Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
The triphenylmethyl radical (often shorted to trityl radical) is an organic compound with the formula (C6H5)3C. It is a persistent radical. It was the first radical ever to be described in organic chemistry. Because of its accessibility, the trityl radical has been heavily exploited.[1]
^Tidwell, Thomas T. (2010). "Triarylmethyl and Related Radicals". Stable Radicals. pp. 1–31. doi:10.1002/9780470666975.ch1. ISBN 9780470666975.
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The triphenylmethylradical (often shorted to trityl radical) is an organic compound with the formula (C6H5)3C. It is a persistent radical. It was the...
chemistry is a triphenylmethyl group Ph3C, e.g. triphenylmethyl chloride (trityl chloride) and the triphenylmethylradical (trityl radical). Triphenylmethane...
It is a charged version of the triphenylmethylradical (C6H5)3C•. The name is often abbreviated to triphenylmethyl or trityl in salts, although these...
reaction via a diazonium salt Gomberg radical reaction, forming a triphenylmethylradical by treating triphenylmethyl chloride with certain metals Moses...
Triphenylcarbenium (triphenylmethyl cation), an ion consisting of a carbon atom with a positive charge connected to three phenyl groups Triphenylmethylradical, a persistent...
Moses Gomberg identifies the first organic radical (according to the modern definition), triphenylmethylradical. Johannes Rydberg refines the expression...
carbanions. Carbocations are often named -um. Examples are tropylium and triphenylmethyl cations and the cyclopentadienyl anion. Haloalkanes are a class of...
homologue hexaphenylethane, which led him to the discovery of the triphenylmethylradical. Tetraphenylborate Triphenylmethane Toluene Robbins, A.; Jeffrey...
correctly identified the triphenylmethylradical, the first persistent radical to be discovered, and is thus known as the founder of radical chemistry. The work...
dissociation of pentaphenylethane into triphenylmethyl and diphenylmethyl radicals was reversible and that persistent triphenylmethyl did not self terminate and transient...
species that will dissociate). While the trivalent triphenylmethylradical, which was the first organic radical described, has been known for over 100 years...
previous tri-valent carbon free radicals, such as triphenylmethyl. His interest in the stability of tri-valent carbon free-radical compounds brought him to publish...
reactive organic intermediates and stable radicals discovered by Moses Gomberg in 1900 (compounds with triphenylmethyl group). Ketenes are highly electrophilic...
doi:10.1021/ja01638a012. Bryant E. Rossiter and Michael O. Frederick "Triphenylmethyl Hydroperoxide" E-EROS Encyclopedia of Reagents for Organic Synthesis...
(1910). "Ueber Triphenylmethyl und Analoga des Triphenylmethyls in der Biphenylreihe" [On triphenylmethyl and analogues of triphenylmethyl in the biphenyl...
alkyl group Tf: triflyl (trifluoromethanesulfonyl) Tr, Trt: trityl (triphenylmethyl) Ts, Tos: tosyl (para-toluenesulfonyl) – (Ts also used for the element...
triphenylmethanol gives deep-yellow solutions in concentrated sulfuric acid. Triphenylmethyl chloride similarly formed orange complexes with aluminium and tin chlorides...
Delicate Balance between Pauli Repulsion and London Dispersion with Triphenylmethyl Derivatives". Journal of the American Chemical Society. 140 (43): 14421–14432...
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