Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Stannane/ˈstæneɪn/ or tin hydride is an inorganic compound with the chemical formula SnH4. It is a colourless gas and the tin analogue of methane. Stannane can be prepared by the reaction of SnCl4 and Li[AlH4].[1]
SnCl4 + Li[AlH4] → SnH4 + LiCl + AlCl3
Stannane decomposes slowly at room temperature to give metallic tin and hydrogen and ignites on contact with air.[1]
Variants of stannane can be found as a highly toxic, gaseous, inorganic metal hydrides and group 14 hydrides.
^ abGreenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
Stannane /ˈstæneɪn/ or tin hydride is an inorganic compound with the chemical formula SnH4. It is a colourless gas and the tin analogue of methane. Stannane...
scientific study of the synthesis and properties of organotin compounds or stannanes, which are organometallic compounds containing tin–carbon bonds. The first...
is widespread. In regards to limitations, both very bulky stannane reagents and stannanes with substitution on the α-carbon tend to react sluggishly...
number of acyclic transition states. (E)-Stannanes exhibit higher syn selectivity than the corresponding (Z)-stannanes. (3) In the presence of certain Lewis...
alkynes. The typical stannane is tributyltin hydride. The reaction mechanism is assumed to operate via oxidative addition of the stannane to give a stannyl...
Related alkanes Ethane Propane Butane Related compounds Silane Germane Stannane Plumbane Supplementary data page Methane (data page) Except where otherwise...
germane GeH4 and digermane Ge2H6. They are germanium analogues of alkanes. Stannane SnH4, a strong reducing agent slowly decomposes at room temperature to...
alkynes, and all hydrocarbons silicon: silane germanium: germane tin: stannane lead: plumbane nitrogen: ammonia ("azane" when substituted), hydrazine...
replaced by an aryl boronic acid and in the Stille reaction by an aryl stannane. The cycle also extends to the other group 10 element nickel for example...
+4 oxidation states: tin(II) sulfide and tin(IV) sulfide (mosaic gold). Stannane (SnH 4), with tin in the +4 oxidation state, is unstable. Organotin hydrides...
(e.g., tin on an optical surface in the source) to form volatile SnH4 (stannane) that can be pumped out from the source proceeds via the reaction: Sn (s)...
is unstable as compared to its lighter congeners silane, germane, and stannane. It cannot be made by methods used to synthesize GeH4 or SnH4. In 1999...
Retrieved 2021-04-21. TETRAVINYLTIN - ChemicalBook Tetravinylstannane at Encyclopedia of Reagents for Organic Synthesis Stannane, tetraethenyl at NIST WebBook...
This biosynthesis can be mimicked in the laboratory by preparing allylic stannane from farnesol, termed Corey synthesis. There are diverse ways to synthesize...
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