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Vanadium pentafluoride information


Vanadium(V) fluoride
Names
IUPAC name
Vanadium(V) fluoride
Other names
Vanadium pentafluoride
Identifiers
CAS Number
  • 7783-72-4 checkY
3D model (JSmol)
  • Interactive image
ECHA InfoCard 100.029.112 Edit this at Wikidata
EC Number
  • 232-023-9
PubChem CID
  • 13416578
UNII
  • 1GNN7H50UE checkY
InChI
  • InChI=1S/5FH.V/h5*1H;/q;;;;;+5/p-5
    Key: NFVUDQKTAWONMJ-UHFFFAOYSA-I
SMILES
  • [F-].[F-].[F-].[F-].[F-].[V+5]
Properties
Chemical formula
VF5
Molar mass 145.934
Appearance colorless solid
Density 2.502 g/cm3 (solid)
Melting point 19.5 °C (67.1 °F; 292.6 K)
Boiling point 48.3 °C (118.9 °F; 321.4 K)
Related compounds
Other cations
Niobium(V) fluoride
Tantalum(V) fluoride
Related Vanadium compounds
Vanadium(V) oxide
Vanadium trifluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Vanadium(V) fluoride is the inorganic compound with the chemical formula VF5. It is a colorless volatile liquid[1] that freezes near room temperature. It is a highly reactive compound, as indicated by its ability to fluorinate organic substances.[2]

  1. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 989. ISBN 978-0-08-037941-8.
  2. ^ Canterford, J. H.; O'Donnell, Thomas A. (1967-03-01). "Reactivity of transition metal fluorides. IV. Oxidation-reduction reactions of vanadium pentafluoride". Inorganic Chemistry. 6 (3): 541–544. doi:10.1021/ic50049a025. ISSN 0020-1669.

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Vanadium pentafluoride

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octahedral vanadium centers. The formation enthalpy of VF5 is -1429.4 ± 0.8 kJ/mol. It is the only known pentahalide of vanadium. Vanadium pentafluoride can...

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Pentafluoride

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pentafluoride, TaF5 Technetium pentafluoride, TcF5 Tungsten pentafluoride, WF5 Uranium pentafluoride, UF5 Vanadium pentafluoride, VF5 This set index article...

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Chromium pentafluoride

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molecular geometry. It has the same crystal structure as vanadium pentafluoride. Chromium pentafluoride is strongly oxidizing, able to fluorinate the noble...

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Vanadium fluoride

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trifluoride), VF3 Vanadium(IV) fluoride (vanadium tetrafluoride), VF4 Vanadium(V) fluoride (vanadium pentafluoride), VF5 This set index article lists chemical...

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Uranium pentafluoride

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the next uranium atom. The structure is reminiscent of that for vanadium pentafluoride. In the β form, the uranium centers adopt a square antiprismatic...

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List of inorganic compounds

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oxide – V2O5 Vanadium carbide – VC Vanadium oxytrichloride (Vanadium(V) oxide trichloride) – VOCl3 Vanadium pentafluoride – VF5 Vanadium tetrachloride...

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Vanadium tetrafluoride

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disproportionation to the tri- and pentafluorides: 2 VF4 → VF3 + VF5 The structure of VF4 is related to that of SnF4. Each vanadium centre is octahedral, surrounded...

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Fluorine compounds

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somewhat volatile. Vanadium, niobium, and tantalum form pentafluorides as their highest charge-neutral fluoride. Vanadium pentafluoride is the only non-volatile...

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Group 5 element

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Group 5 is a group of elements in the periodic table. Group 5 contains vanadium (V), niobium (Nb), tantalum (Ta) and dubnium (Db). This group lies in the...

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Iodine

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fluorinating agent, behind only chlorine trifluoride, chlorine pentafluoride, and bromine pentafluoride among the interhalogens: it reacts with almost all the...

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Square pyramidal molecular geometry

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pyramidal geometry are XeOF4, and various halogen pentafluorides (XF5, where X = Cl, Br, I). Complexes of vanadium(IV), such as vanadyl acetylacetonate, [VO(acac)2]...

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Dehydrogenation

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nitriles can be accomplished using a variety of reagents, such as iodine pentafluoride (IF 5).[citation needed] In typical aromatization, six-membered alicyclic...

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List of CAS numbers by chemical compound

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vanadium(II) iodide 15513–84–5 VI3 vanadium(III) iodide 15513–94–7 VI4 vanadium(IV) iodide 15831–18–2 VN vanadium(III) nitride 24646–85–3 VO vanadium(II)...

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Bromine compounds

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forms a monofluoride and monochloride, as well as a trifluoride and pentafluoride. Some cationic and anionic derivatives are also characterised, such...

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Bromine

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forms a monofluoride and monochloride, as well as a trifluoride and pentafluoride. Some cationic and anionic derivatives are also characterised, such...

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Fluorine

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while those of titanium, vanadium, and niobium are polymeric, melting or decomposing at no more than 350 °C (660 °F). Pentafluorides continue this trend with...

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Glossary of chemical formulae

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iodine pentafluoride 7783-66-6 F5Mo molybdenum pentafluoride 13819-84-6 F5ORe rhenium monoxide pentafluoride 23377-53-9 F5P phosphorus pentafluoride 7647-19-0...

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Chlorine

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stoichiometric reactions have been characterised. Arsenic pentafluoride and antimony pentafluoride form ionic adducts of the form [ClF4]+[MF6]− (M = As, Sb)...

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Iridium

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halogens. For oxidation states +4 and above, only the tetrafluoride, pentafluoride and hexafluoride are known. Iridium hexafluoride, IrF 6, is a volatile...

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List of UN numbers 2401 to 2500

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Hexamethyleneimine UN 2494 ? (UN No. no longer in use) UN 2495 5.1 Iodine pentafluoride UN 2496 8 Propionic anhydride UN 2497 ? (UN No. no longer in use) Sodium...

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Nonmetal

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period 2 onward, in compounds such as nitric acid HN(V)O3 and phosphorus pentafluoride PCl5. Higher oxidation states in later groups emerge from period 3 onwards...

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Dioxygenyl

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reaction of dioxygen difluoride with boron trifluoride or phosphorus pentafluoride at −126 °C: 2 O2F2 + 2 BF3 → 2 O2BF4 + F2 2 O2F2 + 2 PF5 → 2 O2PF6 +...

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Tantalum

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strong high-melting-point alloys. It is a group 5 element, along with vanadium and niobium, and it always occurs in geologic sources together with the...

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Gold

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has been shown to be unexpectedly stable at normal conditions. Gold pentafluoride, along with its derivative anion, AuF−6, and its difluorine complex...

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Niobium

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compounds. The pentahalides (NbX 5) feature octahedral Nb centres. Niobium pentafluoride (NbF5) is a white solid with a melting point of 79.0 °C and niobium...

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Nitrogen

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tetrafluorohydrazine with strong fluoride-acceptors such as arsenic pentafluoride), as is ONF3, which has aroused interest due to the short N–O distance...

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Arsenic

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more well-known phosphorus compounds, and in fluorine to give arsenic pentafluoride. Arsenic makes arsenic acid with concentrated nitric acid, arsenous...

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