Kálmán; Selander, Nicklas (eds.). Organofluorine Chemistry. Wiley. pp. 363–395. doi:10.1002/9783527825158.ch11. ISBN 978-3-527-34711-7...

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Carbon tetrafluoride

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organic chemistry. Additionally, they strengthen as more carbon–fluorine bonds are added to the same carbon. In the one carbon organofluorine compounds...

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Caesium fluoride

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KF or NaF. Caesium fluoride serves as a source of fluoride in organofluorine chemistry. Similarly to potassium fluoride, CsF reacts with hexafluoroacetone...

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Organic reaction

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reactions are found in organosilicon chemistry, organosulfur chemistry, organophosphorus chemistry and organofluorine chemistry. With the introduction of carbon-metal...

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Albert Leon Henne

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variants, bringing modern refrigeration to the masses, and pioneering organofluorine chemistry. Goldwhite, Harold (2021) Midgley Introduces Dichlorodifluoromethane...

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GenX

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GenX is a Chemours trademark name for a synthetic, short-chain organofluorine chemical compound, the ammonium salt of hexafluoropropylene oxide dimer acid...

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Caesium

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fluoride (CsF) is a hygroscopic white solid that is widely used in organofluorine chemistry as a source of fluoride anions. Caesium fluoride has the halite...

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