Sulfurfluoride may refer to any of the following sulfurfluorides: Sulfur hexafluoride, SF6 Disulfur decafluoride, S2F10 Sulfur tetrafluoride, SF4 Disulfur...
the discoverers Henri Moissan and Paul Lebeau in 1901. Some other sulfurfluorides are cogenerated, but these are removed by heating the mixture to disproportionate...
pseudorotation. At the laboratory scale, fluorination of elemental sulfur with cobaltic fluoride suffices: S + 4CoF3 → SF4 + 4CoF2 For larger-scale syntheses...
prepared by direct reaction of fluorine with sulfur dioxide: SO2 + F2 → SO2F2 On a laboratory scale, sulfuryl fluoride has been conveniently prepared from 1...
from the reaction. Silver fluoride and platinum are capable of catalyzing the reaction. It can also be formed by heating sulfur hexafluoride with air to...
generated by the reaction of sulfur dichloride and potassium fluoride or mercury(II) fluoride at low pressures: SCl2 + 2 KF → SF2 + 2 KCl SCl2 + HgF2 → SF2...
Whytlaw-Gray. Each sulfur atom of the S2F10 molecule is octahedral, and surrounded by five fluorine atoms and one sulfur atom. The two sulfur atoms are connected...
example, sulfur hexafluoride and carbon tetrafluoride are not sources of fluoride ions under ordinary conditions. The systematic name fluoride, the valid...
(SbF5), forming fluoroantimonic acid. Hydrogen fluoride is typically produced by the reaction between sulfuric acid and pure grades of the mineral fluorite:...
chlorides, sulfur chlorides, and phosphorus chloride. Like other fluorides, sodium fluoride finds use in desilylation in organic synthesis. Sodium fluoride can...
ethylene to sulfur dichloride: SCl2 + 2 C2H4 → (ClC2H4)2S SCl2 is also a precursor to several inorganic sulfur compounds. Treatment with fluoride salts gives...
PMID 21366337. Irikura, Karl K. (1995). "Structure and thermochemistry of sulfurfluorides SFn (n = 1–5) and their ions SF+ n (n = 1–5)". The Journal of Chemical...
most [economically] important sulfur oxide". It is prepared on an industrial scale as a precursor to sulfuric acid. Sulfur trioxide exists in several forms...
Fluoroantimonic acid is a mixture of hydrogen fluoride and antimony pentafluoride, containing various cations and anions (the simplest being H 2F+ and...
Fluoride toxicity is a condition in which there are elevated levels of the fluoride ion in the body. Although fluoride is safe for dental health at low...
fluorination of sulfur dioxide: SO2 + PF5 → SOF2 + POF3 Thionyl fluoride arises as a fleeting intermediate from the decomposition of sulfur hexafluoride...
tetrafluorohydrazine). Sulfur chloropentafluoride can be synthesized by several routes, starting from two lower sulfurfluorides, sulfur tetrafluoride and...
such as sulfur hexafluoride, are stable and well-known. Sulfur tetrafluoride is also a well-known sulfurfluoride. Certain selenium fluorides, such as...
also produces the intermediate F3SSSF3. hydrogen fluoride catalyses disproportionation to sulfur and sulfur tetrafluoride by forming a reactive intermediate...
composition may vary. This is treated with 93% sulfuric acid to produce calcium sulfate, hydrogen fluoride (HF) and phosphoric acid. The HF is removed as...
of disulfur difluoride, thiothionyl fluoride, with the structure S=SF2. Silver(II) fluoride can fluorinate sulfur in a strictly dry container at 125 °C...
even weak proton acceptors. HSO3F hydrolyzes slowly to hydrogen fluoride (HF) and sulfuric acid. The related triflic acid (CF3SO3H) retains the high acidity...
Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula SO 2. It is...
gases include sulfur compounds, such as various sulfur oxides and hydrogen sulfide, and sometimes hydrogen chloride, hydrogen fluoride, and other gases...
commercial importance as a fluoride source. Hydrogen fluoride is liberated from the mineral by the action of concentrated sulfuric acid: CaF2 + H2SO4 → CaSO4(solid)...
across the double bond to give R2CFOSF3. A solution of sulfur tetrafluoride in hydrogen fluoride converts hydroxy-containing amino acids to the fluoro...
many metals to yield oxides and fluorides. Nonmetals also react: phosphorus reacts with OF2 to form PF5 and POF3; sulfur gives SO2 and SF4; and unusually...
Thiothionyl fluoride is a chemical compound of fluorine and sulfur, with the chemical formula S=SF2. It is an isomer of disulfur difluoride (difluorodisulfane)...