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Wacker process information


Net reaction in the Wacker process

The Wacker process or the Hoechst-Wacker process (named after the chemical companies of the same name) refers to the oxidation of ethylene to acetaldehyde in the presence of palladium(II) chloride and copper(II) chloride as the catalyst.[1] This chemical reaction was one of the first homogeneous catalysis with organopalladium chemistry applied on an industrial scale.[2]

  1. ^ Translated in part from de:Wacker-Verfahren.
  2. ^ Elschenbroich, C. "Organometallics" (2006) Wiley-VCH: Weinheim. ISBN 978-3-527-29390-2

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Wacker process

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The Wacker process or the Hoechst-Wacker process (named after the chemical companies of the same name) refers to the oxidation of ethylene to acetaldehyde...

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Wacker Chemie

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Wacker Chemie AG is a German multinational chemical company which was founded in 1914 by Alexander Wacker. The company is controlled by the Wacker family...

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Wacker

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Look up wacker, Wacker, or whacker in Wiktionary, the free dictionary. Wacker may refer to: Wacker von Wackenfels The Whacker, poker player Garry Bush's...

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Acetylene

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using catalysts such as mercury(II) bromide. Before the advent of the Wacker process, this reaction was conducted on an industrial scale. The polymerization...

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Acetaldehyde

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feedstock. The main method of production is the oxidation of ethene by the Wacker process, which involves oxidation of ethene using a homogeneous palladium/copper...

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Organopalladium chemistry

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it possible to carry out high pressure hydrogenation. 1956 - In the Wacker process ethylene and oxygen react to acetaldehyde with catalyst PdCl2/CuCl2...

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Acetic acid

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by distillation. Acetaldehyde may be prepared from ethylene via the Wacker process, and then oxidised as above. In more recent times, chemical company...

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Heck reaction

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palladium cycle but with different scenes and actors is observed in the Wacker process. This cycle is not limited to vinyl compounds, in the Sonogashira coupling...

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Homogeneous catalysis

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Homogeneous catalysts are also used in a variety of oxidations. In the Wacker process, acetaldehyde is produced from ethene and oxygen. Many non-organometallic...

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Catalytic cycle

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product and regeneration of the catalyst. Articles on the Monsanto process, the Wacker process, and the Heck reaction show catalytic cycles. A catalytic cycle...

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Palladium

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catalysts. For example: Heck reaction Suzuki coupling Tsuji-Trost reactions Wacker process Negishi reaction Stille coupling Sonogashira coupling When dispersed...

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Aldehyde

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Industry oxidizes methanol to formaldehyde on a large scale, and, in the Wacker process, ethylene to acetaldehyde in the presence of copper and palladium catalysts...

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Vinyl alcohol

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Retrieved 2014-08-30. Keith, J. A.; Henry, P. M. (2009). "The Mechanism of the Wacker Reaction: A Tale of Two Hydroxypalladations". Angew. Chem. Int. Ed. 48 (48):...

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Willis Tower

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building occupies a site bounded by Franklin Street, Jackson Boulevard, Wacker Drive, and Adams Street. Graham and Khan designed the building as nine square...

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Catalytic oxidation

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Catalytic oxidation are processes that rely on catalysts to introduce oxygen into organic and inorganic compounds. Many applications, including the focus...

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Alkyne

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aldehyde. This reaction was once a major industrial process but it has been displaced by the Wacker process. This reaction occurs in nature, the catalyst being...

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Wacker Neuson

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Wacker Neuson SE (formerly: Wacker Construction Equipment AG) with headquarters in Munich, Germany, is a manufacturer of construction equipment and compact...

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MDMA

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base, and then oxidize isosafrole to MDP2P. Another method uses the Wacker process to oxidize safrole directly to the MDP2P intermediate with a palladium...

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Organometallic chemistry

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aldehydes. Similarly, the Wacker process is used in the oxidation of ethylene to acetaldehyde. Almost all industrial processes involving alkene-derived...

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List of inorganic reactions

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Transmetalation Ullmann reaction Upjohn dihydroxylation Vollhardt cyclization Wacker process Water gas shift reaction Water oxidation Wurtz coupling Ziegler-Natta...

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IUPAC nomenclature for organic transformations

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named after the company responsible like in the Wacker process or the name only hints at the process involved like in the halogen dance rearrangement...

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Reductive elimination

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step and regenerates the catalyst; however, in the Heck reaction and Wacker process, reductive elimination is involved only in catalyst regeneration, as...

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Otto Wacker

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his brother, the painter and restorer Leonhard Wacker. Otto's father, Hans, was also an artist. Wacker managed to convince prominent Van Gogh experts...

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Oxidative carbonylation

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palladium catalysts. Mechanistically, these reactions resemble the Wacker process. Oxidative carbonylation, using palladium-based catalysts, allows certain...

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Transition metal alkene complex

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The mechanism of the Wacker process involves Pd-alkene complex intermediates....

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GE Digital

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storage space. Wacker Chemical Corporation is a global manufacturer of highly developed specialty chemicals. In Charleston, Tennessee, Wacker produces up...

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