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Triphenylmethyl hexafluorophosphate information


Triphenylmethyl hexafluorophosphate
Names
IUPAC name
Triphenylcarbenium hexafluorophosphate
Systematic IUPAC name
Diphenylmethylbenzene hexafluoridophosphate
Other names
  • Triphenylcarbenium hexafluorophosphate(V)
  • Trityl hexafluorophosphate
  • Tritylium hexafluorophosphate
Identifiers
CAS Number
  • 437-17-2 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 2006130
ECHA InfoCard 100.006.467 Edit this at Wikidata
EC Number
  • 207-112-0
PubChem CID
  • 2723954
CompTox Dashboard (EPA)
  • DTXSID40883238 Edit this at Wikidata
InChI
  • InChI=1S/C19H15.F6P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7(2,3,4,5)6/h1-15H;/q+1;-1
    Key: IBTFOFOFRZKIJU-UHFFFAOYSA-N
SMILES
  • c1ccc(cc1)[C+](c1ccccc1)c1ccccc1.F[P-](F)(F)(F)(F)F
Properties
Chemical formula
[(C6H5)3C]+[PF6]
Molar mass 388.293 g·mol−1
Appearance Brown powder
Melting point 145 °C (293 °F; 418 K)
Hazards
GHS labelling:
Pictograms
GHS05: Corrosive
Signal word
Danger
Hazard statements
H314
Precautionary statements
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
Safety data sheet (SDS) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Triphenylmethyl hexafluorophosphate (also triphenylcarbenium hexafluorophosphate, trityl hexafluorophosphate, or tritylium hexafluorophosphate) is an organic salt with the formula [(C6H5)3C]+[PF6], consisting of the triphenylcarbenium cation [(C6H5)3C]+ and the hexafluorophosphate anion [PF6].[1]

Triphenylmethyl hexafluorophosphate is a brown powder that hydrolyzes readily to triphenylmethanol. It is used as a catalyst and reagent in organic syntheses.[2]

  1. ^ Triphenylcarbenium hexafluorophosphate from PubChem
  2. ^ Urch, C. (2001). "Triphenylmethyl Hexafluorophosphate". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rt363f. ISBN 0471936235.

and 11 Related for: Triphenylmethyl hexafluorophosphate information

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Triphenylmethyl hexafluorophosphate

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Triphenylmethyl hexafluorophosphate (also triphenylcarbenium hexafluorophosphate, trityl hexafluorophosphate, or tritylium hexafluorophosphate) is an organic...

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Triphenylmethyl chloride

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(C6H5)3CCl + Zn → ((C6H5)3C)2 + ZnCl2 Triphenylmethyl radical Triphenylmethane Triphenylmethyl hexafluorophosphate Triphenylmethanol Gomberg's dimer "Archived...

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Carbenium ion

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compounds triphenylmethyl hexafluorophosphate [C(C 6H 5) 3]+ [PF 6]− , triphenylmethyl tetrafluoroborate [C(C 6H 5) 3]+ [BF 4]− , and triphenylmethyl perchlorate...

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Triphenylcarbenium

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exists in important chemical reagents and catalysts such as triphenylmethyl hexafluorophosphate [(C6H5)3C]+[PF6]−. Related salts are known with diverse anions...

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Triphenylmethyl radical

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Vrije Universiteit Amsterdam published proton NMR data. Triphenylmethyl hexafluorophosphate Triphenylmethane Triarylmethane dye Trivalent group 14 radicals...

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Triphenylmethane

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Tetraphenylmethane Triphenylmethanol Triphenylmethyl chloride Triphenylmethyl hexafluorophosphate Triphenylmethyl radical "Triphenylmethane | 519-73-3"...

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List of organic salts

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Salts of morphine Monosodium glutamate Trolamine salicylate Triphenylmethyl hexafluorophosphate Choline chloride Copper ibuprofenate Homatropine methylbromide...

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Carbocation

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2013. doi:10.1016/j.tet.2012.10.042. Urch, C. (2001). "Triphenylmethyl Hexafluorophosphate". Encyclopedia of Reagents for Organic Synthesis. doi:10...

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Cyclopentadienyliron dicarbonyl dimer

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Thus, hydride abstraction from Fp–alkyl compounds using triphenylmethyl hexafluorophosphate affords [Fp(α-alkene)]+ complexes. FpNa + RCH2CH2I → FpCH2CH2R...

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Rhodocene

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salts include decamethylrhodocenium hexafluorophosphate [(η5-C5Me5)2Rh]PF6, decaisopropylrhodocenium hexafluorophosphate [(η5-C5iPr5)2Rh]PF6, and octaphenylrhodocenium...

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Tropylium tetrafluoroborate

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with phosphorus pentachloride, followed by tetrafluoroboric acid. Triphenylmethyl chloride, also known as trityl chloride. Kenneth Conrow (1963). "Tropylium...

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