230 °C (446 °F; 503 K) (at 20 mmHg) and 374.3 °C (at 760 mmHg)
Solubility
soluble in chloroform, benzene, acetone,[1] ether, THF, hexane[2]
Hazards
Flash point
177.9 °C (352.2 °F; 451.0 K)
Safety data sheet (SDS)
Corvine Chemicals MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound
Triphenylmethyl chloride or trityl chloride (TrCl) is a white solid with the chemical formula C19H15Cl. It is an alkyl halide, sometimes used to introduce the trityl protecting group.
^"Archived copy". Archived from the original on 2013-01-24. Retrieved 2014-01-08.{{cite web}}: CS1 maint: archived copy as title (link)
^"Trityl chloride | CAS 76-83-5".
and 25 Related for: Triphenylmethyl chloride information
Triphenylmethylchloride or trityl chloride (TrCl) is a white solid with the chemical formula C19H15Cl. It is an alkyl halide, sometimes used to introduce...
in organic chemistry is a triphenylmethyl group Ph3C, e.g. triphenylmethylchloride (trityl chloride) and the triphenylmethyl radical (trityl radical)...
has been heavily exploited. It can be prepared by homolysis of triphenylmethylchloride 1 by a metal like silver or zinc in benzene or diethyl ether. The...
organic syntheses. Triphenylmethyl hexafluorophosphate can be prepared by combining silver hexafluorophosphate with triphenylmethylchloride: Ag+[PF6]− + (C6H5)3CCl...
although these names also denote the chemical group in compounds like triphenylmethylchloride that do not contain the cation. Triphenylcarbenium is a relatively...
alcohol. For example it reacts with acetyl chloride, not to give the ester, but triphenylmethylchloride: Ph3COH + MeCOCl → Ph3CCl + MeCO2H The three...
diazonium salt Gomberg radical reaction, forming a triphenylmethyl radical by treating triphenylmethylchloride with certain metals Moses Gomberg (1866–1947)...
concentrated sulfuric acid. Triphenylmethylchloride similarly formed orange complexes with aluminium and tin chlorides. In 1902, Adolf von Baeyer recognized...
pentachloride, followed by tetrafluoroboric acid. Triphenylmethylchloride, also known as trityl chloride. Kenneth Conrow (1963). "Tropylium Tetrafluoroborate"...
1002/047084289X.rs040 W.4r B. Renfrow Jr and C. R. Hauser (1993). "Sodium triphenylmethyl". Organic Syntheses{{cite journal}}: CS1 maint: numeric names: authors...
formula (C6H5)3CSH. It is the thiol derivative of the bulky substituent triphenylmethyl (called trityl). The compound forms a number of unusual derivatives...
stable radicals discovered by Moses Gomberg in 1900 (compounds with triphenylmethyl group). Ketenes are highly electrophilic at the carbon atom bonded...
prepare hexaphenylethane (5), Gomberg attempted a Wurtz coupling of triphenylmethylchloride (1). Elemental analysis of the resultant white crystalline solid...
hydrogen chloride. This methodology has been utilized to synthesize numerous substituted phosphaalkynes, including the methyl, vinyl, chloride, and fluoride...
(1910). "Ueber Triphenylmethyl und Analoga des Triphenylmethyls in der Biphenylreihe" [On triphenylmethyl and analogues of triphenylmethyl in the biphenyl...
carbanions. Carbocations are often named -um. Examples are tropylium and triphenylmethyl cations and the cyclopentadienyl anion. Haloalkanes are a class of...
Reagents: The Crystal Structures of [Mg(anthracene)(THF)3] and [Mg(triphenylmethyl)Br(OEt2)2]". Journal of Organometallic Chemistry. 341 (1–3): 39. doi:10...
doi:10.1021/ja01638a012. Bryant E. Rossiter and Michael O. Frederick "Triphenylmethyl Hydroperoxide" E-EROS Encyclopedia of Reagents for Organic Synthesis...
Bn group is widely used in sugar and nucleoside chemistry. Trityl (triphenylmethyl, Tr) — Removed by acid and hydrogenolysis p-Methoxybenzyl ether (PMB) —...
Ayres, Erle B.; Hauser, Charles R. (January 1948). "Rearrangement of N-Triphenylmethyl-O-benzylhydroxylamine by Means of Potassium Amide of Boron Trifluoride"...
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