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Sulfuryl information


The structure of the sulfuryl group

In inorganic chemistry, the sulfuryl group is a functional group consisting of a sulfur atom covalently bound to two oxygen atoms (S(=O)2X2).

It occurs in compounds such as sulfuryl chloride, SO2Cl2 and sulfuryl fluoride, SO2F2.

In organic chemistry, this group is found in sulfones (RSO2R′) and sulfonyl halides (RSO2X), where it is called the sulfonyl group.

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Sulfuryl fluoride

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Sulfuryl fluoride (also spelled sulphuryl fluoride) is an inorganic compound with the formula SO2F2. It is an easily condensed gas and has properties more...

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Sulfuryl chloride

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Sulfuryl chloride is an inorganic compound with the formula SO2Cl2. At room temperature, it is a colorless liquid with a pungent odor. Sulfuryl chloride...

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Sulfuryl

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In inorganic chemistry, the sulfuryl group is a functional group consisting of a sulfur atom covalently bound to two oxygen atoms (S(=O)2X2). It occurs...

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Sulfuryl diazide

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Sulfuryl diazide or sulfuryl azide is a chemical compound with the molecular formula SO2(N3)2. It was first described in the 1920s when its reactions with...

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Sulfuryl chloride fluoride

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Sulfuryl chloride fluoride is a chemical compound with the formula SO2ClF. It is a colorless, easily condensed gas. It is a tetrahedral molecule. Liquified...

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Thionyl chloride

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is sometimes confused with sulfuryl chloride, SO2Cl2, but the properties of these compounds differ significantly. Sulfuryl chloride is a source of chlorine...

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Fumigation

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prevents them from escaping into the neighborhood. It is commonly used for sulfuryl fluoride for the treatment of termites. Fumigation of hospital rooms with...

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Sulfamide

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and structure H2N−S(=O)2−NH2. Sulfamide is produced by the reaction of sulfuryl chloride with ammonia. Sulfamide was first prepared in 1838 by the French...

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Chloride

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anion. Other examples of covalent chlorides are carbon tetrachloride CCl4, sulfuryl chloride SO2Cl2 and monochloramine NH2Cl. A chloride ion (diameter 167 pm)...

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Sulfone

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In organic chemistry, a sulfone is a organosulfur compound containing a sulfonyl (R−S(=O)2−R’) functional group attached to two carbon atoms. The central...

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Sulfur dioxide

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useful reducing agent. It is oxidized by halogens to give the sulfuryl halides, such as sulfuryl chloride: SO2 + Cl2 → SO2Cl2 Sulfur dioxide is the oxidising...

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Sulfur

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dichloride, and higher chlorosulfanes arise from the chlorination of sulfur. Sulfuryl chloride and chlorosulfuric acid are derivatives of sulfuric acid; thionyl...

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Environmental toxicology

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Finally, in 1999 the birds were taken off the U.S endangered species list. Sulfuryl fluoride is an insecticide that is broken down into fluoride and sulfate...

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Sulfonyl group

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group −S(=O)2− is not connected to any carbon atoms, it is referred to as sulfuryl. The names of sulfonyl groups typically end in -syl, such as:: 497  Sulfonyl...

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Iodine

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nitric oxide, and sulfur dioxide (to phosgene, nitrosyl chloride, and sulfuryl chloride respectively), iodine will not do so. Furthermore, iodination...

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Sulfamoyl fluoride

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fluorides can be made by treating secondary amines with sulfuryl fluoride (SO2F2) or sulfuryl chloride fluoride (SO2ClF). Cyclic secondary amines work...

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Catechol

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gives the cyclic chlorophosphonite or chlorophosphonate, respectively; sulfuryl chloride gives the sulfate; and phosgene (COCl2) gives the carbonate: C6H4(OH)2...

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Dimethyl sulfide

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sulfide by reduction of dimethylsulfoxide. With chlorinating agents such as sulfuryl chloride, dimethyl sulfide converts to chloromethyl methyl sulfide: SO2Cl2...

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Selenium

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dichloride. Metastable solutions of selenium dichloride can be prepared from sulfuryl chloride and selenium (reaction of the elements generates the tetrachloride...

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Bromine

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used (in housing fumigation they have been replaced by such compounds as sulfuryl fluoride, which contain neither the chlorine or bromine organics which...

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Chloropicrin

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an indicator and repellent when fumigating residences for insects with sulfuryl fluoride which is an odorless gas. Chloropicrin's mode of action is unknown...

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Ethylamine

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primary alkyl amine, such as acylation and protonation. Reaction with sulfuryl chloride followed by oxidation of the sulfonamide give diethyldiazene,...

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Organochlorine chemistry

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chloride (SOCl2) or phosphorus pentachloride (PCl5), but also commonly with sulfuryl chloride (SO2Cl2) and phosphorus trichloride (PCl3): ROH + SOCl2 → RCl...

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Acetyl chloride

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such as phosphorus trichloride (PCl3), phosphorus pentachloride (PCl5), sulfuryl chloride (SO2Cl2), phosgene, or thionyl chloride (SOCl2). However, these...

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Oxygen difluoride

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→ SO3 + F2 However, in the presence of UV radiation, the products are sulfuryl fluoride (SO2F2) and pyrosulfuryl fluoride (S2O5F2): OF2 + 2 SO2 → S2O5F2...

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Phosphorus pentachloride

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a source of Cl2. For oxidative chlorinations on the laboratory scale, sulfuryl chloride is often preferred over PCl5 since the gaseous SO2 by-product...

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Ethylene oxide

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dichloro derivatives of ethylene oxide can be obtained by combined action of sulfuryl chloride (SOCl2) and pyridine and of triphenylphosphine and carbon tetrachloride...

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Chlorophorus annularis

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Although methyl bromide is effective, it is an ozone depleting chemical. Sulfuryl fluoride is also effective and does not have that problem. "Chlorophorus...

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Chlorosulfuric acid

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traditional. It is an intermediate, chemically and conceptually, between sulfuryl chloride (SO2Cl2) and sulfuric acid (H2SO4). The compound is rarely obtained...

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